FORD PREMIUM MOTOR OIL

Shell Overseas Services Ltd.Saudi Arabia / Safety Data Sheet

Issued: Jan. 2002

SDS No. SN05M007 / Shell Multigrade Super SJ 20W50

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Product name: / Shell Multigrade Super SJ 20W50
Product type: / 01.03.058 Four-stroke gasoline engine oil.
Supplier: / Shell Overseas Services Ltd.
Address: / P.O. Box 16996 Riyadh 11474 Saudi Arabia
Contact numbers:
Telephone:
Telex:
Fax: / 966-1-4774402
None
966-1-4789255
Emergency telephone number:
None / None

2. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation description: / 02.06.nnn Blend of highly-refined mineral oils and additives.
Dangerous components/constituents: / 02.08.SIP1010 May contain less than 1% (m/m) of a calcium sulphonate classified by the supplier as a skin sensitizer. 02.08.SIP1004 Other components are not expected to impart hazardous properties to the product.

3. HAZARDS IDENTIFICATION

Human health hazards: / 03.01.098 No specific hazards under normal use conditions. 03.02.035 Contains mineral oil for which an exposure limit for oil mist applies. 03.01.105 Prolonged or repeated exposure may give rise to dermatitis. 03.01.104 Used oil may contain harmful impurities and excessive or repeated skin contact may give rise to skin cancer.
Safety hazards: / 03.02.036 Not classified as flammable, but will burn.
Environmental hazards: / 03.03.016 Not readily biodegradable. 03.03.018 Expected to have a high potential to bioaccumulate.
Other information: / 03.04.001 Not classified as dangerous for supply or conveyance.

4. FIRST AID MEASURES

Symptoms and effects: / 04.01.041 Not expected to give rise to an acute hazard under normal conditions of use.
First Aid - Inhalation: / 04.03.008 In the unlikely event of dizziness or nausea, remove casualty to fresh air. 04.03.010 If symptoms persist, obtain medical attention.
First Aid - Skin: / 04.04.015 Remove contaminated clothing and wash affected skin with soap and water. 04.04.006 If persistent irritation occurs, obtain medical attention.
04.04.010 If high pressure injection injuries occur, obtain medical attention immediately.
First Aid - Eye: / 04.05.007 Flush eye with copious quantities of water. 04.05.004 If persistent irritation occurs, obtain medical attention.
First Aid - Ingestion: / 04.06.008 Wash out mouth with water and obtain medical attention. 04.06.002 DO NOT INDUCE VOMITING.
Advice to physicians: / 04.07.001 Treat symptomatically. 04.07.003 Aspiration into the lungs may result in chemical pneumonitis. 04.07.002 Dermatitis may result from prolonged or repeated exposure.

5. FIRE FIGHTING MEASURES

Specific hazards: / 05.01.033 Combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases, including carbon monoxide, oxides of sulphur, and unidentified organic and inorganic compounds.
Extinguishing media: / 05.02.006 Foam and dry chemical powder. Carbon dioxide, sand or earth may be used for small fires only.
Unsuitable extinguishing media: / 05.05.003 Water in a jet. 05.05.007 Use of Halon extinguishers should be avoided for environmental reasons.
Protective equipment: / 05.07.002 Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: / 06.01.001 Avoid contact with: 06.01.001A skin and 06.01.001B eyes.
Personal protection: / 06.02.002a Wear impermeable gloves and boots.
Environmental precautions: / 06.03.003 Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers. 06.03.008 Inform local authorities if this cannot be prevented.
Clean-up methods - small spillage: / 06.04.018 Absorb liquid with sand or earth. Sweep up and remove to a suitable, clearly marked container for disposal in accordance with local regulations.
Clean-up methods - large spillage: / 06.05.008 Prevent from spreading by making a barrier with sand, earth or other containment material. 06.05.009 Reclaim liquid directly or in an absorbent. 06.05.010 Dispose of as for small spills.

7. HANDLING AND STORAGE

Handling: / 07.01.051 When handling product in drums, safety footwear should be worn and proper handling equipment should be used. 07.01.052 Prevent spillages.
Storage: / 07.03.069 Keep in a cool, dry, well-ventilated place. 07.03.070 Use properly labelled and closable containers. 07.03.071 Avoid direct sunlight, heat sources, and strong oxidizing agents.
Storage temperature: / 07.04.001 0°C minimum to 07.04.002 50°C maximum.
Recommended materials: / 07.07.003A For containers or container linings, use: 07.07.001 mild steel or 07.07.009 high density polyethylene.
Unsuitable materials: / 07.08.003A For containers or container linings, avoid:
Other information: / 07.09.003 Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering control measures: / 08.01.SIP1001 Use local exhaust ventilation if there is a risk of inhalation of vapours, mists or aerosols.
Occupational exposure standards: / 08.02.004 Threshold limit values are given below. Lower exposure limits may apply locally:
Component name / Limit type / Value / Unit / Other information
Oil mist, mineral / 8-hour TWA / 5 / mg/m3 / ACGIH
15-min STEL / 10 / mg/m3 / ACGIH
Hygiene measures: / 08.03.SIP1001 Wash hands before eating, drinking, smoking and using the toilet.
Respiratory protection: / 08.04.021 Not normally required. 08.04.023 If oil mist cannot be controlled, a respirator fitted with an organic vapour cartridge combined with a particulate pre-filter should be used.
Hand protection: / 08.05.008 PVC or nitrile rubber gloves.
Eye protection: / 08.06.009 Wear safety glasses or full face shield if splashes are likely to occur.
Body protection: / 08.07.026 Minimise all forms of skin contact. 08.07.027 Wear overalls to minimise contamination of personal clothing. Launder overalls and undergarments regularly.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: / 09.01.007 Liquid at ambient temperature.
Colour: / 09.03.001 Amber/Brown
Odour: / 09.04.003 Characteristic mineral oil
Acidity/Alkalinity
Initial boiling point: / Not applicable
09.07.nnn > 320°C
Vapour pressure @ 40 Deg.C / 09.10.nnn < 0.1kPa at 15°C
Density @ 15 Deg C / 09.12.nnn 0.880
Kinematic viscosity @ 40 Deg. C / 09.13.nnn 67 cSt
Vapour density (air=1): / 09.15.nnn > 1
Pour point: / 09.16.nnn -33 Deg. C
Flash point: / 09.22.nnn 196 Deg C
Flammability limit - lower: / 09.26.nnn 1 % V/V
Flammability limit - upper: / 09.25.nnn 10% V/V
Auto-ignition temperature: / 09.27.nnn > 320°C
Solubility in water: / 09.31.009 Negligible
n-octanol/water partition coefficient: / 09.34.nnn Log Pow > 6 (typical)

10. STABILITY/REACTIVITY

Stability: / 10.01.001 Stable between 0 and 50 Deg. C
Conditions to avoid: / 10.02.011 Extremes of temperature and direct sunlight.
Materials to avoid: / 10.03.002 Strong oxidizing agents
Hazardous decomposition products: / 10.04.016 Hazardous decomposition products are not expected to form during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for assessment: / 11.01.001 Toxicological data have not been determined specifically for this product. 11.01.006 Information given is based on a knowledge of the components and the toxicology of similar products.
Acute toxicity - oral: / 11.02.006 LD50 expected to be above 2000 mg/kg
Acute toxicity - dermal: / 11.03.006 LD50 expected to be above 2000 mg/kg
Acute toxicity - inhalation: / 11.04.007 Not considered to be an inhalation hazard under normal conditions of use.
Eye irritation: / 11.05.005 Expected to be slightly irritant.
Skin irritation: / 11.06.006 Expected to be slightly irritant.
Respiratory irritation: / 11.07.004 If mists are inhaled, slight irritation of the respiratory tract may occur.
Skin sensitization: / 11.08.003 Not expected to be a skin sensitizer
Carcinogenicity: / 11.10.016 Product is based on mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. 11.10.017 Other components are not known to be associated with carcinogenic effects.
Mutagenicity: / 11.11.005 Not considered to be a mutagenic hazard.
Other information: / 11.14.SIP1001 Prolonged and/or repeated contact with this product can result in defatting of the skin, particularly at elevated temperatures. This can lead to irritation and possibly dermatitis, especially under conditions of poor personal hygiene. Skin contact should be minimised.
11.14.002 Used engine oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. 11.14.005 It is prudent to assume that prolonged or repeated exposure to used gasoline engine oils may cause skin cancer in man. 11.14.004 ALL used oil should be handled with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

Basis for assessment: / 12.01.001 Ecotoxicological data have not been determined specifically for this product. 12.01.006 Information given is based on a knowledge of the components and the ecotoxicology of similar products.
Mobility: / 12.02.027 Liquid under most environmental conditions. 12.02.005 Floats on water. 12.02.030 If it enters soil, it will adsorb to soil particles and will not be mobile.
Persistence/degradability: / 12.03.002 Not readily biodegradable. 12.03.015 Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment.
Bioaccumulation: / 12.04.003 Has the potential to bioaccumulate.
Ecotoxicity: / 12.10.009 Poorly soluble mixture. 12.10.010 Product is expected to be practically non-toxic to aquatic organisms, LC/EC50 > 100 mg/L. 12.10.011 May cause physical fouling of aquatic organisms.
12.10.012 (LC/EC50 expressed as the nominal amount of product required to prepare aqueous test extract)
Sewage treatment:

13. DISPOSAL CONSIDERATIONS

Waste disposal: / 13.02.012 Used or waste oil should be recycled or disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor. 13.02.014 The competence of the contractor to deal satisfactorily with used oil should be established beforehand. 13.02.016 Used or waste oil should not be allowed to contaminate soil or water.
Product disposal: / 13.03.013 As for waste disposal.
Container disposal: / 13.04.017 200 litre drums should be emptied and returned to the supplier or sent to a drum reconditioner without removing or defacing markings or labels.
13.04.018 Non-reusable small metal and plastic containers should be recycled where possible, or disposed of as domestic refuse.
Local legislation:

14. TRANSPORT INFORMATION

14.00.001 Not dangerous for conveyance under UN, IMO, ADR/RID and IATA/ICAO codes.

15. REGULATORY INFORMATION

EC Classification: / 15.02.001 Not classified as Dangerous under EC criteria
EINECS (EC): / 15.06.008 All components listed or polymer exempt.
TSCA (USA): / 15.10.005 All components in compliance.
Other information: / 15.14.002 For listing on other inventories, eg MITI (Japan), AICS (Australia) and DSL (Canada), please consult suppliers.

16. OTHER INFORMATION

Uses and restrictions: / 16.01.007 Lubricant for gasoline engines
Technical contact point: / Shehryar A. Khan
Technical contact number:
Telephone:
Telex:
Fax: / 966-1-4774402
None
966-1-4789255
SDS history: / 16.04.001 Edition No.: 0
16.04.002 First Issue: Jan. 2002
16.04.003

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