Tarlok Singh Banipal* and Ashwani Kumar Sood
Supplementary Material
Effect of hydrophobicity and temperature on the interactions in the mixed micelles of triblock polymers [(EO76PO29EO76) and (EO19PO69EO19)] with monomeric and gemini surfactants
Tarlok Singh Banipal* and Ashwani Kumar Sood
Department of Chemistry, Guru Nanak Dev University, Amritsar - 143 005 (Punjab), India.
*Corresponding Author: (Tarlok Singh Banipal)
Phone Number: +91 (0183) 2258802-09 Ext. 3319 Fax Number: +91 (0183) 2258819-20
Table S1 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), CMC and surface concentration ratio (Cm/C20) and surface pressure at CMC (CMC) of the binary mixtures of F68 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 308.15 K
/ Cm(mmol·dm-3) / Ci
(mmol·dm-3) / max*106 (mol·m-2) / Amin
(Å2·molecule-1) / Aidmin
(Å2·molecule-1) / Cm/
C20 / CMC
(mN·m-1)
DTAB
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.554 / 0.625 / 2.37 / 070.00 / 111.84 / 1.84 / 31.68
0.356 / 0.621 / 0.769 / 3.27 / 050.73 / 111.96 / 2.48 / 30.50
0.480 / 0.772 / 0.992 / 4.30 / 038.54 / 112.08 / 3.78 / 30.49
0.625 / 0.964 / 1.324 / 4.15 / 039.95 / 113.07 / 4.99 / 31.72
0.787 / 1.233 / 2.162 / 3.54 / 046.91 / 114.05 / 4.89 / 33.20
0.903 / 2.584 / 4.028 / 2.99 / 055.49 / 114.79 / 4.94 / 31.09
1.000 / 15.939 / 15.939 / 1.35 / 122.29 / 2.64 / 27.57
TTAB
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.588 / 0.610 / 2.29 / 072.44 / 113.91 / 1.62 / 31.73
0.356 / 0.692 / 0.733 / 2.67 / 062.15 / 114.14 / 1.85 / 32.29
0.480 / 0.802 / 0.915 / 2.84 / 058.26 / 115.52 / 2.17 / 33.18
0.625 / 0.951 / 1.152 / 2.23 / 074.41 / 117.36 / 2.48 / 31.10
0.787 / 1.354 / 1.627 / 1.55 / 106.92 / 119.66 / 2.96 / 32.41
0.903 / 2.034 / 2.441 / 1.31 / 125.83 / 122.19 / 2.93 / 31.43
1.000 / 3.970 / 3.970 / 1.24 / 133.01 / 2.57 / 29.07
CTAB
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.432 / 0.564 / 1.68 / 098.76 / 117.62 / 1.53 / 30.22
0.356 / 0.481 / 0.613 / 1.33 / 124.47 / 119.95 / 1.93 / 30.32
0.480 / 0.532 / 0.664 / 1.78 / 092.82 / 123.93 / 2.37 / 30.76
0.625 / 0.614 / 0.717 / 1.75 / 094.63 / 126.58 / 2.82 / 30.75
0.787 / 0.684 / 0.788 / 1.35 / 122.20 / 130.23 / 1.66 / 30.25
0.903 / 0.728 / 0.850 / 1.51 / 109.82 / 133.55 / 1.24 / 28.20
1.000 / 0.912 / 0.912 / 1.16 / 143.17 / 2.37 / 28.87
10-2-10
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.551 / 0.618 / 2.42 / 068.60 / 111.30 / 1.43 / 31.56
0.356 / 0.642 / 0.745 / 2.62 / 063.32 / 111.71 / 1.80 / 31.75
0.480 / 0.816 / 0.946 / 2.95 / 056.28 / 112.51 / 1.80 / 31.96
0.625 / 1.052 / 1.228 / 2.07 / 080.01 / 113.01 / 2.47 / 33.25
0.787 / 1.581 / 1.907 / 2.17 / 076.23 / 114.12 / 3.78 / 33.23
0.903 / 2.713 / 3.055 / 1.71 / 096.93 / 115.13 / 6.11 / 32.43
1.000 / 6.500 / 6.500 / 1.38 / 120.06 / 6.36 / 32.30
12-2-12
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.594 / 0.570 / 2.32 / 071.48 / 112.28 / 2.05 / 31.59
0.356 / 0.602 / 0.625 / 2.33 / 070.97 / 113.57 / 2.60 / 32.69
0.480 / 0.647 / 0.679 / 2.66 / 062.24 / 115.28 / 3.06 / 33.34
0.625 / 0.712 / 0.745 / 1.92 / 086.10 / 116.85 / 3.86 / 33.20
0.787 / 0.766 / 0.830 / 1.89 / 087.61 / 119.00 / 3.90 / 32.90
0.903 / 0.847 / 0.910 / 1.85 / 089.33 / 120.71 / 5.46 / 32.80
1.000 / 0.990 / 0.990 / 1.33 / 124.29 / 6.68 / 21.98
14-2-14
0.000 / 0.533 / 0.533 / 1.50 / 110.20 / 1.46 / 31.48
0.156 / 0.307 / 0.360 / 1.77 / 093.52 / 110.63 / 1.53 / 31.06
0.356 / 0.238 / 0.269 / 2.08 / 079.51 / 110.80 / 1.45 / 31.11
0.480 / 0.196 / 0.216 / 2.16 / 076.57 / 110.89 / 1.75 / 31.33
0.625 / 0.158 / 0.185 / 1.62 / 102.33 / 110.96 / 2.02 / 32.47
0.787 / 0.137 / 0.158 / 1.65 / 100.49 / 111.00 / 2.49 / 32.56
0.903 / 0.131 / 0.143 / 1.88 / 088.31 / 111.04 / 3.85 / 32.45
1.000 / 0.132 / 0.132 / 1.49 / 111.36 / 5.73 / 20.80
Table S2 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), CMC and surface concentration ratio (Cm/C20) and surface pressure at CMC (CMC) of the binary mixtures of F68 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 318.15 K
/ Cm(mmol·dm-3) / Ci
(mmol·dm-3) / max*106 (mol·m-2) / Amin
(Å2·molecule-1) / Aidmin
(Å2·molecule-1) / Cm/
C20 / CMC
(mN·m-1)
DTAB
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.098 / 0.111 / 4.77 / 034.79 / 84.12 / 1.30 / 29.24
0.356 / 0.105 / 0.140 / 5.75 / 028.85 / 87.08 / 1.75 / 29.65
0.480 / 0.121 / 0.181 / 4.03 / 041.17 / 90.05 / 2.20 / 31.02
0.625 / 0.154 / 0.250 / 4.38 / 037.83 / 91.83 / 2.96 / 31.45
0.787 / 0.251 / 0.420 / 4.20 / 039.44 / 93.61 / 2.98 / 29.53
0.903 / 0.643 / 0.969 / 2.95 / 056.11 / 95.39 / 3.16 / 28.92
1.000 / 15.830 / 15.830 / 1.21 / 136.34 / 2.62 / 24.34
TTAB
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.102 / 0.111 / 2.44 / 068.03 / 83.85 / 1.45 / 29.20
0.356 / 0.121 / 0.138 / 2.93 / 056.66 / 87.96 / 1.92 / 32.39
0.480 / 0.145 / 0.178 / 2.34 / 070.92 / 93.45 / 2.63 / 31.54
0.625 / 0.177 / 0.240 / 3.29 / 050.44 / 96.88 / 2.49 / 32.02
0.787 / 0.269 / 0.399 / 2.16 / 076.64 / 100.99 / 2.63 / 31.85
0.903 / 0.472 / 0.806 / 1.74 / 095.15 / 105.10 / 1.84 / 32.38
1.000 / 4.124 / 4.124 / 1.14 / 145.56 / 2.01 / 25.33
CTAB
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.092 / 0.110 / 2.78 / 059.62 / 90.52 / 1.39 / 31.35
0.356 / 0.099 / 0.133 / 2.40 / 069.14 / 94.75 / 1.80 / 31.59
0.480 / 0.113 / 0.165 / 1.74 / 095.34 / 101.51 / 2.74 / 31.43
0.625 / 0.142 / 0.215 / 1.47 / 112.79 / 106.59 / 1.67 / 30.79
0.787 / 0.195 / 0.312 / 1.40 / 118.44 / 112.51 / 1.85 / 30.57
0.903 / 0.328 / 0.488 / 1.75 / 094.72 / 119.27 / 1.65 / 31.05
1.000 / 0.914 / 0.914 / 1.02 / 161.55 / 2.25 / 26.42
10-2-10
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.097 / 0.112 / 2.73 / 060.60 / 82.03 / 1.24 / 33.14
0.356 / 0.105 / 0.138 / 2.68 / 061.84 / 86.51 / 1.69 / 31.90
0.480 / 0.128 / 0.181 / 3.11 / 053.31 / 90.99 / 1.93 / 31.73
0.625 / 0.175 / 0.242 / 3.30 / 050.30 / 92.11 / 2.30 / 31.55
0.787 / 0.208 / 0.408 / 2.47 / 067.03 / 94.91 / 2.47 / 31.70
0.903 / 0.395 / 0.812 / 2.32 / 071.30 / 97.15 / 4.29 / 32.65
1.000 / 5.950 / 5.950 / 1.24 / 132.98 / 4.42 / 32.53
12-2-12
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.099 / 0.109 / 3.01 / 055.09 / 84.00 / 1.08 / 32.78
0.356 / 0.118 / 0.131 / 2.61 / 063.46 / 87.83 / 1.19 / 31.75
0.480 / 0.137 / 0.165 / 1.78 / 093.21 / 92.93 / 1.30 / 31.41
0.625 / 0.178 / 0.209 / 2.88 / 057.55 / 96.75 / 1.54 / 30.41
0.787 / 0.266 / 0.304 / 1.68 / 098.71 / 103.12 / 2.14 / 31.02
0.903 / 0.381 / 0.445 / 1.50 / 110.30 / 109.49 / 2.86 / 30.90
1.000 / 0.783 / 0.783 / 1.17 / 140.72 / 2.74 / 21.78
14-2-14
0.000 / 0.095 / 0.095 / 2.14 / 077.30 / 1.10 / 32.73
0.156 / 0.096 / 0.099 / 2.73 / 060.60 / 85.23 / 1.20 / 31.01
0.356 / 0.098 / 0.104 / 2.65 / 062.57 / 90.57 / 1.32 / 31.38
0.480 / 0.103 / 0.109 / 1.96 / 084.58 / 97.84 / 1.58 / 32.54
0.625 / 0.107 / 0.114 / 2.47 / 067.14 / 103.65 / 1.72 / 31.55
0.787 / 0.110 / 0.121 / 1.66 / 099.90 / 110.92 / 2.00 / 32.59
0.903 / 0.114 / 0.126 / 1.49 / 111.26 / 122.56 / 2.85 / 32.81
1.000 / 0.131 / 0.131 / 1.32 / 125.47 / 2.25 / 34.17
Table S3 Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, adsorption and excess free energy (ΔGoads, ΔGoex), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of F68 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 308.15 K
/ ΔGom(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
(J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / ΔGoex
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
DTAB
0.156 / -28.54 / 102.47 / 425.17 / -41.89 / -0.81 / -7.05 / -21.03
0.356 / -28.25 / 108.63 / 444.23 / -37.58 / -1.00 / -6.76 / -21.58
0.480 / -27.72 / 111.31 / 451.19 / -34.79 / -1.11 / -6.44 / -22.04
0.625 / -27.16 / 112.10 / 451.97 / -34.80 / -1.23 / -6.31 / -22.52
0.787 / -26.55 / 106.34 / 431.29 / -35.94 / -1.82 / -6.84 / -23.91
0.903 / -24.72 / 088.97 / 368.97 / -35.11 / -1.26 / -5.61 / -23.76
TTAB
0.156 / -28.39 / 104.72 / 431.99 / -42.23 / -2.01 / -19.32
0.356 / -27.99 / 99.47 / 413.64 / -40.08 / -2.01 / -19.32
0.480 / -27.62 / 98.34 / 408.77 / -39.27 / -0.39 / -3.04 / -20.71
0.625 / -27.20 / 95.52 / 398.28 / -41.14 / -0.54 / -3.13 / -21.28
0.787 / -26.32 / 86.84 / 367.25 / -47.19 / -0.54 / -2.94 / -21.84
0.903 / -25.31 / 71.05 / 312.74 / -49.13 / -0.46 / -2.77 / -22.59
CTAB
0.156 / -29.15 / 101.05 / 422.56 / -47.13 / -0.95 / -2.65 / -20.64
0.356 / -28.89 / 95.52 / 403.76 / -51.62 / -0.68 / -1.85 / -20.44
0.480 / -28.64 / 87.63 / 377.33 / -45.84 / -0.59 / -1.54 / -20.49
0.625 / -28.28 / 72.95 / 328.52 / -45.81 / -0.39 / -1.18 / -20.41
0.787 / -28.02 / 56.45 / 374.11 / -50.28 / -0.42 / -1.28 / -20.65
0.903 / -27.86 / 34.73 / 203.15 / -46.51 / -0.52 / -1.71 / -20.92
10-2-10
0.156 / -28.55 / 110.52 / 451.34 / -41.59 / -0.58 / -5.05 / -20.55
0.356 / -28.17 / 114.47 / 462.92 / -40.28 / -0.56 / -4.46 / -20.72
0.480 / -27.58 / 112.89 / 455.87 / -38.41 / -0.55 / -4.02 / -20.96
0.625 / -26.95 / 103.42 / 423.08 / -42.97 / -0.50 / -3.69 / -21.17
0.787 / -25.94 / 105.00 / 424.93 / -41.20 / -0.50 / -3.44 / -21.75
0.903 / -24.60 / 90.79 / 374.47 / -43.53 / -0.32 / -3.01 / -22.47
12-2-12
0.156 / -28.37 / 105.79 / 435.37 / -41.97 / -0.62 / -19.32
0.356 / -28.33 / 96.31 / 404.52 / -42.31 / -0.62 / -19.32
0.480 / -28.15 / 86.05 / 370.63 / -40.65 / -0.14 / -0.88 / -20.03
0.625 / -27.92 / 71.84 / 323.75 / -45.13 / -0.12 / -0.81 / -20.19
0.787 / -27.73 / 52.65 / 260.90 / -45.10 / -0.25 / -1.07 / -20.61
0.903 / -27.49 / 35.92 / 205.78 / -45.14 / -0.24 / -1.20 / -20.83
14-2-14
0.156 / -30.00 / 80.52 / 358.69 / -47.50 / -0.45 / 0.65 / -18.22
0.356 / -30.63 / 50.44 / 263.13 / -45.53 / -0.46 / 0.60 / -17.63
0.480 / -31.11 / 35.76 / 217.04 / -45.56 / -0.26 / 0.84 / -16.95
0.625 / -31.65 / 28.10 / 193.92 / -51.66 / -0.58 / -0.03 / -17.11
0.787 / -32.00 / 17.19 / 159.64 / -51.71 / -0.68 / -0.77 / -17.00
0.903 / -32.11 / 11.05 / 140.09 / -49.37 / -0.45 / -2.46 / -16.40
Table S4 Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, adsorption and excess free energy (ΔGoads, ΔGoex), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of F68 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 318.15 K
/ ΔGom(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
(J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / ΔGoex
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
DTAB
0.156 / -32.83 / 109.24 / 446.54 / -38.96 / -1.12 / -10.63 / -26.91
0.356 / -32.66 / 115.79 / 467.18 / -37.81 / -1.71 / -10.86 / -28.22
0.480 / -32.31 / 118.65 / 474.53 / -40.00 / -2.29 / -11.14 / -29.52
0.625 / -31.71 / 119.50 / 475.29 / -38.88 / -2.52 / -11.06 / -30.17
0.787 / -30.50 / 113.35 / 452.18 / -37.52 / -2.32 / -10.25 / -30.22
0.903 / -28.17 / 094.84 / 386.66 / -37.94 / -1.36 / -08.22 / -29.06
TTAB
0.156 / -32.73 / 111.64 / 453.77 / -44.70 / -0.66 / -7.38 / -26.00
0.356 / -32.31 / 106.34 / 436.18 / -43.36 / -0.57 / -6.57 / -26.00
0.480 / -31.86 / 104.34 / 429.63 / -45.33 / -1.06 / -6.95 / -27.22
0.625 / -31.37 / 101.86 / 418.66 / -41.10 / -1.24 / -6.91 / -27.82
0.787 / -30.33 / 092.96 / 386.30 / -45.03 / -1.42 / -6.74 / -28.60
0.903 / -28.94 / 075.73 / 329.02 / -47.49 / -1.52 / -6.50 / -29.51
CTAB
0.156 / -32.99 / 107.71 / 442.27 / -44.25 / -0.89 / -5.27 / -26.29
0.356 / -32.81 / 101.82 / 423.76 / -45.96 / -1.12 / -5.10 / -26.89
0.480 / -32.48 / 93.41 / 395.71 / -50.53 / -1.28 / -4.96 / -27.42
0.625 / -31.91 / 77.76 / 344.73 / -52.83 / -1.29 / -4.71 / -27.74
0.787 / -31.13 / 60.17 / 286.97 / -52.94 / -1.35 / -4.55 / -28.27
0.903 / -29.84 / 37.03 / 210.18 / -47.55 / -1.08 / -4.01 / -28.64
10-2-10
0.156 / -32.86 / 117.81 / 473.60 / -44.95 / -0.79 / -8.19 / -26.16
0.356 / -32.66 / 122.02 / 486.86 / -44.54 / -1.09 / -8.04 / -26.90
0.480 / -32.17 / 120.34 / 479.39 / -42.36 / -1.06 / -7.46 / -27.09
0.625 / -31.39 / 110.24 / 444.15 / -40.95 / -1.03 / -7.05 / -27.28
0.787 / -30.97 / 111.92 / 449.15 / -43.77 / -2.51 / -8.74 / -30.18
0.903 / -29.38 / 96.78 / 396.54 / -43.40 / -1.32 / -6.56 / -28.99
12-2-12
0.156 / -32.81 / 112.54 / 457.57 / -43.68 / -0.45 / -4.15 / -25.54
0.356 / -32.37 / 102.67 / 425.83 / -44.51 / -0.32 / -3.35 / -25.51
0.480 / -32.00 / 91.73 / 388.92 / -49.64 / -0.45 / -3.29 / -26.04
0.625 / -31.35 / 76.58 / 339.26 / -41.89 / -0.38 / -2.96 / -26.25
0.787 / -30.36 / 56.13 / 271.86 / -48.80 / -0.38 / -2.79 / -26.85
0.903 / -29.47 / 38.29 / 212.98 / -49.99 / -0.42 / -2.79 / -27.84
14-2-14
0.156 / -32.88 / 85.83 / 373.17 / -44.20 / -0.09 / -0.65 / -24.72
0.356 / -32.83 / 53.52 / 272.39 / -44.66 / -0.17 / -0.67 / -24.90
0.480 / -32.71 / 38.12 / 222.65 / -49.29 / -0.19 / -0.64 / -25.06
0.625 / -32.62 / 29.96 / 196.98 / -45.37 / -0.18 / -0.62 / -25.15
0.787 / -32.55 / 18.32 / 159.89 / -52.16 / -0.28 / -0.86 / -25.38
0.903 / -32.46 / 11.78 / 139.06 / -54.44 / -0.35 / -1.25 / -25.56
Table S5 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), CMC and surface concentration ratio (Cm/C20) and surface pressure at CMC (CMC) of the binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 298.15 K
/ Cm(mmol·dm-3) / Ci
(mmol·dm-3) / max*106 (mol·m-2) / Amin
(Å2·molecule-1) / Aidmin
(Å2·molecule-1) / Cm/
C20 / CMC
(mN·m-1)
DTAB
0.000 / 0.068 / 0.068 / 3.17 / 052.26 / 3.40 / 32.38
0.156 / 0.120 / 0.080 / 2.23 / 074.21 / 57.12 / 2.18 / 31.73
0.356 / 0.138 / 0.100 / 1.92 / 086.34 / 59.29 / 2.05 / 30.32
0.480 / 0.154 / 0.133 / 2.34 / 070.86 / 59.83 / 1.83 / 30.59
0.625 / 0.195 / 0.176 / 1.97 / 083.99 / 60.91 / 2.07 / 30.02
0.787 / 0.355 / 0.310 / 1.33 / 124.24 / 60.37 / 2.95 / 31.76
0.903 / 0.742 / 0.647 / 1.75 / 094.70 / 62.54 / 1.95 / 29.86
1.000 / 16.441 / 16.441 / 1.56 / 106.37 / 2.69 / 29.35
TTAB
0.000 / 0.068 / 0.068 / 3.17 / 052.26 / 3.40 / 32.38
0.156 / 0.095 / 0.079 / 2.61 / 063.53 / 57.36 / 1.75 / 28.96
0.356 / 0.123 / 0.099 / 1.86 / 088.92 / 63.19 / 2.92 / 29.97
0.480 / 0.145 / 0.129 / 2.89 / 057.32 / 66.10 / 2.84 / 29.92
0.625 / 0.189 / 0.172 / 1.62 / 102.00 / 68.29 / 2.12 / 30.01
0.787 / 0.335 / 0.293 / 1.65 / 100.44 / 74.12 / 3.04 / 31.77
0.903 / 0.642 / 0.577 / 1.25 / 132.00 / 79.22 / 4.55 / 30.28
1.000 / 3.632 / 3.632 / 1.32 / 125.13 / 2.70 / 29.59
CTAB
0.000 / 0.068 / 0.068 / 3.17 / 052.26 / 3.40 / 32.38
0.156 / 0.085 / 0.079 / 2.98 / 055.60 / 63.63 / 0.42 / 29.64
0.356 / 0.099 / 0.097 / 2.70 / 061.27 / 65.26 / 0.44 / 30.61
0.480 / 0.112 / 0.123 / 3.12 / 053.07 / 69.32 / 0.47 / 30.63
0.625 / 0.135 / 0.157 / 3.98 / 041.61 / 73.38 / 0.52 / 30.86
0.787 / 0.187 / 0.242 / 2.28 / 072.66 / 81.51 / 0.65 / 29.25
0.903 / 0.314 / 0.402 / 2.49 / 066.54 / 89.63 / 1.01 / 28.90
1.000 / 0.867 / 0.867 / 1.24 / 133.51 / 2.64 / 27.29
10-2-10
0.000 / 0.068 / 0.068 / 3.17 / 052.26 / 3.40 / 32.38
0.156 / 0.095 / 0.080 / 4.08 / 040.68 / 55.18 / 3.39 / 32.68
0.356 / 0.126 / 0.100 / 4.54 / 036.49 / 54.69 / 3.81 / 33.79
0.480 / 0.158 / 0.129 / 4.41 / 037.56 / 57.13 / 3.51 / 30.65
0.625 / 0.223 / 0.178 / 3.36 / 049.40 / 57.13 / 3.43 / 31.88
0.787 / 0.483 / 0.312 / 4.06 / 040.84 / 61.03 / 5.48 / 30.19
0.903 / 0.885 / 0.629 / 2.51 / 066.12 / 65.41 / 4.75 / 32.32
1.000 / 6.960 / 6.960 / 1.64 / 101.00 / 14.90 / 31.13
12-2-12
0.000 / 0.068 / 0.068 / 3.17 / 52.26 / 3.40 / 32.38
0.156 / 0.088 / 0.079 / 3.90 / 42.52 / 54.93 / 5.50 / 29.64
0.356 / 0.102 / 0.097 / 4.18 / 39.63 / 55.38 / 5.36 / 29.49
0.480 / 0.115 / 0.123 / 5.81 / 28.54 / 57.17 / 2.55 / 30.90
0.625 / 0.144 / 0.159 / 3.46 / 47.89 / 60.29 / 4.23 / 31.87
0.787 / 0.223 / 0.248 / 2.29 / 72.49 / 66.09 / 6.75 / 30.33
0.903 / 0.370 / 0.405 / 2.88 / 57.52 / 71.00 / 6.49 / 29.73
1.000 / 0.910 / 0.910 / 1.71 / 96.89 / 7.33 / 30.95
14-2-14
0.000 / 0.068 / 0.068 / 3.17 / 52.26 / 3.40 / 32.38
0.156 / 0.055 / 0.074 / 3.88 / 42.71 / 61.76 / 3.66 / 29.39
0.356 / 0.064 / 0.082 / 3.64 / 45.52 / 62.12 / 4.57 / 28.01
0.480 / 0.080 / 0.092 / 4.22 / 39.25 / 65.04 / 4.21 / 27.27
0.625 / 0.092 / 0.103 / 3.40 / 48.81 / 67.97 / 6.13 / 25.36
0.787 / 0.105 / 0.119 / 3.66 / 45.25 / 72.35 / 4.77 / 25.89
0.903 / 0.121 / 0.134 / 3.25 / 51.05 / 78.56 / 6.72 / 27.88
1.000 / 0.151 / 0.151 / 1.87 / 88.80 / 10.06 / 29.98
Table S6 Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, adsorption and excess free energy (ΔGoads, ΔGoex), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 298.15 K
/ ΔGom(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
(J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / ΔGoex
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
DTAB
0.156 / -32.33 / 186.24 / 733.11 / -46.51 / -5.48 / -23.78
0.356 / -31.98 / 184.76 / 726.99 / -47.75 / -5.48 / -23.78
0.480 / -31.71 / 181.07 / 713.69 / -44.77 / -5.48 / -23.78
0.625 / -31.13 / 181.81 / 714.20 / -46.31 / -5.48 / -23.78
0.787 / -29.64 / 194.31 / 751.36 / -53.41 / -5.48 / -23.78
0.903 / -27.81 / 200.28 / 765.06 / -43.69 / -5.48 / -23.78
TTAB
0.156 / -32.91 / 171.46 / 685.48 / -43.99 / -3.97 / -23.78
0.356 / -32.27 / 172.94 / 688.29 / -48.32 / -3.97 / -23.78
0.480 / -31.86 / 169.24 / 674.53 / -42.19 / -3.97 / -23.78
0.625 / -31.20 / 171.46 / 679.76 / -49.64 / -3.97 / -23.78
0.787 / -29.78 / 174.42 / 684.92 / -49.00 / -3.97 / -23.78
0.903 / -28.17 / 167.77 / 657.20 / -52.25 / 0.15 / -2.87 / -24.22
CTAB
0.156 / -33.18 / 166.29 / 669.05 / -43.11 / -2.54 / -23.78
0.356 / -32.81 / 164.81 / 662.83 / -44.10 / -2.54 / -23.78
0.480 / -32.50 / 159.64 / 644.45 / -42.29 / -0.27 / -3.52 / -24.88
0.625 / -32.04 / 160.38 / 645.37 / -39.77 / -0.51 / -3.78 / -25.62
0.787 / -31.23 / 147.81 / 600.53 / -44.03 / -0.75 / -3.93 / -26.55
0.903 / -29.95 / 139.68 / 568.95 / -41.53 / -0.65 / -3.61 / -27.28
10-2-10
0.156 / -32.91 / 179.59 / 712.74 / -40.92 / -4.62 / -23.78
0.356 / -32.21 / 178.85 / 707.90 / -39.64 / -4.62 / -23.70
0.480 / -31.65 / 175.90 / 696.12 / -38.58 / -4.62 / -23.78
0.625 / -30.79 / 178.11 / 700.69 / -40.28 / -4.62 / -23.78
0.787 / -28.88 / 189.20 / 731.45 / -36.31 / -4.62 / -23.78
0.903 / -27.38 / 185.50 / 714.02 / -40.25 / -4.62 / -23.78
12-2-12
0.156 / -33.10 / 084.99 / 396.09 / -40.69 / -2.59 / -23.78
0.356 / -32.73 / 168.50 / 674.97 / -39.77 / -2.59 / -23.78
0.480 / -32.44 / 164.51 / 660.59 / -37.75 / -0.23 / -3.47 / -24.78
0.625 / -31.88 / 160.08 / 643.85 / -41.07 / -0.33 / -3.49 / -25.27
0.787 / -30.79 / 157.42 / 631.29 / -44.04 / -0.26 / -3.15 / -25.72
0.903 / -29.54 / 148.55 / 597.33 / -39.84 / -0.25 / -3.00 / -26.73
14-2-14
0.156 / -34.26 / 152.98 / 628.28 / -41.83 / -1.06 / -3.21 / -25.30
0.356 / -33.89 / 154.56 / 631.75 / -41.57 / -0.69 / -2.20 / -25.00
0.480 / -33.33 / 150.77 / 617.50 / -39.78 / -0.37 / -1.46 / -24.83
0.625 / -32.99 / 142.64 / 589.07 / -40.44 / -0.29 / -1.27 / -24.95
0.787 / -32.66 / 127.86 / 538.40 / -39.72 / -0.37 / -1.42 / -25.34
0.903 / -32.31 / 114.55 / 492.60 / -40.88 / -0.29 / -1.42 / -25.56
Table S7 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), CMC and surface concentration ratio (Cm/C20) and surface pressure at CMC (CMC) of the binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 308.15 K
/ Cm(mmol·dm-3) / Ci
(mmol·dm-3) / max*106 (mol·m-2) / Amin
(Å2·molecule-1) / Aidmin
(Å2·molecule-1) / Cm/
C20 / CMC
(mN·m-1)
DTAB
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 1.94 / 27.28
0.156 / 0.038 / 0.040 / 4.76 / 34.86 / 50.10 / 1.23 / 25.19
0.356 / 0.047 / 0.050 / 3.47 / 47.84 / 50.89 / 1.48 / 27.51
0.480 / 0.058 / 0.066 / 2.32 / 71.32 / 54.81 / 2.57 / 26.05
0.625 / 0.076 / 0.089 / 1.80 / 91.83 / 56.38 / 1.82 / 27.35
0.787 / 0.134 / 0.153 / 2.08 / 79.71 / 61.09 / 2.40 / 27.23
0.903 / 0.276 / 0.352 / 1.70 / 97.22 / 61.87 / 1.75 / 28.21
1.000 / 159.392 / 159.392 / 1.35 / 122.29 / 2.64 / 27.57
TTAB
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 1.94 / 27.28
0.156 / 0.038 / 0.040 / 4.54 / 36.53 / 49.18 / 2.26 / 26.84
0.356 / 0.045 / 0.049 / 3.69 / 44.98 / 50.96 / 2.63 / 25.26
0.480 / 0.060 / 0.065 / 4.15 / 40.00 / 54.53 / 2.51 / 26.83
0.625 / 0.079 / 0.089 / 3.25 / 51.07 / 58.99 / 3.37 / 26.03
0.787 / 0.138 / 0.152 / 3.67 / 45.18 / 62.55 / 3.10 / 28.12
0.903 / 0.261 / 0.337 / 1.99 / 83.08 / 66.12 / 3.39 / 29.39
1.000 / 39.700 / 39.700 / 1.24 / 133.01 / 2.57 / 29.07
CTAB
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 1.94 / 27.28
0.156 / 0.037 / 0.040 / 3.97 / 41.74 / 51.77 / 0.98 / 27.47
0.356 / 0.046 / 0.050 / 4.12 / 40.27 / 51.77 / 0.93 / 29.84
0.480 / 0.062 / 0.064 / 4.06 / 40.86 / 50.78 / 1.14 / 30.19
0.625 / 0.081 / 0.088 / 3.43 / 48.36 / 59.72 / 0.96 / 28.31
0.787 / 0.134 / 0.150 / 1.73 / 95.75 / 68.66 / 0.92 / 27.00
0.903 / 0.256 / 0.332 / 1.94 / 85.19 / 73.63 / 0.85 / 27.47
1.000 / 9.120 / 9.120 / 1.15 / 143.17 / 2.37 / 28.87
10-2-10
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 1.94 / 27.28
0.156 / 0.037 / 0.040 / 5.05 / 32.84 / 52.97 / 1.85 / 31.44
0.356 / 0.044 / 0.050 / 4.31 / 38.44 / 50.69 / 2.39 / 30.66
0.480 / 0.058 / 0.065 / 3.90 / 42.47 / 52.97 / 3.25 / 29.20
0.625 / 0.078 / 0.090 / 3.54 / 46.87 / 54.50 / 4.00 / 31.91
0.787 / 0.130 / 0.157 / 3.02 / 54.85 / 59.07 / 2.39 / 31.95
0.903 / 0.260 / 0.357 / 2.00 / 82.84 / 64.41 / 2.09 / 33.26
1.000 / 65.000 / 65.000 / 1.38 / 120.06 / 6.36 / 26.77
12-2-12
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 1.94 / 27.28
0.156 / 0.037 / 0.040 / 3.82 / 43.39 / 51.07 / 1.22 / 25.61
0.356 / 0.042 / 0.049 / 3.97 / 41.77 / 52.68 / 1.12 / 26.34
0.480 / 0.055 / 0.065 / 3.24 / 51.08 / 55.09 / 1.51 / 26.27
0.625 / 0.067 / 0.089 / 4.16 / 39.84 / 55.89 / 1.35 / 27.05
0.787 / 0.101 / 0.151 / 2.87 / 57.68 / 62.33 / 1.39 / 26.74
0.903 / 0.218 / 0.321 / 1.98 / 83.68 / 63.94 / 1.71 / 25.85
1.000 / 9.900 / 9.900 / 1.33 / 124.29 / 6.68 / 21.98
14-2-14
0.000 / 0.034 / 0.034 / 3.78 / 43.82 / 2.17 / 27.28
0.156 / 0.041 / 0.044 / 4.02 / 41.22 / 53.95 / 2.64 / 26.27
0.356 / 0.047 / 0.055 / 4.67 / 35.48 / 54.63 / 2.91 / 25.54
0.480 / 0.058 / 0.070 / 2.94 / 56.37 / 56.66 / 3.40 / 24.13
0.625 / 0.072 / 0.096 / 3.25 / 50.96 / 58.68 / 4.11 / 24.29
0.787 / 0.117 / 0.156 / 2.64 / 62.73 / 63.41 / 4.97 / 21.59
0.903 / 0.218 / 0.294 / 2.03 / 81.47 / 68.81 / 4.62 / 22.69
1.000 / 1.320 / 1.320 / 1.49 / 111.36 / 5.73 / 20.80
Table S8 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), CMC and surface concentration ratio (Cm/C20) and surface pressure at CMC (CMC) of the binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 318.15 K
/ Cm(mmol·dm-3) / Ci
(mmol·dm-3) / max*106 (mol·m-2) / Amin
(Å2·molecule-1) / Aidmin
(Å2·molecule-1) / Cm/
C20 / CMC
(mN·m-1)
DTAB
0.000 / 0.085 / 0.085 / 4.26 / 038.94 / 1.73 / 26.11
0.156 / 0.078 / 0.100 / 3.85 / 043.08 / 49.65 / 2.51 / 25.34
0.356 / 0.092 / 0.124 / 2.66 / 062.23 / 50.62 / 2.42 / 25.03
0.480 / 0.114 / 0.164 / 1.78 / 093.15 / 52.57 / 1.96 / 26.86
0.625 / 0.142 / 0.224 / 2.34 / 070.80 / 54.52 / 2.05 / 23.24
0.787 / 0.186 / 0.389 / 1.80 / 091.80 / 59.39 / 1.97 / 22.34
0.903 / 0.331 / 0.876 / 1.31 / 126.26 / 62.31 / 2.20 / 24.29
1.000 / 1583 / 1583 / 1.21 / 136.34 / 2.62 / 24.34
TTAB
0.000 / 0.085 / 0.085 / 4.26 / 038.94 / 1.73 / 26.11
0.156 / 0.092 / 0.100 / 3.75 / 044.26 / 51.73 / 2.08 / 24.43
0.356 / 0.115 / 0.126 / 3.42 / 048.44 / 53.86 / 1.34 / 24.93
0.480 / 0.148 / 0.164 / 3.11 / 053.25 / 57.06 / 1.98 / 27.00
0.625 / 0.184 / 0.227 / 2.32 / 071.51 / 59.19 / 2.06 / 28.74
0.787 / 0.295 / 0.379 / 2.16 / 076.64 / 60.26 / 1.94 / 26.89
0.903 / 0.684 / 0.908 / 1.16 / 142.72 / 64.52 / 3.84 / 25.83
1.000 / 412.4 / 412.4 / 1.14 / 145.56 / 2.01 / 25.33
CTAB
0.000 / 0.085 / 0.085 / 4.26 / 038.94 / 1.73 / 26.11
0.156 / 0.094 / 0.100 / 4.62 / 035.86 / 51.20 / 3.19 / 26.74
0.356 / 0.114 / 0.124 / 4.71 / 035.18 / 52.42 / 3.50 / 25.85
0.480 / 0.148 / 0.164 / 3.17 / 052.31 / 57.33 / 3.03 / 26.39
0.625 / 0.176 / 0.225 / 1.47 / 112.79 / 53.65 / 2.66 / 26.76
0.787 / 0.344 / 0.388 / 1.98 / 083.71 / 62.23 / 3.83 / 26.19
0.903 / 0.723 / 0.839 / 1.50 / 110.14 / 70.81 / 3.14 / 27.75
1.000 / 91.4 / 91.4 / 1.02 / 161.55 / 2.25 / 26.42
10-2-10
0.000 / 0.085 / 0.085 / 4.26 / 38.94 / 1.73 / 26.11
0.156 / 0.074 / 0.010 / 4.52 / 36.73 / 52.10 / 1.68 / 26.15
0.356 / 0.099 / 0.124 / 3.91 / 42.38 / 50.22 / 2.53 / 27.86
0.480 / 0.134 / 0.162 / 4.08 / 40.65 / 53.98 / 2.19 / 26.33
0.625 / 0.178 / 0.222 / 4.54 / 36.55 / 56.80 / 1.79 / 28.47
0.787 / 0.286 / 0.382 / 2.06 / 80.48 / 54.92 / 2.30 / 24.59
0.903 / 0.578 / 0.933 / 1.78 / 93.23 / 55.86 / 2.17 / 22.34
1.000 / 595 / 595 / 1.24 / 132.98 / 4.42 / 28.98
12-2-12
0.000 / 0.085 / 0.085 / 4.26 / 38.94 / 1.73 / 26.11
0.156 / 0.880 / 0.100 / 4.65 / 35.64 / 52.17 / 2.20 / 24.90
0.356 / 0.106 / 0.124 / 5.90 / 28.12 / 51.15 / 2.97 / 23.21
0.480 / 0.134 / 0.163 / 3.23 / 51.31 / 52.17 / 2.75 / 24.56
0.625 / 0.189 / 0.227 / 2.56 / 64.67 / 52.17 / 3.43 / 23.33
0.787 / 0.314 / 0.396 / 1.82 / 90.86 / 58.27 / 3.39 / 24.11
0.903 / 0.668 / 0.859 / 3.37 / 49.23 / 63.36 / 3.35 / 23.47
1.000 / 78.3 / 78.3 / 1.17 / 140.72 / 2.74 / 21.78
14-2-14
0.000 / 0.085 / 0.085 / 4.26 / 38.94 / 1.73 / 26.11
0.156 / 0.087 / 0.099 / 4.65 / 35.64 / 50.18 / 1.98 / 25.89
0.356 / 0.098 / 0.125 / 4.00 / 41.47 / 50.18 / 2.05 / 26.21
0.480 / 0.135 / 0.164 / 2.69 / 61.72 / 51.91 / 2.70 / 29.81
0.625 / 0.194 / 0.220 / 2.74 / 60.40 / 57.11 / 3.52 / 28.88
0.787 / 0.328 / 0.378 / 3.63 / 45.72 / 60.57 / 3.77 / 28.86
0.903 / 0.541 / 0.775 / 2.80 / 59.09 / 66.62 / 3.10 / 31.15
1.000 / 13.1 / 13.1 / 1.32 / 125.47 / 2.25 / 34.17
Table S9 Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, adsorption and excess free energy (ΔGoads, ΔGoex), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 308.15 K
/ ΔGom(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
J·mol-1·K-1 / ΔGoads
(kJ·mol-1) / ΔGoex
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
DTAB
0.156 / -40.85 / 198.94 / 778.19 / -46.14 / -0.51 / -15.59 / -33.44
0.356 / -40.33 / 197.37 / 771.40 / -48.26 / -0.27 / -14.08 / -32.97
0.480 / -39.81 / 193.42 / 756.90 / -51.00 / -1.32 / -15.68 / -35.35
0.625 / -39.18 / 194.21 / 757.39 / -54.30 / -1.60 / -15.64 / -36.08
0.787 / -37.76 / 207.63 / 796.36 / -50.84 / -1.38 / -14.66 / -35.85
0.903 / -35.97 / 213.94 / 811.04 / -52.49 / -1.46 / -14.06 / -36.37
TTAB
0.156 / -40.88 / 183.15 / 727.06 / -46.79 / -0.58 / -13.16 / -33.58
0.356 / -40.43 / 184.73 / 730.70 / -47.27 / -0.65 / -12.57 / -33.83
0.480 / -39.74 / 180.79 / 715.65 / -46.20 / -0.69 / -12.05 / -34.06
0.625 / -39.06 / 183.15 / 721.15 / -47.07 / -1.05 / -12.23 / -34.97
0.787 / -37.69 / 186.31 / 726.95 / -45.34 / -0.86 / -11.29 / -34.77
0.903 / -36.11 / 179.21 / 698.77 / -50.82 / -1.55 / -11.73 / -36.76
CTAB
0.156 / -40.95 / 177.63 / 709.34 / -47.85 / -0.72 / -10.78 / -33.86
0.356 / -40.41 / 176.05 / 702.47 / -47.65 / -0.45 / -9.46 / -33.44
0.480 / -39.65 / 170.52 / 682.08 / -47.09 / -0.26 / -8.30 / -33.09
0.625 / -39.01 / 171.31 / 682.54 / -47.25 / -0.57 / -8.75 / -34.00
0.787 / -37.76 / 157.89 / 634.96 / -53.34 / -0.69 / -8.45 / -34.55
0.903 / -36.16 / 149.21 / 601.57 / -50.26 / -1.07 / -8.51 / -35.94
10-2-10
0.156 / -40.95 / 191.84 / 755.47 / -47.17 / -1.07 / -14.96 / -34.49
0.356 / -40.52 / 191.05 / 751.52 / -47.62 / -1.12 / -14.31 / -34.74
0.480 / -39.84 / 187.89 / 739.05 / -47.31 / -1.16 / -13.74 / -34.97
0.625 / -39.11 / 190.26 / 744.35 / -48.11 / -1.21 / -13.34 / -35.21
0.787 / -37.84 / 202.10 / 778.67 / -48.40 / -1.35 / -12.97 / -35.74
0.903 / -36.12 / 198.15 / 760.29 / -52.72 / -1.75 / -12.92 / -36.91
12-2-12
0.156 / -40.91 / 90.79 / 427.39 / -47.60 / -0.58 / -10.51 / -33.28
0.356 / -40.60 / 180.00 / 715.89 / -47.23 / -1.04 / -10.68 / -34.33
0.480 / -39.98 / 175.73 / 700.05 / -48.06 / -1.28 / -10.48 / -35.01
0.625 / -39.49 / 171.00 / 683.07 / -45.98 / -1.72 / -10.72 / -36.03
0.787 / -38.46 / 168.15 / 670.54 / -47.76 / -1.98 / -10.57 / -36.87
0.903 / -36.56 / 158.68 / 633.60 / -49.59 / -1.81 / -09.69 / -37.12
14-2-14
0.156 / -40.70 / 163.42 / 662.42 / -47.22 / -0.50 / -6.67 / -33.13
0.356 / -40.32 / 165.00 / 666.31 / -45.78 / -0.61 / -6.28 / -33.51
0.480 / -39.83 / 161.05 / 651.91 / -48.02 / -0.95 / -6.41 / -34.41
0.625 / -39.28 / 152.36 / 621.93 / -46.73 / -1.09 / -6.30 / -34.92
0.787 / -38.10 / 136.58 / 566.88 / -46.26 / -0.97 / -5.69 / -35.16
0.903 / -36.56 / 122.37 / 515.75 / -47.69 / -0.97 / -5.32 / -35.98
Table S10 Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, adsorption and excess free energy (ΔGoads, ΔGoex), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of P123 with monomeric/gemini surfactants as a function of the mole fraction of monomeric/gemini surfactant (α) at 318.15 K
/ ΔGom(kJ·mol-1) / ΔHom
(kJ·mol-1 / ΔSom
J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / ΔGoex
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
DTAB
0.156 / -44.81 / 212.07 / 807.43 / -51.39 / -2.94 / -21.96 / -42.97
0.356 / -44.40 / 210.38 / 802.14 / -53.79 / -2.98 / -21.24 / -43.28
0.480 / -43.87 / 206.17 / 785.96 / -58.94 / -3.35 / -21.06 / -44.19
0.625 / -43.33 / 207.02 / 786.90 / -53.24 / -3.76 / -21.12 / -45.14
0.787 / -42.66 / 221.32 / 829.76 / -55.01 / -5.09 / -22.23 / -47.87
0.903 / -41.23 / 228.06 / 846.43 / -59.70 / -5.59 / -22.21 / -49.18
TTAB
0.156 / -44.40 / 195.24 / 753.25 / -50.92 / -1.18 / -16.96 / -39.58
0.356 / -43.85 / 196.92 / 758.54 / -51.12 / -0.83 / -15.56 / -38.98
0.480 / -43.23 / 192.91 / 741.61 / -51.89 / -1.12 / -15.47 / -39.74
0.625 / -42.69 / 195.24 / 747.85 / -55.06 / -1.83 / -16.03 / -41.39
0.787 / -41.52 / 198.60 / 754.75 / -53.93 / -2.23 / -15.95 / -42.49
0.903 / -39.43 / 191.03 / 724.39 / -61.64 / -1.65 / -14.38 / -41.65
CTAB
0.156 / -44.35 / 189.34 / 734.56 / -50.13 / -0.75 / -13.39 / -38.70
0.356 / -43.87 / 187.66 / 729.27 / -49.35 / -0.63 / -12.40 / -38.57
0.480 / -43.23 / 181.77 / 707.22 / -51.54 / -0.99 / -12.45 / -39.51
0.625 / -42.80 / 182.61 / 708.51 / -60.97 / -1.73 / -13.18 / -41.22
0.787 / -41.13 / 168.31 / 658.33 / -54.34 / -0.84 / -11.11 / -39.52
0.903 / -39.29 / 159.05 / 623.44 / -57.70 / -0.95 / -10.63 / -40.20
10-2-10
0.156 / -44.94 / 283.43 / 10.32.15 / -50.73 / -3.49 / -20.54 / -43.51
0.356 / -44.22 / 203.65 / 781.39 / -51.33 / -2.51 / -18.57 / -42.06
0.480 / -43.47 / 200.29 / 766.19 / -49.92 / -2.26 / -17.59 / -41.81
0.625 / -42.77 / 202.81 / 771.91 / -49.04 / -2.33 / -17.21 / -42.11
0.787 / -41.59 / 215.43 / 807.89 / -53.51 / -2.55 / -16.86 / -42.80
0.903 / -39.85 / 211.22 / 789.18 / -52.39 / -2.85 / -16.50 / -43.80
12-2-12
0.156 / -38.81 / 96.78 / 426.17 / -44.15 / -1.32 / -14.10 / -39.83
0.356 / -44.05 / 191.87 / 725.07 / -47.98 / -1.32 / -13.34 / -40.01
0.480 / -43.47 / 187.32 / 725.45 / -51.06 / -1.68 / -13.24 / -40.93
0.625 / -42.62 / 182.28 / 706.90 / -51.71 / -1.31 / -12.24 / -40.36
0.787 / -41.36 / 179.25 / 693.42 / -54.56 / -1.38 / -11.74 / -40.79
0.903 / -39.49 / 169.15 / 655.81 / -46.45 / -1.29 / -10.93 / -41.06
14-2-14
0.156 / -44.53 / 174.20 / 687.51 / -50.09 / -1.10 / -10.46 / -39.34
0.356 / -44.23 / 175.88 / 692.80 / -50.78 / -1.50 / -10.38 / -40.30
0.480 / -43.45 / 171.67 / 676.20 / -54.53 / -1.36 / -9.60 / -40.29
0.625 / -42.55 / 162.42 / 644.28 / -53.06 / -0.76 / -8.16 / -39.24
0.787 / -41.25 / 145.59 / 587.28 / -49.20 / -0.70 / -7.53 / -39.45
0.903 / -40.01 / 130.44 / 535.77 / -51.10 / -1.46 / -8.26 / -41.72
Fig. S1. Plots of βγavg versus m for the binary mixtures of (a) F68 (b) P123 with monomeric (dotted lines) gemini (full lines) and surfactants at (♦) 298.15, (■) 308.15 and (▲) 318.15 K.
Fig. S2. r for the binary mixture of F68 with (a) DTAB, (b) TTAB (c) CTAB at (♦) 298.15, (■) 308.15 and (▲) 318.15 K
Fig. S3. r for the binary mixture of F68 with (a) 12-2-12 and (b) 14-2-14 at (♦) 298.15, (■) 308.15 and (▲) 318.15 K.