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Chapter 4-3
What are the trends in the periodic table?
electron shielding
inner electrons shield the outermost electrons from the full charge of the nucleus
as a result outermost electrons are not held as close to the
nucleus
Atomic radius
Measure of the size of the atom
Increases as you move down a group; caused by the
addition of another main energy level from one period to the next
as n increases, the number of inner electrons increases,
electron shielding increases
for Li
nuclear charge = +3
effective nuclear charge (actual charge experienceds by the electrons) < +3
atomic radius decreases as you move across a period
from left to right within a period, each atom has one more
proton and one more electron than the element before it
additional electrons are going in the same main energy level
electron shielding remains constant
nuclear charge increases but the outer electrons are still in the 2nd energy level
outer electrons are attracted more strongly toward the nucleus resulting in smaller size
Ionization energy
Amount of energy needed to remove an outermost electron from a specific atom or ion in its ground state and in the gas phase
perioic trends in ionization energies are opposite those for
atomic size
decreasing atomic size
outermost electrons held more tightly to nucleus
increasing energy to remove outermost electrons
increasing ionization energy
increasing atomic size
outermost electrons held less tightly to nucleus
decreasing energy to remove outermost electrons
decreasing ionization energy
Electron affinity
Ability of an atom to attract and hold an added electron
Energy emitted upon the addition of an electron to an atom or group of atoms in the gas phase
decreasing atomic size
increasing nuclear charge
increasing electron affinity
increasing electron shielding
increasing atomic size
decreasing electron affinity
ionization energy and electron affinity are properties of isolated atoms
electronegativity
measure of the ability of an atom in a bond to attract
electrons to itself
same periodic trend as electron affinity