File No: LTD/1944
April 2017
NATIONAL INDUSTRIAL CHEMICALS NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS)
PUBLIC REPORT
HANSA® SQ 2050
This Assessment has been compiled in accordance with the provisions of the Industrial Chemicals (Notification and Assessment) Act 1989 (the Act) and Regulations. This legislation is an Act of the Commonwealth of Australia. The National Industrial Chemicals Notification and Assessment Scheme (NICNAS) is administered by the Department of Health, and conducts the risk assessment for public health and occupational health and safety. The assessment of environmental risk is conducted by the Department of the Environment and Energy.
This Public Report is available for viewing and downloading from the NICNAS website or available on request, free of charge, by contacting NICNAS. For requests and enquiries please contact the NICNAS Administration Coordinator at:
Street Address: / Level 7, 260 Elizabeth Street, SURRY HILLS NSW 2010, AUSTRALIA. /Postal Address: / GPO Box 58, SYDNEY NSW 2001, AUSTRALIA.
TEL: / + 61 2 8577 8800
FAX: / + 61 2 8577 8888
Website: / www.nicnas.gov.au
Director
NICNAS
TABLE OF CONTENTS
SUMMARY 3
CONCLUSIONS AND REGULATORY OBLIGATIONS 3
ASSESSMENT DETAILS 5
1. APPLICANT AND NOTIFICATION DETAILS 5
2. IDENTITY OF CHEMICAL 5
3. COMPOSITION 5
4. PHYSICAL AND CHEMICAL PROPERTIES 5
5. INTRODUCTION AND USE INFORMATION 6
6. HUMAN HEALTH IMPLICATIONS 7
6.1. Exposure Assessment 7
6.1.1. Occupational Exposure 7
6.1.2. Public Exposure 8
6.2. Human Health Effects Assessment 8
6.3. Human Health Risk Characterisation 9
6.3.1. Occupational Health and Safety 9
6.3.2. Public Health 9
7. ENVIRONMENTAL IMPLICATIONS 9
7.1. Environmental Exposure & Fate Assessment 9
7.1.1. Environmental Exposure 9
7.1.2. Environmental Fate 10
7.1.3. Predicted Environmental Concentration (PEC) 10
7.2. Environmental Effects Assessment 10
7.2.1. Predicted No-Effect Concentration 11
7.3. Environmental Risk Assessment 11
Appendix A: Physical and Chemical Properties 12
Appendix B: Toxicological Investigations 13
B.1. Acute toxicity – oral 13
Appendix C: Environmental Fate and Ecotoxicological Investigations 14
C.1. Environmental Fate 14
C.1.1. Inherent biodegradability 14
C.2. Ecotoxicological Investigations 14
C.2.1. Acute toxicity to fish 14
C.2.2. Acute toxicity to aquatic invertebrates 15
C.2.3. Algal growth inhibition test 15
C.2.4. Inhibition of microbial activity 16
C.2.5. Acute study in earthworm 16
BIBLIOGRAPHY 18
April 2017 NICNAS
SUMMARY
The following details will be published in the NICNAS Chemical Gazette:
ASSESSMENT REFERENCE / APPLICANT(S) / CHEMICAL OR TRADE NAME / HAZARDOUS chemical / INTRODUCTION VOLUME / USELTD/1944 / CHT Australia Pty Ltd / HANSA® SQ 2050 / ND* / ≤ 150 tonnes per annum / Component of a soil conditioning agent, fabric softener and two-part polyurethane adhesive system
*ND = not determined
CONCLUSIONS AND REGULATORY OBLIGATIONS
Hazard classification
Based on the limited information, the notified polymer cannot be classified according to the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), as adopted for industrial chemicals in Australia.
The environmental hazard classification according to the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) is presented below. Environmental classification under the GHS is not mandated in Australia and carries no legal status but is presented for information purposes.
Hazard classification / Hazard statementAcute category 2 / H401 – Toxic to aquatic life
Chronic category 2 / H411 – Toxic to aquatic life with long lasting effects
Human health risk assessment
Provided that the recommended controls are being adhered to, under the conditions of the occupational settings described, the notified polymer is not considered to pose an unreasonable risk to the health of workers.
When used in the proposed manner, the notified polymer is not considered to pose an unreasonable risk to public health.
Environmental risk assessment
On the basis of its use pattern, the notified polymer is not expected to pose an unreasonable risk to the environment at the maximum use concentration in soil.
Recommendations
Control Measures
Occupational Health and Safety
· A person conducting a business or undertaking at a workplace should implement the following engineering controls to minimise occupational exposure to the notified polymer:
- Enclosed and automated processes, where possible
- Adequate general ventilation and local exhaust ventilation
· A person conducting a business or undertaking at a workplace should implement the following safe work practices to minimise occupational exposure during handling of the notified polymer:
- Avoid contact with skin and eyes
· A person conducting a business or undertaking at a workplace should ensure that the following personal protective equipment is used by workers to minimise occupational exposure to the notified polymer:
− Eye protection
− Gloves
− Coveralls
− Safety boots
· Boom spray applications should be carried out in accordance with the Australian Pesticides and Veterinary Medicines Authority’s Spray Drift management guideline or relevant State or Territory Code of Practice.
· A copy of the SDS should be easily accessible to employees.
· If products and mixtures containing the notified polymer are classified as hazardous to health in accordance with the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) as adopted for industrial chemicals in Australia, workplace practices and control procedures consistent with provisions of State and Territory hazardous substances legislation should be in operation.
Disposal
· Where reuse or recycling are not appropriate, dispose of the notified polymer in an environmentally sound manner in accordance with relevant Commonwealth, state, territory and local government legislation.
Emergency procedures
· Spills or accidental release of the notified polymer should be handled by physical containment, collection and subsequent safe disposal.
Regulatory Obligations
Secondary Notification
This risk assessment is based on the information available at the time of notification. The Director may call for the reassessment of the chemical under secondary notification provisions based on changes in certain circumstances. Under Section 64 of the Industrial Chemicals (Notification and Assessment) Act (1989) the notifier, as well as any other importer or manufacturer of the notified chemical, have post-assessment regulatory obligations to notify NICNAS when any of these circumstances change. These obligations apply even when the notified polymer is listed on the Australian Inventory of Chemical Substances (AICS).
Therefore, the Director of NICNAS must be notified in writing within 28 days by the notifier, other importer or manufacturer:
(1) Under Section 64(1) of the Act; if
- the polymer has a number-average molecular weight of less than 1,000 Da;
or
(2) Under Section 64(2) of the Act; if
- the function or use of the polymer has changed from component of a soil conditioning agent, fabric softener and two-part polyurethane adhesive system, or is likely to change significantly;
- the amount of polymer being introduced has increased, or is likely to increase, significantly;
- the polymer has begun to be manufactured in Australia;
- additional information has become available to the person as to an adverse effect of the polymer on occupational health and safety, public health, or the environment.
The Director will then decide whether a reassessment (i.e. a secondary notification and assessment) is required.
Safety Data Sheet
The SDS of the notified polymer provided by the notifier was reviewed by NICNAS. The accuracy of the information on the SDS remains the responsibility of the applicant.
ASSESSMENT DETAILS
1. APPLICANT AND NOTIFICATION DETAILS
Applicant(s)
CHT Australia Pty Ltd (ABN: 54 006 849 869)
33 Elliot Road
DANDENONG SOUTH VIC 3175
Notification Category
Limited: Synthetic polymer with Mn ³ 1,000 Da.
Exempt Information (Section 75 of the Act)
Data items and details claimed exempt from publication: chemical name, CAS number, molecular and structural formulae, molecular weight, analytical data, degree of purity, polymer constituents, residual monomers, impurities, use details and import volume.
Variation of Data Requirements (Section 24 of the Act)
Variation to the schedule of data requirements is claimed as follows: melting point/boiling point, specific gravity/density, vapour pressure, hydrolysis as a function of pH, partition co-efficient, absorption/desorption, dissociation constant, flash point, flammability limits, autoignition temperature, explosive properties, oxidising properties and reactivity.
Previous Notification in Australia by Applicant(s)
None
Notification in Other Countries
Canada, China and the USA
2. IDENTITY OF CHEMICAL
Marketing Name(s)
HANSA® SQ 2050
Molecular Weight
> 1,000 Da
Analytical Data
Reference NMR, IR and GPC spectra were provided.
3. COMPOSITION
Degree of Purity
˃ 90 %
Loss of Monomers, Other Reactants, additives, Impurities
No degradation, decomposition or depolymerisation of the notified polymer is expected to occur under normal conditions of use.
4. PHYSICAL AND CHEMICAL PROPERTIES
Appearance at 20 ºC and 101.3 kPa: light yellow liquidProperty / Value / Data Source/Justification
Melting Point/Freezing Point / Not determined / Expected to be < 0 °C
Boiling Point / Not determined / Expected to be > 100 °C. Decomposition is expected to occur prior to boiling point being reached.
Vapour Pressure / Not determined / Expected to have a low vapour pressure based on high molecular weight.
Water Solubility / < 0.005 g/L / Measured
Hydrolysis as a Function of pH / Not determined / Significant hydrolysis at environmental pH is not expected given the notified polymer is insoluble in water.
Partition Coefficient (n-octanol/water) / Not determined / The notified polymer is expected to be surface active based on its structure. Therefore, the notified polymer is expected to partition to phase boundaries.
Adsorption/Desorption / Not determined / Expected to partition to soil surface based on its surface activity.
Flash Point / > 100 °C (pressure unknown) / SDS
Autoignition Temperature / Not determined / Not expected to undergo autoignition.
Explosive Properties / Not determined / Contains no functional groups that would imply explosive properties.
Oxidising Properties / Not determined / Contains no functional groups that imply oxidative properties.
Discussion of Properties
For full details of tests on physical and chemical properties, refer to Appendix A.
Reactivity
The notified polymer is expected to be stable under normal conditions of use.
Physical hazard classification
Based on the submitted physico-chemical data depicted in the above table, the notified polymer is not recommended for hazard classification according to the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), as adopted for industrial chemicals in Australia.
5. INTRODUCTION AND USE INFORMATION
Mode of Introduction of Notified Chemical (100%) Over Next 5 Years
The notified polymer will not be manufactured in Australia. It will either be imported in neat form or as a component of end-use products at ≤ 30% concentration.
Maximum Introduction Volume of Notified Chemical (100%) Over Next 5 Years
Year / 1 / 2 / 3 / 4 / 5Tonnes / 10–150 / 10–150 / 10–50 / 10–150 / 10–150
Port of Entry
Major ports in Australia
Identity of Recipient
CHT Australia Pty Ltd
Transportation and Packaging
The notified chemical will be imported in 1,000 L intermediate bulk containers (IBC) which will be distributed to end-users.
The notified polymer will be imported and reformulated into end-use products, in 20 or 205 L drums, containing the notified polymer ≤30% concentration.
The notified polymer and the reformulated products containing the notified polymer will be transported primarily by road to retail stores in packages suitable for retail sale.
Uses
The notified polymer will be used as a:
· soil conditioning agent at 1–5% concentration (> 95% of the total import volume)
· dry-cleaning fabric softener at ≤ 30% concentration (< 5% import volume)
· catalyst in a two-part polyurethane adhesive system at 0.2% concentration (< 5% import volume)
Operation description
The notified polymer will be sent to end-use sites in the original containers or repackaged into 20 or 205 L drums. Where the notified polymer is reformulated (≤ 30% concentration), it will be pumped from the 1,000 L IBC into a blending tank along with solvents and other additives, including emulsifiers. The blended mixture is then pumped to a filling machine and filled into 20 or 205 L drums.
The notified polymer may also be imported in a diluted form (≤ 30% concentration) and repackaged in Australia.
6. HUMAN HEALTH IMPLICATIONS
6.1. Exposure Assessment
6.1.1. Occupational Exposure
Category of Workers
Category of Worker / Exposure Duration (hours/day) / Exposure Frequency (days/year)Transport and warehouse / 2–6 / 12–24
Reformulation workers / 2–4 / 12–24
Farmers / 100–200 / 1–5
Dry-cleaning workers / 100–200 / 200
Polyurethane adhesive plant operators / 10–20 / 24–48
Manufacturing workers using adhesives / 100–200 / 200
Exposure Details
Transport and warehouse workers
Transport and storage workers are not expected to be exposed to the notified polymer except in the unlikely event of an accident.
Reformulation
Reformulation of the notified polymer into end-use products will be largely automated. However, reformulation workers may be exposed (via the dermal and ocular routes) to the neat notified polymer when connecting pumping equipment to containers, during transfer of the contents to the blending tank, and during quality control testing. The reformulation workers may also be exposed to the notified polymer at ≤ 30% concentration during filling processes. The reformulation and filling process will take place in a bunded area which is equipped with local ventilation.
Dermal and ocular exposure of the notified polymer to workers should be mitigated through the use of personal protective equipment (PPE) including coveralls, safety boots, impervious gloves and safety glasses.
Farm workers
Dermal and ocular exposure to the notified polymer at 1–5% concentration to farm workers is possible during transferring containers containing the notified polymer from storage sheds into the loading area, opening containers, and connecting pumping equipment to the onsite fertigation water system. Dermal and ocular exposure to workers should be mitigated by the use of personal protective equipment (PPE) including coveralls, safety boots, impervious gloves and safety glasses.
Farm workers may be exposed (dermal and ocular exposure) to the notified polymer when mixing, connecting and disconnecting equipment, and spraying the notified polymer using a boom-sprayer. Workers may also be exposed to the notified polymer at ≤ 5% concentration if the come into contact with fertigation water. Dermal and ocular exposure to workers should be mitigated through the use of personal protective equipment (PPE) including coveralls, gum boots, impervious gloves and safety glasses.