المحاضرة الثانية
The identification of lattice planes
The spacing of the planes of lattice points in a crystal is an important quantitative
aspect ofits structure. However, there are many different sets of planes (Fig. 1), andwe need to be able to label them. Two-dimensional lattices are easier to visualize thanthree-dimensional lattices, so we shall introduce the concepts involved by referringto two dimensions initially, and then extend the conclusions by analogy to threedimensions.
(a) The Miller indices
Consider a two-dimensional rectangular lattice formed from a unit cell of sides a, b (as in Fig. 1). Each plane in the illustration (except the plane passing through the origin) can be distinguished by the distances at which it intersects the a and b axes. One way to label each set of parallel planes would therefore be to quote the smallest intersection distances. For example, we could denote the four sets in the illustration as (1a,lb), (1/2a, 1/3b), (-1a, lb), and (∞a,lb). However, if we agree to quote distances along the axes as multiples of the lengths of the unit cell, then we can label the planes more simply as (1,1), (1/2, 1/3), (-1,1), and (∞,1). If the lattice in Fig. 1 is the top view of a three-dimensional orthorhombic lattice in which the unit cell has a length c in the z- direction, all four sets of planes intersect the z-axis at infinity. Therefore, the full labels are (1,1,∞), (1/2,1/3,∞), (-1,1,∞), and (∞,1,∞).
The presence of fractions and infinity in the labels is inconvenient. They can be
eliminated by taking the reciprocals of the labels. As we shall see, taking reciprocals turns out to have further advantages. The Miller indices, (hkl), are the reciprocals of intersection distances (with fractions cleared by multiplying through by an appropriate factor, if taking the reciprocal results in a fraction).
The Miller indices for the four sets of planes in Fig. 1 are therefore (1l0), (230), (110), and (010). Figure 2 shows a three dimensional representation of a selection of planes, including one in a lattice with non-orthogonal axes. The notation (hkl) denotes an individual plane. To specify a set of parallel planes we use the notation {hkl}. Thus, we speak of the (110) plane in a lattice, and the set of all {110} planes that lie parallel to the (110) plane. A helpful feature to remember is that, the smaller the absolute value of h in {hkl}, the more nearly parallel the set of planes is to the a axis (the {h00} planes are an exception). The same is true of k and the b axis and I and the c axis. When h = 0, the planes intersect the a axis at infinity, so the {0kl} planes are parallel to the a axis. Similarly, the {h01} planes are parallel to b and the {hk0} planes are parallel to c.
Fig. 1 Some of the planes that can be drawn through the points of a rectangular space lattice and their corresponding Miller indices (hkl): (a) (110), (b) (230), (c) (110), and (d) (010).
Fig. 2 Some representative planes in three dimensions and their Miller indices. Note that a 0 indicates that a plane is parallel to the corresponding axis, and that the indexing may also be used for unit cells with non-orthogonal axes.
(b) The separation of planes
The Miller indices are very useful for expressing the separation of planes. The separation of the {hk0} planes in the square lattice shown in Fig. 3 is given by
1/d2hkl =( h2+k2 ) /a2 or dhkl = a / (h2 + k2)1/2
By extension to three dimensions, the separation of the {hk1} planes of a cubic lattice is given by:
1/d2hkl =( h2+k2+l2 ) /a2 or dhkl = a / (h2 + k2+l2)1/2
The corresponding expression for a general orthorhombic lattice is the generalization of this expression:
1/d2hkl =( h2/a2 + k2/b2 + l2/c2)
Fig. 3 The dimensions of a unit cell and their relation to the plane passing through the lattice points.
Fig.1.12 The separation of the {220} planes is half that of the {110} planes.
In general, (the separation of the planes {nh,nk,nl} is n times smaller than the separation of the {hkl} planes).
Example 1 Using the Miller indices
Calculate the separation of (a) the {123} planes and (b) the {246} planes of an
orthorhombic unit cell with a = 0.82 nm, b = 0.94 nm, and c = 0.75 nm.
Answer
1/d2hkl =( h2/a2 + k2/b2 + l2/c2)
Hence, d123 = 0.21 nm. It then follows immediately that d246 is one-half this value, or 0.11 nm.
Self-test 1 Calculate the separation of (a) the {133} planes and (b) the {399}
planes in the same lattice. [0.19 nm, 0.063 nm]