Tradename:Benzeneheartcut(Naphtha(Petroleum),Catalyticreformed)

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WHMIS / PersonalProtectionEquipment / TDG(Ground)

Product identifier

Tradename:BenzeneHeartcut(Naphtha(petroleum),catalyticreformed)

SDSNr:SDS-0024

Chemicaldescription:Benzene 71-43-2(>10%)

CASNo:68955-35-1

EC No:649-308-00-2

Registration-No:Registrationdeadline notexpired.

Use:Rawmaterialforusedintheproductionandformulationofvariouschemicalsincluding gasoline and gasolineproducts.

Companyidentification: FreepointCommodities, LLC

58CommerceRoad

Stamford,Ct.06902

E-Mailaddress(competent person):Lou Santore

LouSantore[]Emergencytelephonenumber:Withinthe U.S.or Canada:1800 4249300

Outside the U.S. and Canada: +1 703 527 3887(collectcallsaccepted)

MSDSprepared by:PaulePatterson,ENERCONServices, Inc.

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GHSClassification:

FlammableLiquid–Category1or2dependingonformulation.AspirationHazard–Category1.

Carcinogenicity–Category2

SpecificTargetOrganToxicity(RepeatedExposure)–Category2SpecificTargetOrganToxicity(SingleExposure)–Category3SkinIrritation–Category2

EyeIrritation–Category2B

ChronicAquaticToxicity–Category2

GHSLABELELEMENTS

Symbol(s)

SignalWord

Danger

CLPHazardStatements:PHYSICALHAZARDS:

H224:Extremelyflammableliquidandvapor.

.

ENVIRONMENTALHAZARDS:

H411:Toxic toaquaticlifewithlong lasting effects.

HEALTHHAZARDS:

H315:Causesskinirritation.

H304:Maybefatal ifswallowedand entersairways.H361:Suspectedofdamaging fertilityortheunbornchild.H340:Maycausegeneticdefects.

H350:Maycausecancer.

H336:Maycausedrowsiness or dizziness.

EUH066:Repeatedexposure maycauseskin dryness or cracking.

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CLPPrecautionarystatementsPrevention :

P201:Obtainspecialinstructionsbefore use.

P210:Keep awayfrom heat/sparks/open flames/hotsurfaces. - No smoking.P261:Avoidbreathing dust/fume/gas/mist/vapors/spray.

P273:Avoidreleaseto the environment.

P280:Wearprotective gloves/protectiveclothing/eyeprotection/face protection.

Storage:

P403+P233:Storein a well-ventilatedplace.Keep container tightlyclosed.

Response :

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.

P331:DoNOTinduce vomiting.

Disposal:

P501:Disposeofcontentsandcontainertoappropriatewastesiteorreclaimerinaccordancewithlocal,state,andnationalregulations.

EC Symbols:

FHighlyflammable.TToxic.

NDangerousfortheenvironment.

EC Classification:

Highlyflammable.Toxic.Carcinogenic,category1. Mutagenic,category2.

EC Risk Phrases:

R45Maycausecancer.

R46Maycause heritablegeneticdamage.R11Highlyflammable.

R36/38Irritating to eyes and skin.

R48/23/24/25Toxic:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation,in contactwithskinandifswallowed.

R62Possibleriskofimpaired fertility.

R63Possibleriskofharmtothe unbornchild.

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R65Harmful:maycauselung damageifswallowed.R67Vaporsmaycausedrowsinessanddizziness.

R51/53Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.

EC SafetyPhrases:

S53 Avoidexposure.Obtain specialinstructionsbefore use.S16 Keepawayfromsourcesofignition- No smoking.

S29Do notemptyinto drains.

S45Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthelabelwherepossible).

S61Avoidreleasetotheenvironment.Refertospecialinstructions/Safetydatasheets.

SafetyHazards:

Vaporsmaycausedrowsinessanddizziness.Slightlyirritatingtorespiratorysystem.Irritatingtoeyesandskin.Harmful:maycauselungdamageifswallowed.Possibilityoforganororgansystemdamagefromprolongedexposure;seeChapter11fordetails.Targetorgan(s):Blood.Blood-formingorgans.Peripheralnervoussystem.Immunesystem.Centralnervoussystem(CNS).Respiratorysystem.Auditorysystem.Visualsystem.Maycausecancer.Maycauseleukemia(AML-acutemyelogenousleukemia).Maycauseheritablegeneticdamage.Toxic:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation,incontactwithskinandifswallowed.Possibleriskofimpaired fertility.Possibleriskofharm totheunbornchild.

AggravatedMedicalConditions:

Pre-existingmedicalconditionsofthefollowingorgan(s)ororgansystem(s)maybeaggravatedbyexposuretothismaterial:Auditorysystem.Blood.Blood-formingorgans.Cardiovascularsystem.Centralnervoussystem(CNS).Eyes.Immunesystem.Respiratorysystem.Skin.Visualsystem.

SafetyHazards:

Extremelyflammable.Electrostaticchargesmaybegeneratedduring handling.Electrostaticdischarge maycause fire.Liquidevaporatesquicklyandcan igniteleading toa flash fire,oran explosionin aconfinedspace.

EnvironmentalHazards:

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Toxic toaquaticorganisms,maycauselong-termadverseeffectsin the aquaticenvironment.

ChemicalName / CASNo. / EINECS / REACHRegistrationNo. / Concentration
Benzene / 71-43-2 / 200-753-7 / 01-2119447106-44 / 30.00-70.00%W
Benzene / 71-43-2 / 200-753-7 / 01-2119447106-44 / 30.00-70.00%W
Benzene / 71-43-2 / 200-753-7 / 01-2119447106-44 / 30.00-70.00%W
Benzene / 71-43-2 / 200-753-7 / 01-2119447106-44 / 30.00-70.00%W

FirstAid:Eyes

Incaseofcontactwitheyes,immediatelyflushwithclean,low-pressurewaterforatleast15 min. Holdeyelidsopentoensure adequate flushing.Seekmedicalattention.

FirstAid:Skin

Removecontaminatedclothing.Flushcontaminatedareasforatleast15minutes.Washcontaminatedareasthoroughlywithsoapandwaterorwaterlesshandcleanser.Obtainmedicalattentionifirritationorrednessdevelops.Thermalburnsrequireimmediate medicalattentiondepending ontheseverityandthearea ofthe bodyburned.

FirstAid:Ingestion

DONOTINDUCEVOMITING.Donotgiveliquids.Obtainimmediatemedicalattention.Ifspontaneousvomitingoccurs,leanvictimforwardtoreducetheriskofaspiration.Monitorforbreathingdifficulties.Smallamountsofmaterialwhichenterthemouthshould berinsed outuntil the tasteisdissipated.

Ifanyofthefollowingdelayedsignsandsymptomsappearwithinthenext6hours,transporttothenearestmedicalfacility:fevergreaterthan101°F(38,3°C),shortnessofbreath,chestcongestionor continuedcoughing or wheezing.

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FirstAid:Inhalation

Keepvictimcalm.Removepersontofreshair.Ifpersonisnotbreathing,provideartificialrespiration.Ifnecessary,provideadditionaloxygenoncebreathingisrestorediftrained todoso.Seekmedicalattentionimmediately.

Immediate MedicalAttention:

Potentialforchemicalpneumonitis.Potentialforcardiacsensitisation,particularlyinabusesituations.Hypoxiaornegativeinotropesmayenhancetheseeffects.Consider:oxygentherapy.Call adoctoror poisoncontrol centerfor guidance.

GeneralFire Hazards

See Section9for FlammabilityProperties.

Vaporscanreadilyformexplosivemixtureswithair.Heavierthanairvaporscanflowalongsurfacestoignitionsourcesandflashback.Useself-containedbreathingapparatusinenclosedareas.Formassivefires,useunmannedhoseholdersormonitornozzles.Ifthisisimpossible,withdrawfromareaandletfireburn.Always stayawayfromtanksengulfedinfire.

UnusualFire orExplosionHazards

Highlyvolatilematerial.Keepawayfromheat,sourcesofignitionandstrongoxidizers. Thismaterial canreactviolentlywithoxidizing agents.

HazardousCombustionProducts

Fumes,smoke,carbonmonoxide,sulfuroxides,aldehydesandotherdecomposition products,inthecaseofincompletecombustion.

ExtinguishingMedia

SMALLFIRES:AnyextinguishersuitableforClassBfires,drychemical,CO2,firefightingfoam,orgaseousextinguishingagent.Watermaysplashandspreadflamingliquid.Avoidspreadingburningliquidwithwaterusedforcoolingpurposes.Donotflushdownpublicsewers.Theuseofself- containedbreathingapparatusandprotectiveclothingisrecommendedfor firefighters.Avoidinhalationofvapors.

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LARGEFIRES:Waterspray,fogorfirefightingfoam.Watermaybeineffectiveforfightingthefire,butmaybeusedtocoolfire-exposedcontainers.Watermaysplashandspreadflamingliquid.Avoidspreadingburningliquidwithwaterusedforcoolingpurposes.Donotflushdownpublicsewers.Theuseofself-containedbreathingapparatusandprotectiveclothingisrecommendedforfirefighters.Avoidinhalationofvapors.

UnsuitableExtinguishingMedia

Waterdirectedatsource.

FireFightingEquipment/Instructions

Smallfiresintheincipient(beginning)stagemaytypicallybeextinguishedusinghandheldportablefireextinguishersandotherfirefightingequipment.Firefightingactivitiesthatmayresultinpotentialexposuretohighheat,smokeortoxicby-productsofcombustionshouldrequireNIOSH/MSHA-approvedpressure-demandself-containedbreathingapparatuswithfullfacepieceandfullprotectiveclothing.Isolateareaaroundcontainer involvedin fire.

Cooltanks,shells,andcontainersexposedtofireandexcessiveheatwithwater.Formassivefirestheuseofunmannedhoseholdersormonitornozzlesmaybeadvantageoustofurtherminimizepersonnelexposure.Majorfiresmayrequirewithdrawal,allowingthetanktoburn.Largestoragetankfirestypicallyrequirespeciallytrainedpersonnelandequipmenttoextinguishthefire,oftenincludingtheneedforproperlyappliedfirefightingfoam.

RecoveryandNeutralization

Danger,Flammable,eliminateallignitionsources.Equipmentusedinspillcleanupmustbegroundedtopreventsparking.Prevententryintowaterways,sewers,andconfinedareas.Carefullycontainandstopthesourceofthespill,ifsafetodoso.

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Materials andMethodsforClean-Up

Takeupwithsandor other oilabsorbingmaterials.Carefullyshovel, scooporsweepupintoa waste container,sealtightlyfor proper disposal or reclamation.

EmergencyMeasuresSmallSpills:

Evacuatenonessentialpersonnelandremoveorsecureallignitionsources.Consider winddirection; stayupwindanduphill,ifpossible.Evaluatethe directionofproducttravel,diking,sewers,etc.toconfirmspillareas.Productmayreleasesubstantialamountsofflammablevaporsandgases(e.g.,methane,ethane,andpropane),atorbelowambienttemperaturedependingonsourceandprocessconditionsand pressure.

LargeSpills(> 55gallons):

Isolatethehazardareaatleast150feetinalldirectionsandrestrictentrytounnecessarypersonnel.Shutoffsourceofleakonlyifitcanbedonesosafelyordikeandcontainthespill.Wearappropriaterespiratorandprotectiveclothing.Waterfogmaybeusefulinsuppressingvaporcloudcontainrun-off.Removewithvacuumtrucks.Soakupresiduewithsandorothersuitablematerial,placeincontainersforproperdisposal.Flushwithwateranddisposalofflushingsolutionsasabove.Local,stateandfederaldisposalregulationsmustbefollowed.

RegulatoryRequirements:Recoverednon-usablematerialisregulatedbytheUSEPAasahazardouswasteduetoitsignitibilitycharacteristics(D001)anditsbenzenecontent(D018).

PersonalPrecautions andProtectiveEquipment

Responseandclean-upcrewsmustbeproperlytrainedandmustutilizeproperprotectiveequipment(seeSection 8).

EnvironmentalPrecautions

Protectbodiesofwaterbydiking,absorbents,orabsorbentboom,ifpossible.Donotflushdownsewer or drainagesystems,unlesssystemisdesignedandpermittedtohandlesuchmaterial.Theuseoffirefightingfoammaybeusefulin

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certainsituationstoreducevapors.Theproperuseofwaterspraymayeffectivelydisperseproductvaporsortheliquiditself,preventingcontactwithignitionsourcesorareas/equipmentthatrequireprotection-donotdischargesolidwater streampatternsinto theliquidresulting insplashing.

Preventionof SecondaryHazards

None

HandlingProcedures

Avoidbreathingvaporsorcontactwithmaterial.Washthoroughlyafterhandling.OnguidanceonselectionofpersonalprotectiveequipmentseeChapter8ofthisSafetyDataSheet.Forcomprehensiveadviceonhandling,producttransfer,storageandtankcleaningrefertotheproductsupplier.Usetheinformationinthisdatasheetasinputtoariskassessmentoflocalcircumstancestohelpdetermineappropriatecontrolsforsafehandling,storageanddisposalofthismaterial.Extinguishanynaked flames.Do notsmoke.Removeignitionsources.

Handleasaflammableliquid.Keepawayfromheat,sparks,andopenflame!Electricalequipmentshouldbeapprovedforclassifiedarea.Bondandgroundcontainersduringproducttransfertoreducethepossibilityofstatic-initiatedfireor explosion.

Donot getineyes,on skinoronclothing.Donot breathevapors,mistsor fumes.Wearprotectiveequipmentdescribedinsection8ifexposureconditionswarrant.Useonlywithadequateventilation.

StorageProcedures

VaporsfromtanksshouldNOTbereleasedtotheatmosphere. Breathinglossesduringstorageshould becontrolledbyasuitablevapor treatmentsystem.

Bulktanksshould be encompassed byadike or containment.

Keepawayfromflame,sparks,excessivetemperatures,staticelectricity,pilotlights, and other ignition sources. Use approved vented containers. Keep

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containersclosedandclearlylabeled.Emptyproductcontainersorvesselsmaycontainexplosivevapors.Donotpressurize,cut,heat,weldorexposesuchcontainerstosourcesofignition.Bondandgroundcontainersduringtransferofgasoline.

The vapor is heavier than air. Beware of accumulation in pits and confinedspaces.

Storeinawell-ventilatedarea.ThisstorageareashouldcomplywithNFPA30"FlammableandCombustibleLiquidCode".Avoidstoragenearincompatiblematerials.ThecleaningoftankspreviouslycontainingthisproductshouldfollowAPIRecommendedPractice(RP)2013"CleaningMobileTanksInFlammableandCombustibleLiquidService"andAPIRP2015"CleaningPetroleumStorageTanks."

Incompatibilities

Keep awayfrom strong oxidizers.

Donotuse Natural,butyl,neopreneornitrilerubber containersfor storage.

Component ExposureLimits

Benzene(71-43-2)
ACGIH: / 0.5ppmTWA
2.5ppmSTEL
Skin-potentialsignificantcontributiontooverallexposurebythecutaneousroute
OSHA / 1ppmTWA
5ppmSTEL(Cancerhazard,Flammable,See29CFR1910.1028,15min);0.5ppmActionLevel
NIOSH / 0.1ppmTWA1ppmSTEL
Toluene(108-88-3)
OSHAPEL / 200ppmTWA
300ppmSTEL
ACGIHTLV / 50ppmTWA
NIOSH / 100ppmTWA
150ppmSTEL
NIOSHIDLH / 500ppm
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n-Hexane(110-54-3)
OSHAPEL / 500ppmTWA
ACGIHTLV / 50ppmTWA
NIOSH / 50ppmTWA
NIOSHIDLH / 1100ppm

(TWA)-TimeWeightedAverageis the employee’saverage airborne exposureinany8-hourworkshift of a 40-hourworkweekwhichshall not

be exceeded.

(STEL)-ShortTermExposureLimitis the employee’s15-minute time weightedaverage exposurewhichshall not be exceededatanytime duringaworkdayunlesstime limitisspecified.

EngineeringMeasures

UseadequateventilationtoprovideexplosionproofventilationtomeetTLVrequirementsinenclosedworkareas.Keepvaporconcentrationsofthisproductbelowoccupationalexposureandflammabilitylimits,particularlyinconfinedspaces.

PersonalProtectiveEquipment:Respiratory

ANIOSH/MSHA-approvedair-purifyingrespiratorwithorganicvaporcartridgesorcanistermaybepermissibleundercertaincircumstanceswhereairborneconcentrations(forexposuresoverTLVupto1000ppm)areormaybeexpectedtoexceedexposurelimitsorforodororirritation.Protectionprovidedbyair-purifying respiratorsislimited.

Useapositivepressure,air-suppliedrespiratorifthereisapotentialforuncontrolledrelease,exposurelevelsarenotknown,inoxygen-deficientatmospheres,oranyothercircumstancewhereanair-purifyingrespiratormaynotprovideadequate protection.

Employeesengagedinhandlingoperationsinvolvingbenzenemustbeprovidedwith,andrequiredtowearanduse,ahalf-maskfilter-typerespiratorfordusts,mists,andfumes.Arespiratoraffordinghigherlevelsofprotectionthanthisrespiratormaybesubstituted.

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MonitoringMethods:

MonitoringoftheconcentrationofsubstancesinthebreathingzoneofworkersorinthegeneralworkplacemayberequiredtoconfirmcompliancewithanOccupationalExposureLimit(OEL)andadequacyofexposurecontrols.Forsome substancesbiologicalmonitoringmayalsobe appropriate.

PersonalProtectiveEquipment:Hands

Chemicallyresistantglovesconstructed ofnitrileor neoprenearerecommended.

PersonalProtectiveEquipment: Eyes

Safetyglassesorgogglesarerecommendedwherethereisapossibilityofsplashing or spraying.

PersonalProtectiveEquipment: SkinandBody

ChemicalprotectiveclothingsuchasofE.I.DuPontTyChem®,Saranex®orequivalentrecommendedbasedondegreeofexposure.Note:Theresistanceofspecificmaterialmayvaryfromproducttoproductaswellaswithdegreeofexposure.Consultmanufacturer specificationsforfurther information.

HygieneMeasures

Emergencyeyewashcapabilityshouldbeavailableinthenearproximitytooperationspresentingapotentialsplashexposure.Usegoodpersonalhygienepractices.Avoidrepeatedand/orprolongedskinexposure.Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donotuseasacleaningsolventontheskin.Donotusegasolineorsolvents(naphtha,kerosene,etc.)forwashingthisproductfromexposedskin areas.Waterless handcleanersareeffective.

Promptlyremovecontaminatedclothingandlaunderbeforereuse.Usecarewhenlaunderingtopreventtheformationofflammablevaporswhichcouldigniteviawasheror dryer.Consider the needto discardcontaminatedleather shoesandgloves.

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Appearance: / Clear tolightyellow / Odor: / Characteristic light, hydrocarbonodor
PhysicalState: / Liquid / pH: / ND
VaporPressure: / 8.5 – 15.0 psi @ 100 F / VaporDensity: / 3.3
BoilingPoint: / AP95- 302°F / MeltingPoint: / ND
Solubility(H2O): / Negligible / SpecificGravity: / AP0.7-.0.9(varies)
Evaporation Rate: / Variable,but1 / VOC: / ND
Octanol/H2O Coeff.: / ND / FlashPoint: / -22°F
FlashPointMethod: / TCC / UpperFlammabilityLimit (UFL): / 6.0%
LowerFlammabilityLimit(LFL): / 1.0% / BurningRate: / ND
AutoIgnition: / >572°F

ChemicalStability

This isastable materialunder normalconditionsofuse.

HazardousReactionPotential

HazardousPolymerizationwill not occur.

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ConditionstoAvoid

Avoid high temperatures, open flames, sparks, welding, smoking and otherignitionsources.

Incompatible Products

Keep awayfrom strong oxidizers.

HazardousDecompositionProducts

Thermaldecompositionishighlydependentonconditions.

Carbonmonoxide,carbondioxideandnon-combustedhydrocarbons(smoke),sulfur oxides,aldehydes and other decompositionproducts.

AcuteToxicity

A:GeneralProduct Information

May be Fatal or Harmful if swallowed and enters airways.Occupationalexposureto thesubstanceormixturesmaycause adverseeffects.

B:ComponentAnalysis- LD50/LC50

Petroleumdistillates (naphtha) (8002-05-9)

OralLD50Rat>4300 mg/kg;DermalLD50Rabbit>2000 mg/kg

Benzene(71-43-2)

Inhalation LC50 Rat13050-14380ppm 4h; OralLD50Rat1800 mg/kg

PotentialHealthEffects: Skin ContactProperty

Causesskinirritation.

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PotentialHealthEffects: EyeContact Properties

Contactwitheyes maycause moderatetosevereirritation.

PotentialHealthEffects: Ingestion

Ingestion maycauseirritationand malaise.Swallowing or vomiting oftheliquidmayresultin aspirationinto thelungs.

PotentialHealthEffects: Inhalation

Inhalation ofvaporsmaycausedrowsinessanddizziness.

Germ cellMutagenicity:

Maycausegeneticdefects.Inin-vitroexperiments,neither benzene,toluenenorxylenechanged thenumberofsister-Chromatidexchanges(SCEs) or thenumberofchromosomalaberrationsin humanlymphocytes.However,tolueneandxylenecaused asignificantcellgrowthinhibitionwhichwas notobservedwithbenzeneinthesameconcentrations.Inin-vivoexperiments,

toluenechanged thenumber ofsister-chromatidexchanges(SCEs) inhumanlymphocytes.

Toluene maycause heritablegeneticdamage.

Carcinogenicity

A:GeneralProduct Information

Maycausecancer.Containsbenzene,aclassifiedIARC1chemical(KnownHumanCarcinogen).Alsocontainsethylbenzene,whichisclassifiedasanIARC2Bchemical(PossiblyCarcinogenic toHumans).

Benzeneislisted as a humancarcinogen bytheNTP,IARC,OSHAand ACGIH.

IARCMonographs.OverallEvaluationof Carcinogenicity

Benzene(CAS71-43-2) 1Carcinogenicto humans.

Gasoline; Lowboilingnaphtha - unspecified(CAS86290-81-5) 2BPossiblycarcinogenic to humans.

Toluene(CAS108-88-3) 3Notclassifiable astocarcinogenicitytohumans.

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Reproductivetoxicity:

Suspected ofdamaging theunborn child.Suspectedofdamaging fertility.Benzene,xyleneandtoluenehavedemonstrated animaleffectsofreproductivetoxicity. Animal studiesofbenzene haveshowntesticular effects,alterationsinreproductivecycles,chromosomalaberrationsand embryo/fetotoxicity.Ethanolhas demonstrated humaneffectsofreproductivetoxicity. Maydamage fertilityorthe unbornchild.Cancause adversereproductiveeffects - suchasbirthdefects,miscarriages, or infertility.Avoidexposureto womenduring earlypregnancy.

Avoidcontactduring pregnancy/whilenursing.

USExportGasolines -AllGrades(Refer to Synonyms for ProductName)SDSEU

903868 Version #:05 Revisiondate:17-August-2012Issue date:28-July-201112/16

Specific target organtoxicity-singleexposure- Maycausedrowsiness ordizziness.

Specific target organtoxicity-repeatedexposure-Notclassified.

B:Component Carcinogenicity

Petroleum distillates (naphtha) (8002-05-9)
IARC: / Monograph45[1989](Group3(notclassifiable))
Benzene(71-43-2)ACGIH: / A1-ConfirmedHumanCarcinogen
OSHA: / 5ppmSTEL(Cancerhazard,Flammable,See29CFR1910.1028,15min);0.5ppmActionLevel;1ppmTWA
NIOSH: / potentialoccupationalcarcinogen
NTP: / KnownHumanCarcinogen(SelectCarcinogen)
IARC: / Monograph100F[inpreparation]

Ecotoxicity

Incompleteecotoxicologicaldataareavailableforthisproduct.Theinformationgivenbelowisbasedpartlyonknowledgeofthecomponentsandtheecotoxicologyofsimilarproducts.

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A:GeneralProduct Information

Keepoutofsewers,drainageareasandwaterways.Reportspillsandreleases,as applicable,under local,State,andFederalregulations.

Maybedangerousifitenterswater intakes.Notifylocalhealthand wildlifeofficials.

Notifyoperatorsofnearbywater intakes.

Waste DisposalInstructions

SeeSection7forHandlingProcedures.SeeSection8forPersonalProtectiveEquipmentrecommendations.

Thismaterialanditscontainermustbe disposedofin asafeway.

It istheresponsibilityof theusertodetermine ifdisposalmaterialishazardousaccording to federal,state and localregulations.

It istheresponsibilityof theusertodetermine ifdisposalmaterialishazardousaccording to federal,state and localregulations.

Disposalof ContaminatedContainersorPackaging

Disposeofcontents/container inaccordance withlocal,state,and federalregulations.

DisposalRegulatoryRequirements:

Recoverednon-usable materialisregulatedbytheUSEPAasahazardouswasteduetoitsignitibilitycharacteristics(D001) anditsbenzenecontent(D018).

ContainerCleaningandDisposal:“Empty”ContainerWarning:

“Empty” containersretainproductresidue (liquidand/or vapor) andcanbedangerous.DONOTPRESSURIZE,CUT,WELD, BRAZE,SOLDER,DRILL,GRIND, OR EXPOSESUCHCONTAINERSTOHEAT,FLAME,SPARKS,STATICELECTRICITY, OR OTHER SOURCESOF IGNITION.THEYMAYEXPLODEANDCAUSEINJURYOR DEATH.

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DOTInformation:Placard:

ShippingName:HYDROCARBONS,LIQUID,N.O.S.

UN #:3295

HazardClass:3-Packing -I

Landtransport (ADR/RID):ADR

14.1UNnumber:3295

14.2UNproper shipping name:HYDROCARBONS,LIQUID,N.O.S.

14.3Transporthazardclass(es): 3

14.4Packing group : IDanger label(primaryrisk): 3Danger label(subsidiaryrisk): 3

14.5Environmentalhazards:Yes

RID

14.1UNnumber:3295

14.2UNproper shipping name:HYDROCARBONS,LIQUID,N.O.S..

14.3Transporthazardclass(es): 3

14.4Packing group : IDanger label(primaryrisk): 3Danger label(subsidiaryrisk): 3

14.5Environmentalhazards:Yes

Seatransport (IMDGCode):

14.1UNnumber:3295

14.2UNproper shipping name:HYDROCARBONS,LIQUID,N.O.S.

14.3Transporthazardclass(es): 3

14.4Packing group : IDanger label(primaryrisk): 3Danger label(subsidiaryrisk): 3

14.5Environmentalhazards:Yes

14.5 Environmentalhazards:Yes.MarinePollutant

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Airtransport (IATA):

14.1UNnumber:3295

14.2UNproper shipping name:HYDROCARBONS,LIQUID,N.O.S.

14.3Transporthazardclass(es): 3,Subsidiaryclass/Division: 6.1

14.4Packing group:I

ComponentAnalysis

ThismaterialcontainsoneormoreofthefollowingchemicalsrequiredtobeidentifiedunderSARASection302(40CFR355AppendixA),SARASection313(40CFR

372.65) and/or CERCLA(40CFR302.4).

EPA Regulations

RCRA HazardousWasteNumber:D001

RCRA HazardousWasteClassification(40 CFR 261):D018

CERCLA ReportableQuantity(RQ)(40 CFR 302.4):

Compound / CAS Number / RQ
Benzene / 71-43-2 / 10
Toluene / 108-88-3 / 1000
n-Hexane / 110-54-3 / 5000
SARASection311/312–HazardClassesAcuteHealth / ChronicHealth / Fire / SuddenReleaseofPressure / Reactive
X / X / X / -- / --

SARASECTION 313-SUPPLIERNOTIFICATION

This productcontainsthe following toxic chemicals subject tothereporting requirementsofsection313oftheEmergencyPlanningandCommunityRight-To-Know Act(EPCRA)of1986 andof 40 CFR372:

INGREDIENTNAME(CASNUMBER) / CONCENTRATIONPERCENTBYWEIGHT
Benzene(71-43-2) / <0.1to2
/ SAFETYDATASHEET / Page:Page20of20
Revisionedition:2
Date:8/3/2015
BenzeneHeartcut / Supersedes:Revision1
SDS-0024

Thefollowingstatement(s)areprovidedundertheCaliforniaSafeDrinkingWaterandToxicEnforcementActof1986(Proposition 65):

WARNING!ThisproductcontainsachemicalknowntothestateofCaliforniatocausecancer.

WARNING!ThisproductcontainsachemicalknowntothestateofCaliforniatocausereproductive/developmentaleffects.

ComponentAnalysis- WHMISIDL

ThefollowingcomponentsareidentifiedundertheCanadianHazardousProductsActIngredientDisclosureList:

Component / CAS# / MinimumConcentration
Benzene / 71-43-2 / 0.1%

DISCLAIMEROFLIABILITY:Beforeusingthisproductinanynewprocessorexperiment,a thoroughmaterialcompatibilityand safetystudyshouldbe carriedout.

Thisdocumentisgeneratedforthepurposeofdistributinghealth,safety,andenvironmentaldata.

InformationiscorrecttothebestofourknowledgeatthedateoftheSDSpublication.Itisnotaspecificationsheetnorshouldanydisplayeddatabeconstruedasaspecification.

Theinformationonthiswasobtainedfromsourceswhichwebelievearereliable.However,theinformationisprovidedwithoutanywarranty,expressedorimplied,regardingitscorrectness.Someinformationpresentedandconclusionsdrawnhereinarefromsourcesotherthandirecttestdataonthesubstanceitself.Theconditionsormethodsofhandling,storage,useanddisposaloftheproductarebeyondourcontrolandmaybebeyondourknowledge.Forthisandotherreasons,wedonotassumeresponsibilityandexpresslydisclaimliabilityforloss,damage,orexpensearisingoutoforinanywayconnectedwithhandling,storage,use,ordisposalofthisproduct.Iftheproductisusedasacomponentinanotherproduct,thisSDSinformationmaynotbeapplicable.