SHERWIN-WILLIAMS CO -- SPARVAR PRODUCTS-3, S-500 PERMACLEAR -- 8010-00N083644
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MSDS Safety Information
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FSC: 8010
MSDS Date: 09/01/1996
MSDS Num: CGRCD
LIIN: 00N083644
Tech Review: 01/22/2002
Product ID: SPARVAR PRODUCTS-3, S-500 PERMACLEAR
Responsible Party
Cage: DO642
Name: SHERWIN-WILLIAMS CO
Address: 31500 SOLON RD
City: SOLON OH 44139 US
Info Phone Number: 800-777-2966
Emergency Phone Number: 216-566-2917
ReviewInd: N
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Contractor Summary
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Cage: DO642
Name: SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Address: 6830 COCHRAN RD.
Box: 6709
City: SOLON OH 44139-3908
Country: NK
Phone: 216-292-7400
Cage: 09800
Name: SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address: 26300 FARGO AVENUE
City: BEDFORD HEIGHTS OH 44146 US
Phone: 216-292-7400 OR 216-595-8634
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Ingredients
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Cas: 74-98-6
RTECS #: TX2275000
Name: PROPANE.VP: 760.
% by Wt: 15
OSHA PEL: 1000 PPM
ACGIH TLV: ASPHYXIANT
Ozone Depleting Chemical: N
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Cas: 106-97-8
RTECS #: EJ4200000
Name: BUTANE. VP: 760.
% by Wt: 15
OSHA PEL: 800 PPM
ACGIH TLV: 800 PPM
Ozone Depleting Chemical: N
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Cas: 64742-89-8
Name: LACOLENE; (LT ALIPHATIC HYDROCARBON SOLVENT). VP: 53.
% by Wt: 6
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313). VP: 7.1.
% by Wt: 4
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM; 125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
Ozone Depleting Chemical: N
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). VP: 5.9.
% by Wt: 22
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM; 150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
Ozone Depleting Chemical: N
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Cas: 64742-94-5
RTECS #: WF3100000
Name: SOLVENT NAPHTHA; (MEDIUM AROMATIC HYDROCARBONS).VP: 0.1.
% by Wt: 2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 67-64-1
RTECS #: AL3150000
Name: ACETONE (SARA 313) (CERCLA). VP: 180.
% by Wt: 26
OSHA PEL: 1000 PPM
ACGIH TLV: 750 PPM; 1000 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: N
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: IRRIT OF EYES, SKIN & RESPIRATORY SYSTEM. MAY
CAUSE NERVOUS SYSTEM DEPRESS. EXTREME OVEREXP MAY RESULT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS
TO VAPS/SPRAY MISTS. REDNESS & ITCH OR BURNING SENSATION MAY INDICATE
EYE/EXCESS SKIN EXPOS. CHRONIC: PRLNGD OVEREXP TO LISTED SOLVENT INGREDS
MAY CAUSE ADVERSE EFFECTS TO LIVER, URINARY, BLOOD-FORMING,
CARDIOVASCULAR & REPRODUCTIVE SYSTEMS. REPORTS HAVE ASSOC RPTD & PRLNGD
OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE GENERALLY RECOGNIZED.
First Aid: INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP
WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMD CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH EYES W/LARGE AM TS OF
WATER FOR AT LEAST 15 MIN. GET MED ATTN. INGEST: NEVER GIVE ANYTHING BY
MOUTH TO AN UNCON PERSON. DO NOT INDUCE VOMIT. GIVE CONSCIOUS PATIENT
SEVERAL GLASSES OF WATER. SEEK MED ATTN.
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Handling and Disposal
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Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR. DISPOSE
OF I/A/W FE DERAL, STATE & LOCAL REGS REGARDING POLLUTION.
Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPKS & OPEN FLAME.
VAPS WILL ACCUM READILY & MAY IGNITE EXPLO. DURING USE & UNTIL ALL VAPS
ARE GONE:KEEP AREA VENTD - DO NOT SMOKE - EXTING ALL FLAMES, PILOT
LIGHTS & HEATERS - TU RN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER
SOURCES OF IGNIT. CONSULT NFPA CODE. USE (SUPDAT)
Other Precautions: INTENTIONAL MISUSE BY DEBLIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THIS COATING MAY CNTN
MAT LS CLASSIFIED AS NUISANCE OTHER PRECS: PARTICULATES LISTED "AS DUST"
IN INGRED SECTION WHICH MAY BE PRESENT (OTHER INFO)
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point Text: <0F,<-18C
Lower Limits: 0.7%
Upper Limits: 12.0%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP(FP N).
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILDUP & POSS AUTOIGNIT
OR EXPLO WHEN EXPOS TO EXTREME HEAT.
Unusual Fire/Explosion Hazard: ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN
FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATN
TO HOT SURFS REQS SPEC PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS
MAY CAUSE HLT H HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.
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Control Measures
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Respiratory Protection: IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESP
APPRVD BY NIOSH. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP
APPRVD BY N IOSH FOR DUST WHICH MAY BE GENERATED FROM THIS PROD,
UNDERLYING PAINT OR THE ABRASIVE.
Ventilation: LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOS
TO MATLS LISTED IS MAINTAINED BELOW EXPOS LIMITS. REFER TO OSHA STDS
1910.94, 1910.107, 1910.108.
Protective Gloves: CHEMICAL RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: HNDLG/STOR PRECS: APPRVD BONDING &
GROUNDING PROCEDURES. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCINERATE
OR EXPOSE TO TEMPS ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES,
HOT H*20 & OTHER HEAT S OURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
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Physical/Chemical Properties
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B.P. Text: <395F,<202C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 0.714 (FP N)
VOC Pounds/Gallon: 3.93
Evaporation Rate & Reference: FASTER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Other Information: VOLATILE ORGANIC COMPOUND BY WT PER BAAQMD RULE 49:
66.5%; VOC TOTAL: 3.93 LBS/GAL. OTHER PRECS: AT HAZ LEVS ONLY DURING
SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC
LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15
MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION).
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HAZCOM Label
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Product ID: SPARVAR PRODUCTS-3, S-500 PERMACLEAR
Cage: DO642
Company Name: SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Street: 6830 COCHRAN RD.
PO Box: 6709
City: SOLON OH
Zipcode: 44139-3908
Country: NK
Health Emergency Phone: 216-566-2917
Date Of Label Review: 03/02/1998
Label Date: 03/02/1998
Chronic HazardIND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: EYES/SKIN: IRRITATION
WITH REDNESS AND ITCHING OR BURNING SENSATION. INHALATION: RESPIRATORY
SYSTEM IRRITATION WITH HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION, UNCON SCIOUSNESS AND POSSIBLY DEATH. CHRONIC:OVEREXPOSURE
TO SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY,
BLOOD-FORMING, CARDIOVASCULAR AND REPRODUCTIVE SYSTEMS AND HAS BEEN
ASSOCIATED WITH PER MANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
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This information is formulated for use by elements of the Department of
Defense. The United States of America in no manner whatsoever expressly
or implied warrants, states, or intends said information to have any
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liability for such use. Any person utilizing this instruction who is not
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seek competent professional advice to verify and assume responsibility
for the suitability of this information to their particular situation
regardless of similarity to a corresponding Department of Defense or
other government situation.