Silver4schools

The History of silver mining

Silver has been known since ancient times. It is mentioned in the Book of Genesis, and slag heaps found in Asia Minor and on the islands of the Aegean Sea indicate that silver was being separated from lead as early as the 4th millennium BCE. The silver mines at Laurium were very rich and helped support the economy of Ancient Athens. It involved mining the ore in underground galleries, washing the ores and smelting it to produce the metal. Elaborate washing tables still exist at the site using rain water held in cisterns and collected during the winter months. . Although it is usually found in ores with less rare metals, such as copper, lead, and zinc, silver was apparently discovered in nugget form, called native silver, about 4000 B.C. Silver utensils and ornaments have been found in ancient tombs of Chaldea, Mesopotamia, Egypt, China, Persia, and Greece.

Extraction of silver from lead ore was widespread in Roman Britain as a result of Roman mining very soon after the conquest of the first century AD.

Silver in Europe

Europeans found a huge amount of silver in the New World in the now Mexican State of Zacatecas (discovered in 1546) and Potosí (Bolivia, also discovered in 1546), which triggered a period of inflation in Europe. The conquistador Francisco Pizarro was said to have resorted to having his horses shod with silver horseshoes due to the metal's abundance, in contrast to the relative lack of iron in Peru. Silver, which was extremely valuable in China, became a global commodity, contributing to the rise of the Spanish Empire. The rise and fall of its value affected the world market.

Silver in North America

Silver mining was a driving force in the settlement of western North America, with major booms for silver and associated minerals (lead, mostly) in the galena ore silver is most commonly found inThe first major silver ore deposits in the United States were discovered at the Comstock Lode in Virginia City, Nevada, in 1859.

Silver is found in native form very rarely as nuggets, but more usually combined with sulfur, arsenic, antimony, or chlorine and in various ores such as argentite (Ag2S) and chlorargyrite ("horn silver," AgCl). The principal sources of silver are copper, copper-nickel, gold, lead and lead-zinc ores obtained from Canada, (such as Cobalt, Ontario), Mexico (such as Batopilas), Peru, Bolivia, Australia and the United States.

Silver in Mexico

Mexico is the world's second largest silver producer after Peru in 2005. According to the Secretary of Economics of Mexico, it produced 80,120,000 troy ounces (2,492 metric tons) in 2000, about 15 percent of the annual production of the worl

The ManufacturingProcess

Silver was first obtained in sixteenth-century Mexico by a method called the patio process. It involved mixing silver ore, salt, copper sulphide, and water. The resultant silver chloride was then picked up by adding mercury. This inefficient method was superseded by the von Patera process. In this process, ore was heated with rock salt, producing silver chloride, which was leached out with sodium hyposulfite. Today, there are several processes used to extract silver from ores.

A method called the cyanide, or heap leach, process has gained acceptance within the mining industry because it is a low-cost way of processing lower-grade silver ores. However, the ores used in this method must have certain characteristics: the silver particles must be small; the silver must react with cyanide solutions; the silver ores must be relatively free of other mineral contaminants and/or foreign substances that might interfere with the cyanidation process; and the silver must be free from sulfide minerals. The idea for cyanidation actually dates back to the eighteenth century, when Spanish miners percolated acid solutions through large heaps of copper oxide ore. The process developed into its present form during the late nineteenth century. The cyanide process is described here.

Preparing the ore

  • 1 Silver ore is crushed into pieces, usually with 1-1.5 in (2.5-3.75 cm) diameters, to make the material porous. Approximately 3-5 lb (1.4-2.3 kg) of lime per ton of silver ore is added to create an alkaline environment.

The ore must be completely oxidized so the precious metal is not confined in sulfide minerals. Where fines or clays exist, the ore is agglomerated to create a uniform leach pile. This process consists of crushing the ore, adding cement, mixing, adding water or a cyanide solution, and curing in dry air for 24-48 hours.

  • 2 Broken or crushed ore is stacked on impermeable pads to eliminate the loss of the silver cyanide solution. Pad material may be asphalt, plastic, rubber sheeting, and/or clays. These pads are sloped in two directions to facilitate drainage and the collection of the solutions.

Adding the cyanide solution and curing

  • 3 A solution of water and sodium cyanide is added to the ore. Solutions are delivered to the heaps by sprinkler systems or methods of ponding, including ditches, injection, or seepage from capillaries.

Recovering the silver

  • 4 Silver is recovered from heap leach solutions in one of several ways. Most common is Merrill-Crowe precipitation, which uses fine zinc dust to precipitate the precious metal from the solution. The silver precipitate is then filtered off, melted, and made into bullion bars.
  • 5 Other methods of recovery are activated carbon absorption, where solutions are pumped through tanks or towers containing activated carbon, and the addition of a sodium sulfide solution, which forms a silver precipitate. In another method, the solution is passed through charged resin materials which attract the silver. The recovery method is generally decided based on economic factors.

Silver is rarely found alone, but mostly in ores which also contain lead, copper, gold, and other metals which may be commercially valuable. Silver emerges as a byproduct of processing these metals. To recover silver from zinc-bearing ores, the Parkes process is used. In this method, the ore is heated until it becomes molten. As the mixture of metals is allowed to cool, a crust of zinc and silver forms on the surface. The crust is removed, and the metals undergo a distillation process to remove the zinc from the silver.

To extract silver from copper-containing ores, an electrolytic refining process is used. The ore is placed in an electrolytic cell, which contains a positive electrode, or anode, and a negative electrode, or cathode, in an electrolyte solution. When electricity is passed through the solution, silver, with other metals, accumulates as a slime at the anode while copper is deposited on the cathode. The slimes are collected, then roasted, leached, and smelted to remove impurities. The metals are formed into blocks which are used as anodes in another round of electrolysis. As electricity is sent through a solution of silver nitrate, pure silver is deposited onto the cathode.

Silver is commonly extracted from ore by smelting or chemical leaching. Ore treatment by mercury amalgamation, such as in the patio process or pan amalgamation was widely used through the 1800s, but is seldom used today.

Silver is also produced during the electrolytic refining of copper and by application of the Parkes process on lead metal obtained from lead ores that contain small amounts of silver. Commercial grade fine silver is at least 99.9 percent pure silver and purities greater than 99.999 percent are available.