The Nature and Structure of Matter
- Matter - anything that has mass and occupies space.
- States of Matter: Solid, Liquid, Gas, Plasma
- Particle arrangement:
- Solids: closely spaced, little movement & energy, doesn't change shape.
- Liquids: farther spaced, more movement & energy, changes shape.
- Gas: farthest apart, greatest movement and energy, changes shape.
- Crystalline and Noncrystalline (amorphous) solids
- Examples of Physical Properties (observable / measurable characteristics) of Matter:
- Hardness - firmness of object.
- Malleability - ability to be worked into different shapes.
- Ductility - ability to be drawn into a wire.
- Conductivity - ability to carry heat / electricity.
- Boiling point - temp. at which liquid turns to gas.
- Freezing point - temp. at which liquid turns to solid.
- Melting point – temp. at which solid turns to liquid.
- pH –measure of the hydronium ion concentration of a solution.
- Viscosity – resistance to flowing.
- Sensory characteristics: color, taste, smell, luster (shine of substance), texture.
- Chemical Properties of Matter (changes / reactions with other substances):
- Rust
- Burn
- React with other substances.
- Physical / Chemical Changes:
- Physical Changes: affects appearance only.
1. Signs of physical change:
- Size or shape changes.
- State changes - particles are rearranged:
- Types of state changes:
- Liquid to a gas: evaporation
- Gas to a liquid: condensation
- Solid to a liquid: melting
- Liquid to a solid: freezing
- Gas to a solid: deposition.
- Solid to a gas: sublimation
- Remember, due to conservation laws: mass before change = mass after change.
- Chemical changes: - affects appearance AND composition (due to rusting, burning, or reacting)
- New substance is formed with different chemical properties.
- Signs of a chemical change:
- Heat, light, or energy is given off.
- Chemical color change.
- Gas is given off.
- Density – physical property of matter determined by an object’s mass (matter) in relation to its volume.
- More mass in same volume = more density.
- More volume in same mass = less density.
Example:
CarCrushed car
* greater volume* less volume
* less density* greater density
- Formula:
D = M / vD = density (g/mL, kg/L, g/ cm3)
m = D x vm = mass (g, kg, cg)
v = m / Dv = volume (mL, L, cm3)
1. D = m / v2. m = d x v
D = 15 kg / 5 cm3 m = 6 g/mL x 3 mL
D = 3 kg/cm3 m = 18 g
- Molecular Structure of Elements:
- Atom – smallest particle of an element with the same properties of the element.
- Element – consists of identical atoms.
- Molecule – atoms that are chemically joined, and the smallest part of a compound that still has properties of that compound.
- Compound – consists of identical molecules.
- Molecular structure of compounds (chemical combination):
- example: FeS2 (Iron disulfide) compound – fool’s gold.
- The smallest piece of the above compound is one molecule of FeS2 (one atom of Fe and two atoms of S).
- Iron and Sulfur have properties different than Iron disulfide.
- Compounds can ONLY be separated by chemical means.
- Molecular Structure of Mixtures (physical combination):
- Mixture – consists of substances that are NOT chemically bonded. It can be any combination of elements or compounds. Ex: gold jewelry is mixture of Au, Cu, and Ag.
- Mixtures can be separated by physical means:
- by hand
- by heating to different melting points
- by density (centrifuge)
- by evaporation
- by use of magnet
- by distillation
- by chromatography
- by solubility of a substance
- Solution – A mixture in which the particles are evenly distributed throughout.
- types:
- gaseous solutions (air)
- liquid solutions (sugar water, tea)
- solid solutions (steel, 14K gold)
- Solute – substance being dissolved. (instant tea mix)
- Solvent – substance dissolving the solute. (water for instant tea mix)
- Saturated solution – solution that has dissolved all the solute it can hold at a given temperature.
- Behavior / Uses of Some States of Matter:
- Behavior of Gases:
- Pressure – amount of force exerted per unit of area. P = F / A
- Units of pressure = Pa (pascal) or kPa
- 1 Pa = 1 N / m2
- Earth’s atmosphere exerts pressure on everything
- Boyle’s Law – If volume of gas is decreased, pressure is increased when temperature is constant. (balloon example)
- Charles’s Law – The volume of a gas increases with increase in temp. if pressure is constant. (hot air balloon example)
- Uses of Fluids:
- Bouyancy – ability of a fluid (liquid or gas) to exert an upward force on an object immersed in it.
- Archimedes’ Principle – buoyant force on an object in a fluid is equal to the weight of the fluid displaced by the object. (boat in water example)
- Pascal’s Principle – pressure applied to a fluid is transmitted unchanged throughout the fluid (toothpaste tube, hydraulics example)
- Bernoulli’s Principle – as the velocity of a fluid increases, the pressure exerted by the fluid decreases. (airplane wings, shower curtain examples)