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WHMIS / PersonalProtectionEquipment / TDG(Ground)

Product identifier

Tradename:Vacuum Gas Oil

SDSNr:SDS-0028

Chemicaldescription:Gas oils(petroleum),lightvacuumCASNo:64741-58-8

EC No:256-059-9

Registration-No:Registrationdeadline notexpired.

Use:Usedintheproductionandformulationofcoatings,cleansingagents,rubber,gasolineandfuelproducts.Usedaslubrications,bindingagents,explosives,andforroadwork.

Companyidentification: FreepointCommodities, LLC

58CommerceRoad

Stamford,Ct.06902

E-Mailaddress(competent person):Lou Santore

LouSantore[]Emergencytelephonenumber:Withinthe U.S.or Canada:1800 4249300

Outside the U.S. and Canada: +1 703 527 3887(collectcallsaccepted)

MSDSprepared by:PaulePatterson,ENERCONServices, Inc.

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GHSClassification:

Acute toxicity(Inhalation) –Category4Aspiration Hazard–Category1.

Carcinogenicity–Category2

SpecificTargetOrgan Toxicity(Repeated Exposure)–Category2SkinIrritation –Category2

ChronicAquaticToxicity–Category2

GHSLABELELEMENTS

Symbol(s)

SignalWord

Danger

CLPHazardStatements:ENVIRONMENTALHAZARDS:

H411:Toxic toaquaticlifewithlong lasting effects.

HEALTHHAZARDS:

H304- Maybefatal if swallowedand entersairwaysH315- Causesskin irritation

H3326 –Harmfulifinhaled

H351 –Suspected ofcausing cancer

H373 –Maycause damagetoorgansthroughprolongedor repeatedexposures.H411-Toxic to aquatic life withlong lasting effects

CLPPrecautionarystatementsPrevention :

P261:Avoidbreathing mist, spray,vapors.

P280:Wearprotective gloves/protectiveclothing/eyeprotection/face protection.

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Storage:

P403+P233:Storein a well-ventilatedplace.Keep container tightlyclosed.

Response :

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.

P331:DoNOTinduce vomiting.

P332+P313;Ifskinirritation occursgetmedicaladviceor attention.

Disposal:

P501:Disposeofcontentsandcontainertoappropriatewastesiteorreclaimerinaccordancewithlocal,state,andnationalregulations.

Combustibleliquid.Spilledmaterialmaypresentaslipping hazard.Repeatedexposuremaycauseliver damageorfailure.Maycausephotosensitization.

Component / Product Identifiers / Percent / Classification according toDirective67/548/EEC
Gasoils(petroleum),lightvacuum / CASNo:64741-58-8
ECNo: 256-059-9 / 100 / Xn;R65Xn;R20
Carc.Cat.3;R40Xi;R38
N;R51/53
Component / Product Identifiers / Percent / Classificationaccording toRegulation(EC) No.
1272/2008[CLP]
Gasoils(petroleum),lightvacuum / CASNo:64741-58-8
ECNo: 256-059-9 / 100 / Asp.Tox.1,H304Carc.2,H351
SkinIrrit.2,H315
AcuteTox.4(Inhalation),H332STOTRE2,H373
AquaticChronic2,H411
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FirstAid:Eyes

Incaseofcontactwitheyes,immediatelyflushwithclean,low-pressurewaterforatleast15 min. Holdeyelidsopentoensure adequate flushing.Seekmedicalattention.

FirstAid:Skin

Removecontaminatedclothing.Rinsethoroughlyforatleast15minutes.Washcontaminatedareasthoroughlywithsoapandwaterorwaterlesshandcleanser.Obtainmedicalattentionifirritation or rednessdevelops.

FirstAid:Ingestion

DONOTINDUCEVOMITING.Donotgiveliquids.Obtainimmediatemedicalattention.Ifspontaneousvomitingoccurs,positionvictimforward,withheadbetweenknees,toreducetheriskofaspiration.Monitor forbreathingdifficulties.Smallamountsofmaterialwhichenter the mouth should berinsed outuntil the tasteisdissipated.

FirstAid:Inhalation

Removepersontofreshair.Ifpersonisnotbreathing,provideartificialrespiration.Ifnecessary,provideadditionaloxygenoncebreathingisrestorediftrainedtodoso.Seekmedicalattention immediately.

GeneralFire Hazards

See Section9for FlammabilityProperties.

Vaporscanreadilyformexplosivemixtureswithair.Heavierthanairvaporscanflowalongsurfacestoignitionsourcesandflashback.Useself-containedbreathingapparatusinenclosedareas.Formassivefires,useunmannedhoseholdersormonitornozzles.Ifthisisimpossible,withdrawfromareaandletfireburn.Always stayawayfromtanksengulfedinfire.

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UnusualFire orExplosionHazards

Keepawayfromheat,sourcesofignitionandstrongoxidizers.Thismaterialcanreactviolentlywithoxidizing agents.

HazardousCombustionProducts

Fumes,smoke,carbonmonoxide,sulfuroxides,aldehydesandotherdecomposition products,inthecaseofincompletecombustion.

ExtinguishingMedia

SMALLFIRES:AnyextinguishersuitableforClassBfires,drychemical,CO2,firefightingfoam,orgaseousextinguishingagent.Watermaysplashandspreadflamingliquid.Avoidspreadingburningliquidwithwaterusedforcoolingpurposes.Donotflushdownpublicsewers.Theuseofself-containedbreathingapparatusandprotectiveclothingisrecommendedforfirefighters.Avoidinhalationofvapors.

LARGEFIRES:Waterspray,fogorfirefightingfoam.Watermaybeineffectiveforfightingthefire,butmaybeusedtocoolfire-exposedcontainers.Watermaysplashandspreadflamingliquid.Avoidspreadingburningliquidwithwaterusedfor cooling purposes.Donotflushdownpublicsewers. Theuse of self- containedbreathingapparatusandprotectiveclothingisrecommendedforfirefighters.Avoidinhalationofvapors.

UnsuitableExtinguishingMedia

Waterdirectedatsource.

FireFightingEquipment/Instructions

Firefightingactivitiesthatmayresultinpotentialexposuretohighheat,smokeortoxicby-productsofcombustionshouldrequireNIOSH/MSHA-approvedpressure-demandself-containedbreathingapparatuswithfullfacepieceandfullprotective clothing.Isolate area aroundcontainer involvedinfire.

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Cooltanks,shells,andcontainersexposedtofireandexcessiveheatwithwater.Formassivefirestheuseofunmannedhoseholdersormonitornozzlesmaybeadvantageoustofurtherminimizepersonnelexposure.Majorfiresmayrequirewithdrawal,allowingthetanktoburn.Largestoragetankfirestypicallyrequirespeciallytrainedpersonnelandequipmenttoextinguishthefire,oftenincludingtheneedforproperlyappliedfirefightingfoam.

RecoveryandNeutralization

Danger,Flammable,eliminateallignitionsources.Equipmentusedinspillcleanupmustbegroundedtopreventsparking.Prevententryintowaterways,sewers,andconfinedareas.Carefullycontainandstopthesourceofthespill,ifsafetodoso.

Materials andMethodsforClean-Up

Takeupwithsandor other oilabsorbingmaterials.Carefullyshovel, scooporsweepupintoa waste container,sealtightlyfor proper disposal or reclamation.

EmergencyMeasuresSmallSpills:

Evacuatenonessentialpersonnelandremoveorsecureallignitionsources.Consider winddirection; stayupwindanduphill,ifpossible.Evaluatethe directionofproducttravel,diking,sewers,etc.toconfirmspillareas.Productmayreleasesubstantialamountsofflammablevaporsandgases(e.g.,methane,ethane,andpropane),atorbelowambienttemperaturedependingonsourceandprocessconditionsand pressure.

LargeSpills:

Isolatethehazardareaatleast150feetinalldirectionsandrestrictentrytounnecessarypersonnel.Shutoffsourceofleakonlyifitcanbedonesosafelyordikeandcontainthespill.Wearappropriaterespiratorandprotectiveclothing.

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Waterfogmaybeusefulinsuppressingvaporcloudcontainrun-off.Removewithvacuumtrucks.Soakupresiduewithsandorothersuitablematerial,placeincontainersforproperdisposal.Flushwithwateranddisposalofflushingsolutionsasabove.Local,stateandfederaldisposalregulationsmustbefollowed.

PersonalPrecautions andProtectiveEquipment

Responseandclean-upcrewsmustbeproperlytrainedandmustutilizeproperprotectiveequipment(seeSection 8).

EnvironmentalPrecautions

Protectbodiesofwaterbydiking,absorbents,orabsorbentboom,ifpossible.Donotflushdownsewer or drainagesystems,unlesssystemisdesignedandpermittedtohandlesuchmaterial.Theuseoffirefightingfoammaybeusefulincertainsituationstoreducevapors.Theproperuseofwaterspraymayeffectivelydisperseproductvaporsortheliquiditself,preventingcontactwithignitionsourcesorareas/equipmentthatrequireprotection-donotdischargesolidwater streampatternsinto theliquidresulting insplashing.

Preventionof SecondaryHazards

None

HandlingProcedures

Handleasaflammableliquid.Keepawayfromheat,sparks,andopenflame!Electricalequipmentshould be approved forclassifiedarea.

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Donot getineyes,on skinoronclothing.Donot breathevapors,mistsor fumes.Wearprotectiveequipmentdescribedinsection8ifexposureconditionswarrant.Useonlywithadequateventilation.

StorageProcedures

Keepawayfromflame,sparks,excessivetemperatures,staticelectricity,pilotlights,andotherignitionsources.Useapprovedventedcontainers.Keepcontainersclosedandclearlylabeled.Emptyproductcontainersorvesselsmaycontainexplosivevapors.Donotpressurize,cut,heat,weldorexposesuchcontainers to sourcesofignition.

Storeinawell-ventilatedarea.ThisstorageareashouldcomplywithNFPA30"FlammableandCombustibleLiquidCode".Avoidstoragenearincompatiblematerials.ThecleaningoftankspreviouslycontainingthisproductshouldfollowAPIRecommendedPractice(RP)2013"CleaningMobileTanksInFlammableandCombustibleLiquidService"andAPIRP2015"CleaningPetroleumStorageTanks."

Incompatibilities

Keep awayfrom strong oxidizers andstrongacids.

Component ExposureLimits

Gasoils(petroleum),lightvacuum(64741-58-8)
OSHAPEL / 5mg/m3
ACGIHTLV / 5mg/m3

EngineeringMeasures

Useadequateventilationtoprovideexplosionproofventilationto meetTLVrequirementsinenclosedworkareas.Keepvapor concentrationsofthisproductbelowoccupationalexposure and flammabilitylimits,particularlyinconfinedspaces.Emergency eyewash fountainsand safetyshowersshould beavailableinthe immediatevicinityofanypotentialexposure.

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PersonalProtectiveEquipment:Respiratory

ANIOSH/MSHA-approvedair-purifyingrespiratorwithorganicvaporcartridgesorcanistermaybepermissibleundercertaincircumstanceswhereairborneconcentrations(forexposuresoverTLVupto1000ppm)areormaybeexpectedtoexceedexposurelimitsorforodororirritation.Protectionprovidedbyair-purifying respiratorsislimited.

Useapositivepressure,air-suppliedrespiratorifthereisapotentialforuncontrolledrelease,exposurelevelsarenotknown,inoxygen-deficientatmospheres,oranyothercircumstancewhereanair-purifyingrespiratormaynotprovideadequate protection.

Employeesengagedinhandlingoperationsinvolvingbenzenemustbeprovidedwith,andrequiredtowearanduse,ahalf-maskfilter-typerespiratorfordusts,mists,andfumes.Arespiratoraffordinghigherlevelsofprotectionthanthisrespiratormaybesubstituted.

PersonalProtectiveEquipment:Hands

Glovesconstructed ofnitrileor neopreneare recommended.

PersonalProtectiveEquipment: Eyes

Safetyglassesorgogglesarerecommendedwherethereisapossibilityofsplashing or spraying.

PersonalProtectiveEquipment: SkinandBody

ChemicalprotectiveclothingsuchasofE.I.DuPontTyChem®,Saranex®orequivalentrecommendedbasedondegreeofexposure.Note:Theresistanceofspecificmaterialmayvaryfromproducttoproductaswellaswithdegreeofexposure.Consultmanufacturer specificationsforfurther information.

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HygieneMeasures

Emergencyeyewashcapabilityshouldbeavailableinthenearproximitytooperationspresentingapotentialsplashexposure.Usegoodpersonalhygienepractices.Avoidrepeatedand/orprolongedskinexposure.Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donotuseasacleaningsolventontheskin.Donotusegasolineorsolvents(naphtha,kerosene,etc.)forwashingthisproductfromexposedskin areas.Waterless handcleanersareeffective.

Promptlyremovecontaminatedclothingandlaunderbeforereuse.Usecarewhenlaunderingtopreventtheformationofflammablevaporswhichcouldigniteviawasheror dryer.Consider the needto discardcontaminatedleather shoesandgloves.

Appearance: / Colorless / Odor: / Characteristicheavy,hydrocarbonodor
PhysicalState: / Liquid / pH: / ND
VaporPressure: / ND / VaporDensity: / ND
BoilingPoint: / AP273-755°F / MeltingPoint: / ND
Solubility(H2O): / Negligible / SpecificGravity: / ND
EvaporationRate: / ND / VOC: / ND
Octanol/H2OCoeff.: / ND / FlashPoint: / 142°F
FlashPointMethod: / TCC / UpperFlammabilityLimit (UFL): / 6.5%
LowerFlammabilityLimit (LFL): / 1.0% / BurningRate: / ND
AutoIgnition: / >536°F
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ChemicalStability

This isastable material.

HazardousReactionPotential

HazardousPolymerizationwill not occur.

ConditionstoAvoid

Avoid high temperatures, open flames, sparks, welding, smoking and otherignitionsources.

Incompatible Products

Keep awayfrom strong oxidizers andstrongacids.

HazardousDecompositionProducts

Carbonmonoxide,carbondioxideandnon-combustedhydrocarbons(smoke),sulfur oxides,and other decomposition products.

AcuteToxicity

A:GeneralProduct Information

May be Fatal or Harmful if swallowed and enters airways.Occupationalexposureto thesubstanceormixturesmaycause adverseeffects.

B:ComponentAnalysis- LD50/LC50

Gasoils(petroleum),lightvacuum(64741-58-8))

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OralLD50>2000mg/kg (Rat)DermalLD50>5000 mg/kg (Rabbit)Inhalation LC50 4.1 mg/l/4hr(RAT)

PotentialHealthEffects: Skin ContactProperty

Causesskinirritation.

PotentialHealthEffects: EyeContact Properties

NotClassified.

PotentialHealthEffects: Inhalation

Maybefatal ifswallowedand entersairways.

Germ cellMutagenicity:

NotClassified.

Carcinogenicity

A:GeneralProduct Information

Maycausecancer.

Eco toxicity

A:GeneralProduct Information

Keepoutofsewers,drainageareasandwaterways.Reportspillsandreleases,as applicable,under local,State,andFederalregulations.

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B:ComponentAnalysis- Ecotoxicity-AquaticToxicity

Naphtha(petroleum),catalyticreformed(68955-35-1) / Conditions
LC50fishes / 21mg/l96hours
LC50other aquaticorganisms / >1000ppm 40hours
EC50Daphnia / >5.3ml/l48hours
NOEC(acute) / 0.2mg/l 21 days
NOEC(chronic) / 0.083mg/l 14 days
ErC50(algae) / 3.1mg/l 72hours

Substance isnotconsideredreadilybiodegradable.Containsconstituentswiththepotential to bio accumulate.Maybedangerousifitenterswater intakes.

Notifylocalhealthand wildlifeofficials.Notifyoperatorsofnearbywater intakes.

Waste DisposalInstructions

SeeSection7forHandlingProcedures.SeeSection8forPersonalProtectiveEquipmentrecommendations.

Thismaterialanditscontainermustbe disposedofin asafeway.

It istheresponsibilityof theusertodetermine ifdisposalmaterialishazardousaccording to federal,state and localregulations.

It istheresponsibilityof theusertodetermine ifdisposalmaterialishazardousaccording to federal,state and localregulations.

Disposalof ContaminatedContainersorPackaging

Disposeofcontents/container inaccordance withlocal,state,and federalregulations.

DisposalRegulatoryRequirements:

Recoverednon-usable materialisregulatedbytheUSEPAasahazardouswasteduetoitsignitibilitycharacteristics(D001) anditsbenzenecontent(D018).

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ContainerCleaningandDisposal:“Empty”ContainerWarning:

“Empty” containersretainproductresidue (liquidand/or vapor) andcanbedangerous.DONOTPRESSURIZE,CUT,WELD, BRAZE,SOLDER,DRILL,GRIND, OR EXPOSESUCHCONTAINERSTOHEAT,FLAME,SPARKS,STATICELECTRICITY, OR OTHER SOURCESOF IGNITION.THEYMAYEXPLODEANDCAUSEINJURYOR DEATH.

DOTInformation:

ShippingName:ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.

UN #:3082

HazardClass:9-Packing -III

Placard:

Landtransport(ADR/RID):ADR

14.1UNnumber:3082

14.2UNproper shipping name:ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.

14.3Transporthazardclass(es): 9

14.4Packing group : IIIDanger label(primaryrisk) : 9Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes

RID

14.1UNnumber:1268

14.2UNproper shipping name:ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.

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14.3Transporthazardclass(es): 9

14.4Packing group : IIIDanger label(primaryrisk) : 9Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes Subsidiaryclass/Division:6.1

ComponentAnalysis

USARight-to-Know-State

Tracecomponentsappearononeormoreofthefollowingstatehazardoussubstanceslists.Somecomponents(includingthosepresentonlyintracequantities,andthereforenotlistedinthisdocument)maybeincludedontheRightToKnowlistsofotherU.S.states.Thereader isthereforecautionedto contacthis or her FreepointCommoditiesrepresentative forfurther U.S.State RightTo Knowinformation.

Component / CAS#/EC # / NJ / PA
Gasoils(petroleum),lightvacuum / CASNo:64741-58-8
ECNo: 256-059-9 / NO / YES

CanadianRegulations- Federaland ProvincialCanadianFederalWHMISIDL

ThefollowingcomponentsareidentifiedundertheCanadianHazardousProductsActIngredientDisclosureList:

Component / CAS#/EC #
Gasoils(petroleum),lightvacuum / CASNo:64741-58-8
ECNo: 256-059-9 / 1%(Englishitem1224,FrenchItem977)(relatedtoOil,mineral)

WHMISClassification

WorkplaceHazardousMaterialsInformationSystems(WHMIS):ThisproducthasbeenclassifiedinaccordancewiththehazardcriteriaoftheCanadianControlledProductRegulations(CPR),andtheMSDScontainsall of theinformationrequiredbythe

Controlled ProductsRegulations.WHMISClassD2A:Carcinogen

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WHMISClassD2B:Materialcausing other toxiceffects.

CanadianProvincialRegulations

Federal,provincialorlocalregulationsmayapplytospillsorotheremissions.Checkindividualprovincialandlocalrequirements.

DISCLAIMEROFLIABILITY:Beforeusingthisproductinanynewprocessorexperiment,a thoroughmaterialcompatibilityand safetystudyshouldbe carriedout.

Thisdocumentisgeneratedforthepurposeofdistributinghealth,safety,andenvironmentaldata.

InformationiscorrecttothebestofourknowledgeatthedateoftheSDSpublication.Itisnotaspecificationsheetnorshouldanydisplayeddatabeconstruedasaspecification.

Theinformationonthiswasobtainedfromsourceswhichwebelievearereliable.However,theinformationisprovidedwithoutanywarranty,expressedorimplied,regardingitscorrectness.Someinformationpresentedandconclusionsdrawnhereinarefromsourcesotherthandirecttestdataonthesubstanceitself.Theconditionsormethodsofhandling,storage,useanddisposaloftheproductarebeyondourcontrolandmaybebeyondourknowledge.Forthisandotherreasons,wedonotassumeresponsibilityandexpresslydisclaimliabilityforloss,damage,orexpensearisingoutoforinanywayconnectedwithhandling,storage,use,ordisposalofthisproduct.Iftheproductisusedasacomponentinanotherproduct,thisSDSinformationmaynotbeapplicable.