Safety Data Sheet
according to 1907/2006/EC, Article 31
Page1/6
Printingdate 26.03.2010 (DD.MM.YYYY)Revision: 26.03.2010
* 1Identification of substance:
·Productname: VarioChlorineFree-DPDF5,F10,25ml
·Catalognumber:251397Y, 251401Y, 251402Y
·Applicationofthesubstance/thepreparation:Reagent for water analysis
· Supplier:
YSI
1725 Brannum Lane
Yellow Springs, OH45387
USA
tel: +1 937-767-7241
· Informingdepartment:
· Emergencyinformation:
Chemtrec toll free (USA and Canada): (800) 424-9300
Chemtrec International Telephone Number: 001 703-527-3887 (Collect Calls Accepted)
* 2Hazards identification
·Hazarddesignation:void
·Informationpertainingtoparticulardangersformanandenvironment
Theproduct doesnot havetobelabelledduetothecalculationprocedureofthe"General Classificationguidelinefor
preparationsoftheEU"(1999/45/EC)inthelatest validversion.
·GHS label elements
Safety data sheet availableonrequest.
* 3Composition/information on ingredients
·Description:Mixturecontainsanorganicandorganiccompounds.
·Dangerouscomponents:CAS: 6283-63-2
EINECS: 228-500-6 / N,N-diethylbenzene-1,4-diammoniumsulphate
Xn,Xi; R 20/21/22-36 / ≤2.5%
Warning: 3.1.O/4,3.1.D/4,3.1.I/4,3.3/2
·REACH-Pre-registeredsubstances All componentsareREACHpre-registered.
·Additionalinformation Forthewordingofthelistedriskphrasesrefertosection16.
* 4First aid measures
·General informationInstantly removeany clothingsoiledby theproduct.
·AfterinhalationSupply freshair; consult doctorincaseofsymptoms.
·AfterskincontactInstantly rinse withwater.
(Contd.onpage2)
GB
Productname:VarioChlorineFree-DPDF5,F10,25ml
·Aftereyecontact
Rinseopenedeyeforseveral minutes(at least 10min)underrunningwater.
Seek immediate medical advice.
·After swallowing
Rinseout mouthandthendrink1-2glassesofwater.
Seek immediate medical advice.
·Thefollowingsymptomsmayoccur:
after inhalation:
allergic reactions irritations
Afterswallowingoflargeamounts:
mucous membrane irritation gastricpain
general feelingofsickness cramps
(Contd.ofpage1)
5Fire fighting measures
·Suitableextinguishingagents
CO2,extinguishingpowderorwaterjet.Fight largerfireswithwaterjet oralcohol-resistant foam.
·Specialhazardscausedbythematerial,its productsofcombustionorresultinggases:
Formationoftoxicgasesis possibleduringheatingorincaseoffire.
nitrogenoxides(NOx)
carbonmonoxideandcarbondioxide
Phosporusoxides(PxOx) sodium monoxide dipotassiumoxide
·Protective equipment:
Wearself-containedbreathingapparatus.
Wear full protective suit.
·Additionalinformation
Collect contaminatedfirefightingwaterseparately.It must not enterdrains.
Disposeoffiredebrisandcontaminatedfirefightingwaterinaccordance with official regulations.
6Accidental release measures
·Person-relatedsafetyprecautions: Wearprotectiveequipment.Keepunprotectedpersonsaway.
·Measuresforenvironmentalprotection:Donotallowproducttoreachsewagesystemorwaterbodies.
·Measures for cleaning/collecting:
Disposeofcontaminatedmaterialaswasteaccordingtoitem13.
Collect mechanically.
Ensure adequate ventilation.
·Additionalinformation:Nodangerousmaterialsarereleased.
* 7Handling and storage
·Handling
·Informationforsafehandling:Thoroughdedusting.
·Informationaboutprotectionagainstexplosionsandfires:
Substance/product is auto-extinguishing,but canburnwhencombinedwithflammablematerial.
·Storage
·Requirementstobemetbystoreroomsandcontainers:Storeincool location.
·Information about storage in one common storage facility: Storeawayfromoxidizingagents.
(Contd.onpage3)
GB
Productname:VarioChlorineFree-DPDF5,F10,25ml
·Furtherinformationaboutstorageconditions:
Protect fromheat anddirect sunlight.
Storeunderdryconditions.
Protectfromhumidityandkeepawayfromwater. Protectfromtheeffectsoflight.
·Recommendedstoragetemperature:20°C +/-5°C
(Contd.ofpage2)
* 8Exposure controls and personal protection
·Additional informationaboutdesignoftechnical systems: Nofurther data; see item7.
·Componentswithlimitvaluesthatrequire monitoring at the workplace:
Theproductdoesnotcontainanyrelevant quantities of materials with critical valuesthathavetobemonitoredatthe
workplace.
·Additionalinformation:The lists that were valid duringthe compilationwere usedas basis.
·Personal protective equipment
·General protective and hygienic measures
Washhandsduringbreaksandat theendofthework.
Donot eat,drinkorsmokewhile working.
·Breathingequipment: Usebreathingprotectionagainst theeffectsoffumes/dust/aerosol.
·Recommended filter device for short term use:Filter P1
·Protectionofhands:Preventiveskinprotectionby useofskin-protectingagents is recommended.
·Material ofgloves
nitrile rubber,NBR
Recommendedthickness ofthe material:≥ 0.11mm
·Penetrationtimeofglovematerial
Theexact breaktroughtimehastobefoundout by themanufactureroftheprotectiveglovesandhastobeobserved.
Value for the permeation: Level≥ 1(>10min)
·Eyeprotection:Safety glasses
·Bodyprotection:Protectiveworkclothing.
* 9Physical and chemical properties:
·Form:Powder
·Colour:White
·Odour:Odourless
·Meltingpoint/Meltingrange:Not determined
·Boilingpoint/Boilingrange:Not determined
·Flashpoint:Not applicable
·Dangerofexplosion:Product is not explosive.
·DensityNot determined
·Solubilityin / Miscibilitywith
Water:Soluble
·pH-value(10g/l)at20°C:6.3
·Solventcontent:
Organic solvents:0.0%
Solidscontent:100.0%
GB
(Contd.onpage4)
Productname:VarioChlorineFree-DPDF5,F10,25ml
(Contd.ofpage3)
*10Stability and reactivity
·Thermal decomposition / conditions to be avoided:Toavoidthermal decompositiondonot overheat.
·Materialstobeavoided:oxidizingagents
·Dangerousreactions Nodangerousreactionsknown
·Dangerousproductsofdecomposition:see chapter 5
*11Toxicological information
·Acutetoxicity:Quantitative data onthe toxicity ofthe preparationare not available.
·LD/LC50valuesthatarerelevantforclassification:6283-63-2N,N-diethylbenzene-1,4-diammoniumsulphate
Oral / LD50 / 497mg/kg(rat)
(MERCK)
·Primaryirritanteffect:
·ontheskin:DPD may cause allergic skinreaction
·ontheeye:Irritant effect.
·Sensitization:Sensitizing effect by skin contact ispossiblebyprolonged/repeated exposure.
·Additional toxicological information:
The product is not subject to classificationaccordingtothecalculationmethodoftheGeneral EC Classification Guidelines for
Preparations as issuedinthe latest version.
Whenusedandhandledaccordingtospecifications,theproductdoesnothaveanyharmfuleffectsaccordingtoourexperience andtheinformationprovidedtous.
The usual precautionary measuresshouldbeadheredtogeneralrulesforhandlingchemicals. Afterswallowingoflargeamounts:
disorderofelectrolyte balance
·CMReffects(carcinogenity,mutagenicityandtoxicityforreproduction)nodata available
*12Ecological information:
·Information about elimination (persistence and degradability):
·Otherinformation:
Quantitative data on the ecological effectofthisproductarenotavailable.
Thefollowingstatements refertotheindividual components.
·Behaviour in environmental systems:6283-63-2N,N-diethylbenzene-1,4-diammoniumsulphate
log P(o/w) / 2.24 (.)
·Mobility and bioaccumulationpotential:
Phosphatesand/ornitrogencompounds: may contributetotheeutrophicationofwatersupplies
·Ecotoxical effects:
·Remark: Toxicforfish: sulphates7g/l
·Bacterialtoxicity: sulphatestoxic2.5g/l
·Additional ecological information:
·General notes:
Waterhazardclass2(GermanRegulation)(Self-assessmentacc.VwVwSAnnex4):hazardousforwater.
Donotallowproducttoreachgroundwater,waterbodiesorsewagesystem.
·PBT assessments:nodata available
(Contd.onpage5)
GB
Productname:VarioChlorineFree-DPDF5,F10,25ml
·vPvB assessments: nodata available
(Contd.ofpage4)
13Disposal considerations
·Product:
·Recommendation
Handovertodisposersofhazardouswaste.
Mustnotbedisposedoftogether withhouseholdgarbage.Donotallowproducttoreachsewagesystem.
·Europeanwastecatalogue
160509 discardedchemicalsotherthanthosementionedin160506,160507or160508
·Uncleanedpackagings:
·Recommendation:Disposalmustbemadeaccordingtoofficialregulations.
·Recommendedcleaningagent:Water, if necessary with cleaning agent.
*14Transport information
·LandtransportADR/RID (cross-border)
·ADR/RID-GGVS/EClass:-
·MaritimetransportIMDG:
·IMDGClass:-
·Marinepollutant:No
·AirtransportICAO-TIandIATA-DGR:
·ICAO/IATAClass:-
·UN"Model Regulation":-
·Transport/Additional information: Notdangerousaccordingtothe above specifications.
*15Regulatory information
·DesignationaccordingtoECguidelines:
The product is not subject to classificationaccordingtothecalculationmethodsofthe "General Classification Guideline for
Preparations of the EC" as issuedinthe last version.
·Specialdesignationofcertainpreparations:
Safety data sheet availableforprofessional useronrequest.
·National regulations
·Informationaboutlimitationofuse:Not required.
*16Other information
Thesedataarebasedonourpresentknowledge.However,they shall not constitute a guaranteeforanyspecificproduct featuresandshall not establishalegally validcontractual relationship.
·RelevantR-phrases
20/21/22Harmful by inhalation,incontact withskinandifswallowed.
36Irritatingtoeyes.
·Abbreviationsandacronyms:
ADR:AccordeuropéensurletransportdesmarchandisesdangereusesparRoute(EuropeanAgreementconcerningtheInternationalCarriageofDangerous
GoodsbyRoad)
RID:Règlementinternationalconcernantletransportdesmarchandisesdangereusesparchemindefer(RegulationsConcerningtheInternationalTransportof
DangerousGoodsbyRail)
(Contd.onpage6)
GB
Productname:VarioChlorineFree-DPDF5,F10,25ml
IMDG:InternationalMaritimeCodeforDangerousGoods
IATA:InternationalAirTransportAssociation
IATA-DGR:DangerousGoodsRegulationsbythe"InternationalAirTransportAssociation"(IATA) ICAO:InternationalCivilAviationOrganization
ICAO-TI:TechnicalInstructionsbythe"InternationalCivilAviationOrganization"(ICAO) GHS:GloballyHarmonizedSystemofClassificationandLabellingofChemicals
LC50:Lethalconcentration,50percent
LD50:Lethaldose,50percent
·Sources
Data arise fromreference works andliterature.
NTP(National Toxicology Program)
IUCLID(InternationalUniformChemicalInformationDatabase)
·*Datacomparedtotheprevious version altered.
(Contd.ofpage5)
GB