Safety data sheet

IT’S COLOR permanent creme haircolor

1 Elements identifying the substance or preparation and the company
Commercial name: IT’S COLOR permanent color haircream
Sales code: from 11010501 to 11010643; from 11030700 to 11030714
packaging: tube 150 ml
Manufacturer/supplier:
UNICOMPANY S.p.a. Via Pontina vecchia km 33,600 Ardea (Rome)
Telephone number for urgent calls to the company and/or to an official
consultancy body:
UNICOMPANY S.p.a. – Tel. +39 069145177
Technical person who is responsible for writing MSDS:

2 Hazard identification
Danger classification:
R22 Harmful if swallowed
R36/38 Irritant for eyes and skin
3 Composition/information on ingredients
Description: Mixture of dyes in crème for professional hair care use.
Ingredients (according to INCI nomenclature):
NEUTRAL: Aqua – Cocamide MEA – Cetearyl alcohol – Ceteareth-30 – Lauramidopropyl betaine – Decyl oleate – Lanolin - Tetrasodium EDTA – Parfum – Sodium sulfite – Sodium Hydrosulfite – Hexyl cinnamal - Cynnamyl alcohol – Citronellol – Geraniol – Benzyl salicylate – Benzyl benzoate – Linalool – Coumarin - Eugenol
COLOR BASE AND EXTRA BLONDING CREAM: Aqua – Cocamide MEA – Ammonia – Cetearyl alcohol – Ceteareth-30 – Lauramidopropyl betaine – Decyl oleate – Lanolin - Tetrasodium EDTA – Parfum – Sodium sulfite – Sodium Hydrosulfite – Hexyl cinnamal - Cynnamyl alcohol – Citronellol – Geraniol – Benzyl salicylate – Benzyl benzoate – Linalool – Coumarin - Eugenol

GROUPS OF NUANCES

/ RELATIVE DYES INCI NAME
1N - 1B – Blu enhancer / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; N-phenyl-p-phenylenediamine; N,N-bis-(2-hydroxyethyl)-p-phenylenediamine
1V - 2N - 3N - 6.01 - 7.01 - 8.01 - 9.01 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine
4N - 7.16 - 4.3 - 5.3 - 8.41 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; p-aminophenol; HC yellow 2
5N - 6N – 5.71 – 6.71 – 7.71 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; p-aminophenol; HC yellow 2; resorcinol
7N - 8N - 9N – Yellow Enhancer / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; p-aminophenol; HC yellow 2; HC orange 1
10N - 8.3 - 9.3 - 5.43 / p-phenylenediamine; 2-methylresorcinol; p-aminophenol; HC yellow 2; 1-naphthol; HC orange 1; resorcinol; 2-amino-3-hydroxy pyridine
4.4 – 6.7 - 3.16 - 5.16 – 5.41 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine;
N,N-bis-(2-hydroxyethyl)-p-phenylenediamine
p-aminophenol; HC yellow 2; 1-naphthol; HC orange 1; resorcinol; 2-amino-3-hydroxy pyridine
7.44 - 5.4 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; p-aminophenol; 1-naphthol; 2-amino-3-hydroxy pyridine; 3-nitro-p-hydroxyethylaminophenol
6.4, 7.4, 8.43, 8.44 / p-phenylenediamine; 4-amino-2-hydroxy toluene; p-aminophenol
6.66, 7.66 / p-phenylenediamine; 1- hydroxyethyl 4,5-Diamino pyrazole sulfate; 4-amino-2-hydroxy toluene; p-aminophenol; 1-naphthol; 2-amino-3-hydroxy pyridine
8.4 - 9.4 - 7.40, - 9.44 - 5.5 - 7.5 - 6.65 – 7.3 –6.43 - 7.43 – 8.33 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; 2-methylresorcinol; 4-amino-2-hydroxy toluene; p-aminophenol
6.5 – 4.7 – Red Enhancer / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; p-aminophenol; resorcinol; 2-amino-3-hydroxy pyridine
4.6 –5.6 - 6.6 - 7.6 / p-phenylenediamine; 4-chlororesorcinol; 1- hydroxyethyl 4,5-Diamino pyrazole sul fate, 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; p-aminophenol; 1-naphthol; 2-amino-3-hydroxy pyridine; HC red 3
5.7 - 3.7 - 4.71 – 4.41 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; p-aminophenol; HC yellow 2; resorcinol; 2-amino-3-hydroxy pyridine
6.64 - 7.64 - 7.65 / p-phenylenediamine; m-aminophenol; 4-amino-2-hydroxy toluene; p-aminophenol
7S - 8S - 9S - 900 – 903 – 6.3 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol
911 - 912 - 9.11 - 8.11 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; N-phenyl-p-phenylenediamine
3P / p-phenylenediamine; 4-chlororesorcinol; 4-amino-2-hydroxy toluene; Disperse violet 1
6.16 – 5.11 – 6.11 – 7.11 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; N,N-bis-(2-hydroxyethyl)-p-phenylenediamine; p-aminophenol; basic red 51; basic blue 99
7F – 6F / basic red 51 - basic yellow 87 – Etidronic acid - Ethanolamine
6.33 – 7.33 – 9.33 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; 2-methylresorcinol; 4-amino-2-hydroxy toluene; p-aminophenol; HC yellow 2; 1-naphthol; HC orange 1; resorcinol; 2-amino-3-hydroxy pyridine; 4-amino-m-cresol
4.65 – 5.65 / p-phenylenediamine; 4-chlororesorcinol; 4-amino-2-hydroxy toluene; p-aminophenol; 1-naphthol
6.41 – 7.41 – 7.7 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol; 2-methylresorcinol; 4-amino-2-hydroxy toluene; N-phenyl-p-phenylenediamine; p-aminophenol
4.5 – 4.62 – 5.62 / p-phenylenediamine; 2-amino-4-hydroxyethylamino anisole sulfate; 2-methylresorcinol; 4-amino-2-hydroxy toluene
5.01 - 901 / p-phenylenediamine; 4-chlororesorcinol; 2-amino-4-hydroxyethylamino anisole sulfate; m-aminophenol
Dangerous substances:
Name/classification CAS N.67/548/CE EINECS
Ammonia 1336-21-6 215-647-6 -
Xi–Irritant R36/37/38
1-naphthol 90-15-3 201-969-4 -
Xn harmful R21/22
Xi Irritant R37/38 R41
4 First aid measures
Inhalation: The product cannot be inhaled
Contact with the skin: Washing with running water
Contact with the eyes: Washing well with large amount of running water
Swallowing: Washing out the mouth. Consult immediately a doctor
5 Fire fighting measures
Suitable extinguishers:
Large amount of water. No type of extinguisher prohibited
Combustion risks: None
Specific protective equipment: None
6 Accidental release measures
Personal protection: None
Environmental precautions: None
Cleaning/absorption methods:
Collect up the product with suitable medium. Use suitable container to the
disposal.
7 Handling and storage
Handling:
Product can be handle without problem.
Storage:
Requirements for the warehouse and containers:
Store in a cool place.
Store in the original sealed containers
Check the state and temperature of containers at frequent intervals.
Protect from heat and direct sunlight.
8 Checking individual protection/exposure
Precautionary measures: Keep out from food and beverage.
Respiratory protection: None
Hand protection: Use proper gloves
Eye protection: None
9 Physical and chemical properties
Appearance and colour: Colored creme
Odour: Characteristic of fragrance
Specific weight between 0.97 and 0.99
pH(as is): between 9,0 and 10,5
Boiling point: n.a.
Melting point: 38°C
Properties supporting combustion: no supports combustion
Vapour pressure: not available
Water solubility: partially soluble
Vapour density: not available
10 Stability and reactivity
Thermal decomposition /conditions to be avoided:
Stable in normal conditions. Avoid heat, heat sources.
Dangerous reactions: None
11 Toxicological information
The product contains ingredients that might irritate sensitive skin. We suggest a preliminary sensibility test about 48 hours before the first application.
Extended (chronic)exposure: The product has not been tested according with “OSHA Hazard communication standard”
Target organ: skin
Organism entrance way: ingestion and skin
General health conditions during the extended exposure will be related with the primary toxic effects of the substances used. The presence of skin irritant might get worse pre-existent dermatitis.
12 Ecological information
Use in accordance with normal rules of good practice at work, avoiding any dispersion of the product into the surrounding environment
13 Notes on waste disposal
Product: Do not dispose of the product along with normal domestic waste.
Dirty packing materials: Dispose of in conformity with current administrative requirements
14 Transport information
The product does not contains dangerous substances for the rail/road transport, air transport and marine transport.
ADR/RID rail/road transport (outside national boundaries): not classified
ICAO-TI and IATA-DGR air transport: not classified
IMDG marine transport: not classified
15 Information on regulations
Classification according to EEC directives:
Product danger code and labelling: not dangerous
Dangerous components requiring labelling: none
Nature of specific risks (R phrases):
R22 Harmful if swallowed
R36/38 Irritant for eyes and skin
Safety recommendations (S phrases)
S2 keep out of reach of children
S7 keep container well close
Legislative reference list:
Law 11/10/1986, n° 713 and subsequent modifications – cosmetic products
D.law 136/83 - biodegradability
D. law 5/02/97, n° 22 – classification, packing, labelling of dangerous preparations
D. law 277/91 – exposure to chemical agent
D. law 626/94 – worker safety
D. law 3/02/97, n° 52 – classification of dangerous substances
D. law 16/07/98, n° 285 – classification of dangerous preparations
D.P.R. 303/56 – sanitary inspections
Directive 1999/45/EC
Directive 2001/58/EC
And subsequent modifications and provisions for implementation.
16 Other information
The data provided is based on our current knowledge, and in no way guarantees
the product characteristics or gives support to any legal contractual
relations.
DATA SHEET REALIZED BY: UNICOMPANY S.p.a.
This data sheet substitutes all previous versions
Previous revision: 3 of the 5th June 2008

MATERIAL SAFETY DATA SHEET IT’S COLOR crème haircolor

6

Revision 4 of the 26th September 2008