Agates

Inside Out

Designed, Written, and Compiled by Karen A. Brzys

Photography by Thomas P. Shearer

Research Assistance by Candace Prill

Cover Photograph: An intricate Lake Superior agate.

Figure 1 (above): A condor agate from Argentina.

Table of Contents

Dedication ...... vi

Acknowledgements...... vii

Introduction...... viii

CHAPTER 1: What Is An Agate? ...... 1

A BASIC DESCRIPTION...... 1

AGATES AND HUMAN HISTORY...... 2

AGATES AND THEIR “FIRST COUSINS”...... 4

Macrocrystalline Quartz ...... 4

Fibrous Microcrystalline Quartz ...... 8

Granular Microcrystalline Quartz...... 9

Silicified Fossils...... 10

QUARTZ PROPERTIES...... 14

CHAPTER 2: How Did Agates Form? ...... 16

THE EARTH — IN THE BEGINNING...... 16

AGATE FORMATION ...... 21

INFLOW AGATE GENESIS THEORY...... 24

Possible Sources of Silica...... 28

Silica Transport ...... 31

Infiltration Channels ...... 34

Concentric Banding...... 41

Horizontal Banding...... 55

SILICA GEL AGATE GENESIS THEORY...... 57

AGATE GENESIS CONCLUSIONS ...... 60

Silica Gel Theory ...... 60

Inflow Theory ...... 62

TYPES OF HOST ROCK...... 65

Igneous Rock Agates ...... 67

Amygdaloidal Agates ...... 67

Rhyolitic Agates ...... 70

Sedimentary Rock Agates ...... 73

TIMING OF AGATE FORMATION...... 76

CHAPTER 3: How Do You Find Agates? ...... 82

A POCKET FILLED IN...... 88

BANDING AND OTHER PATTERNS...... 90

TRANSLUCENCY...... 93

COLOR...... 95

SHAPE, SIZE, AND WEIGHT...... 106

LUSTER...... 109

HUSK...... 112

CONNECTIVE CHANNELS...... 118

PSEUDOBANDS...... 120

AGATE-WANT-TO-BE...... 122

Chert , Flint, and Jasper...... 122

Metamorphic Rocks ...... 126

Secondary Fills...... 127

Silicified Fossils...... 128

Other Agates -Want-To-Be...... 132

CARING FOR AND CLEANING AGATES...... 135

ASSESSING THE VALUE OF AGATES ...... 138

CHAPTER 4: What Are the Different Types of Agate? ...... 139

BOTRYOIDAL (GRAPE) AGATES...... 139

BRECCIATED (MOSAIC) AGATES...... 140

CANDY STRIPED AGATES ...... 141

CARNELIAN AGATES...... 142

CLOUD AGATES...... 144

CRAZY LACE AGATES...... 144

DENDRITIC AGATES...... 146

ENHYDRO (WATER-FILLED) AGATES ...... 150

EYE AGATES ...... 151

FIRE AGATES...... 156

FLAME AGATES...... 158

FLOATER BAND AGATES ...... 159

FORTIFICATION AGATES ...... 159

GEODE AGATES...... 161

IRIS (RAINBOW) AGATES...... 162

JASPER AGATES...... 165

MOSS AGATES...... 165

PAINTSTONE AGATES...... 168

PEELER AGATES...... 168

PLUME AGATES...... 170

POLYHEDROID AGATES...... 172

PSEUDOMORPH AGATES...... 173

RUIN AGATES...... 174

SAGENITE AGATES...... 175

SARDONYX...... 177

SEAM AGATES...... 178

SHADOW AGATES...... 180

STALK AGGREGATE AGATES...... 182

Thunder Egg Agates ...... 182

Tube Agates ...... 184

Water -Level Agates ...... 186

CHAPTER 5: Where Can You Find Agates?...... 187

A SELECTION OF UNITED STATES AGATES...... 187

California...... 190

Florida...... 191

Idaho...... 192

Iowa ...... 193

Kentucky...... 194

Michigan...... 196

Minnesota ...... 198

Missouri...... 200

Montana ...... 201

New Mexico...... 203

Oregon...... 204

South Dakota ...... 207

Texas...... 210

Wyoming...... 211

A SELECTION OF INTERNATIONAL AGATES ...... 212

Argentina...... 212

Australia...... 215

Botswana , Africa...... 216

Brazil...... 218

Canada...... 220

Caribbean ...... 223

China...... 225

Mexico...... 227

References...... 231

Index ...... 239

MUSEUM INFORMATION ...... 243

HOW TO VOTE FOR YOUR FAVORITE PHOTOgraph...... 244

INFORMATION ABOUT AGATE DVDS & OTHER PRODUCTS244

Rock hunting log ...... 245

CHAPTER 1 What Is An Agate?

A BASIC DESCRIPTION

One of the most intriguing forms of quartz produced by nature is the semi-precious gemstone, agate. It is a variegated form of chalcedony (pronounced kal-sed’-nee), which is a type of microcrystalline quartz made of silicon dioxide (SiO2).2 Microcrystalline means that the crystals are so small that they cannot be seen with the naked eye or with a normal optical microscope.3 In fact, the only way to see actual agate crystals is to use powerful technology such as transmission electron microscopy TEM or scanning electron microscopy SEM.4

Agates naturally develop when empty pockets or veins inside host rock fill in molecule-by-molecule and layer-by-layer as quartz microcrystals self-organize to form concentric bands or other patterns. Agates can be found in igneous, sedimentary, and metamorphic rocks and have been discovered on every continent.5 They can be collected from deserts, mountains, rivers, shorelines, gravel pits, prairies, and fields.

Agates are technically classified as sedimentary because they are deposited in empty pockets with silica from mineral-rich fluids or gels.6The colors and arrangement of microcrystals are influenced by changes in pressure, temperature, and mineral content that occur during the formation process.7 Unlike other gemstones, each agate is unique. Even slabs cut from the same specimen will vary.