Icarecleaningptoductsptyltd Phone:0294765392

Section1-IdentificationofChemicalProductandCompany

iCareCleaningPtoductsPtyLtd Phone:0294765392

Substances: Blendofacidicingredientsandsurfactant

TradeName: MagWheelCleaner

ProductUse: MagWheelCleanerandAluminiumbrighteneremulsion.

CreationDate: May,2010

Section2-HazardsIdentification

StatementofHazardousNature

Thisproductisclassifiedas:HazardousaccordingtothecriteriaofNOHSCAustralia.DangerousaccordingtotheAustralianDangerousGoods(ADG)Code.

Dangerousgoodscode:8corrosivesubstances.

RiskPhrases:R34,R41.Causesburns.Riskofseriousdamagetoeyes.

SafetyPhrases:S20,S26,S28,S36,S46,S1/2,S37/39.Whenusing,donoteatordrink.Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandcontactadoctororPoisonsInformationCentre.Aftercontactwithskin,washimmediatelywithplentyofwater.Wearsuitableprotectiveclothing.Ifswallowed,contactadoctororPoisonsInformationCentreimmediatelyandshowthiscontainerorlabel.Keeplockedupandoutofreachofchildren.Wearsuitableglovesandeye/faceprotection.

Subriskclass:nonallocated

ADGClassification:Class8(CAUSTICALKALILIQUID,N.O.S.)

UNNumber:1760 Hazchemcode:2x

EmergencyOverview

PhysicalDescriptionColour:Yellow(Magwheel)clearliquidfor(AluminiumBrightener).Odour:Mildodour.

MajorHealthHazards:causesburns,maycauseseriousdamagetoeyes.

PotentialHealthEffects

Inhalation

ShortTermExposure:Datasuggeststhatthisproductistoxicifinhaledproblemsextendedormajorexposuremayleadtosevereconsequencesincludingdeath.

LongTermExposure:Extendedormajorexposuremayleadtosevereconsequencesincludingdeath.

SkinContact:

ShortTermExposure:Availabledataindicatesthatthisproductislikelytobeabsorbedthroughtheskinandbetoxicbyskinabsorption.

LongTermExposure:Majorskinexposuremayleadtoserioushealthproblemsandevendeathifnot

treatedpromptly.Thisproductisalsocorrosivetoskin.Itwillcauseeffectssuchassevereitchiness

,blisteringandskinreddeninganddeathofskintissues.Exposuremayleadtopermanentdamageincludingscarring.

EyeContact:

ShortTermExposure:thisproductiscorrosivetotheeyes.Itwillquicklycauseintensediscomfortsuchasseverepain,copiouswateringandrednessoftheeyesunlessquicklytreated,corrosiveeffectsleadingtopermanentcorneal

damage,evenblindnesswilloccur.

LongTermExposure:Nodataforhealtheffectsassociatedwithlongtermeyeexposure.

Ingestion:datasuggeststhatthisproductistoxicifswallowed.Ingestionofsmallquantitiesaycauseharmandlargequantitiesmayleadtodeath.Thisproductisalsocorrosiveyothegastrointestinaltract.Willcauseburningtothemouthandthroat,possibleirreversibleproblems,evendeathunlesstreatedpromptly

ShortTermExposure:Datasuggest.

LongTermExposure:Nodataforhealtheffectsassociatedwithlongtermingestion.

CarcinogenStatus:

NOHSC:NosignificantingredientisclassifiedascarcinogenicbyNOHSC.

NTP:NosignificantingredientisclassifiedascarcinogenicbyNTP.

IARC:NosignificantingredientisclassifiedascarcinogenicbyIARC.

Section3-Composition/InformationonIngredients

Ingredients / CASNo / Conc,% / TWA(mg/m3) / STEL(mg/m3)
Sulfuricacid / 7664-93-9 / 3-6 / 1 / 3
Nitricacid
Othernonhazardousingredients
Water / 7697-37-2secret
7732-18-5 / 3-6
10-20approxto100 / 5.2
notsetnotset / 10
notsetnotset

Thisisacommercialproductwhoseexactratioofcomponentsmayvaryslightly.Minorquantitiesofothernon

hazardousingredientsarealsopossible.

TheTWAexposurevalueistheaverageairborneconcentrationofaparticularsubstancewhencalculatedoveranormal8hourworkingdayfora5dayworkingweek.TheSTEL(ShortTermExposureLimit)isanexposurevaluethatshouldnotbeexceededformorethan15minutesandshouldnotberepeatedformorethan4timesperday.Thereshouldbeatleast60minutesbetweensuccessiveexposuresattheSTEL.Theterm"peak"isusedwhentheTWAlimit,becauseoftherapidactionofthesubstance,shouldneverbeexceeded,evenbriefly.

Section4-FirstAidMeasures

GeneralInformation:

YoushouldcallThePoisonsInformationCentreifyoufeelthatyoumayhavebeenpoisoned,burnedorirritatedbythisproduct.Thenumberis131126fromanywhereinAustralia(0800764766inNewZealand)andisavailableatalltimes.HavethisMSDSwithyouwhenyoucall.Obtainasupplyofcalciumgluconategelandleaveitinanearbyunlockedmedicinecabinet.Eyebathsoreyewashstationandsafetydelugeshowersshouldbeprovidedwherethisproductisbeingused.

Swallowed:ifswallowedDONOTinducevomiting.Washmouthwithwaterandgiveaglassofwatertodrink.Eyes:ifthisproductcomesintocontactwitheyes,holdopenandwashwithrunningwater.DONOTtrytoremove

contactlensesunlesstrained.Seekimmediatemedicalattention.

Skin:ifproductgetsonskinimmediatelyremovecontaminatedclothingandwashskinwithsoapandrunningwatertoremoveproductfromskinimmediatelyapplycalciumgluconategeltoaffectedskinseekmedicalattentionifsafetyshowerisavailableuseitpromptly.Becauseofthetoxicityofthisproductspeedmaysavealife.

Inhalation:removefromcontaminatedarea.Applyartificialrespirationifnotbreathing.

Advicetodoctor:Treatsymptomaticallyandnotethetreatmentofthisproduct.

Section5-FireFightingMeasures

FireandExplosionHazards:Thereisnoriskofanexplosionfromthisproductundernormalcircumstancesifitisinvolvedinafire.

ExtinguishingMedia: NotCombustible.

Flashpoint: Doesnotburn.

UpperFlammabilityLimit: Doesnotburn.

LowerFlammabilityLimit: Doesnotburn.

Autoignitiontemperature: Notapplicable-doesnotburn.

FlammabilityClass: Doesnotburn.

Specialfirefightingprocedures:immediatelyevacuatetheareaofunnecessarypersonnel.Whenfightingfiresinvolvingthisproductwearsafetyboots,nonflammableoveralls,gloves,hat,gogglesandrespirator.Allskinareasshouldbecoveredensurethatnospillageentersdrainsorwatercourses.

Unusualfirefighting&explosionhazards:firedecompositionproductsfromthisproductmayformtoxicandcorrosivemixturesinconfinedspaceslikelytodecomposeonlyafterheatingtodrynessfollowedbyfurtherstrongheating.

Stability:thisproductisunlikelytospontaneouslydecompose

Polymerisation:thisproductisunlikelytospontaneouslydecompose

DecompositionProducts:carbondioxideandifcombustionisincompletecarbonmonoxideandsmokes.Oxidesofsulphur.Water.

Materialstoavoid:bases

Section6-AccidentalReleaseMeasures

Accidentalrelease:Intheeventofamajorspill,preventspillagefromenteringdrainsorwatercourses.Evacuatethespillareaanddenyentrytounnecessaryandunprotectedpersonnel.Wearfullprotectivechemicallyresistantclothingincludingeye/faceprotection,gauntletsandselfcontainedbreathingapparatus.SeebelowunderPersonalProtectionregardingAustralianStandardsrelatingtopersonalprotectiveequipment.Suitablematerialsforprotectiveclothingincluderubber,Viton,Nitrile,butylrubber,Barricade,neoprene,Teflon,polyethylene,PE/EVAL,Saranex,Responder.Eye/faceprotectiveequipmentshouldcompriseasaminimum,protectivegoggles.Ifthereisasignificantchancethatvapoursormistsarelikelytobuildupinthecleanuparea,werecommendthatyouusearespirator.Usually,norespiratorisnecessarywhenusingthisproduct.However,ifyouhaveanydoubtsconsulttheAustralianStandardmentionedbelow(section8).

Stopleakifsafetodoso,andcontainspill.Absorbontosand,vermiculiteorothersuitableabsorbentmaterial.Ifspillistoolargeorifabsorbentmaterialisnotavailable,trytocreateadiketostopmaterialspreadingorgoingintodrainsorwaterways.Becauseofthecorrosivenessofthisproduct,specialpersonalcareshouldbetakeninanycleanupoperation.Sweepupandshovelorcollectrecoverableproductintolabelledcontainersforrecyclingorsalvage,anddisposeofpromptly.Recyclecontainerswhereverpossibleaftercarefulcleaning.Afterspills,washareapreventingrunofffromenteringdrains.Ifasignificantquantityofmaterialentersdrains,adviseemergencyservices.Contaminatedareamaybeneutralisedbywashingwithwaterodilutealkali.maybesuitable.Thismaterialmaybesuitableforapprovedlandfill.Ensurelegalityofdisposalbyconsultingregulationspriortodisposal.Thoroughlylaunderprotectiveclothingbeforestorageorre-use.Adviselaundryofnatureofcontaminationwhensendingcontaminatedclothingtolaundry.

Section7-HandlingandStoragetransport

Handling:Keepexposuretothisproducttoaminimum,andminimisethequantitieskeptinworkareas.CheckSection8ofthisMSDSfordetailsofpersonalprotectivemeasures,andmakesurethatthosemeasuresarefollowed.Themeasuresdetailedbelowunder"Storage"shouldbefollowedduringhandlinginordertominimiserisksto

personsusingtheproductintheworkplace.Also,avoidcontactorcontaminationofproductwithincompatible

materialslistedinSection10.

Storage:.ThisproductisclassedasUN1760,DangerousgoodsClass8CorrosiveSubstancesshallnotbeloadedinthesamevehicleorpackedinthesamefreightcontainerwithClasses1(Explosives),4.3(DangerousWhenWetSubstances),5.1(OxidisingAgents),5.2(OrganicPeroxides),6(ToxicSubstanceswheretheToxicSubstancesarecyanidesandtheCorrosivesareacids),7(RadioactiveSubstances),Foodstuffsandfoodstuffempties.TheymayhoweverbeloadedinthesamevehicleorpackedinthesamefreightcontainerwithClasses2.1(FlammableGases),

2.2(Non-Flammable,Non-ToxicGases),2.3(PoisonousGases),3(Flammableliquids),4.1(FlammableSolids),4.2(SpontaneouslyCombustibleSubstances),6(ToxicSubstancesexceptwheretheToxicSubstancesarecyanidesandtheCorrosivesareacids)and9(MiscellaneousDangerousGoods).

ThisproductisaScheduledPoisonS7Observeallrelevantregulationsregardingsale,transportandstorageofthisscheduleofpoison.Storeinacool,wellventilatedarea.Checkcontainersperiodicallyforcorrosionandleaks.Containersshouldbekeptclosedinordertominimisecontamination.Makesurethattheproductdoesnotcomeintocontactwithsubstanceslistedunder"Incompatibilities"inSection10.Ifyoukeepmorethan1000kgor1000LofCorrosiveSubstancesofPackagingGroupIII,youareprobablyrequiredtolicensethepremisesornotifyyourDangerousGoodsauthority.Ifyouhaveanydoubts,wesuggestyoucontactyourDangerousGoodsauthorityinordertoclarifyyourobligations.Checkpackaging-theremaybefurtherstorageinstructionsonthelabel.

Section8-ExposureControlsandPersonalProtection

ThefollowingAustralianStandardswillprovidegeneraladviceregardingsafetyclothingandequipment:

RiskphrasesareR34,R41,R23/24/25.Causeburns.Riskofseriousdamagetoeyes.Toxicbyinhalationincontactwithskinandifswallowed.

ExposureStandards:

Atimeweightedaverage(twa)hasbeenestablishedforHydrogenfluoridepresentinsignificantquantitiesinthisproduct.Thisvalueis2.6mg/m3.ThecorrespondingSTELlevelis“peak”.TheSTEL(shorttermexposurelimit)isanexposurevaluethatshouldnotbeexceededformorethan15minutesandshouldnotberepeatedformorethan4timesperday.Thereshouldbeatleast60minutesbetweensuccessiveexposuresattheSTEL.TheexposurevalueattheTWAistheaverageisairborneconcentrationofaparticularsubstancewhencalculatedoveranormal8hourworkingdayfora5dayworkingweek.Seeingredientssectiononpage1ofdatasheet.Theterm“peak”isusedwhentheTWAlimit,becauseoftherapidactionofthesubstances,shouldneverbeexceededevenbriefly.

EngineeringControls:

Inindustrialsituation,concentrationvaluebelowtheTWAvalueshouldbemaintained.Valuemaybereducedbyprocessmodification,useoflocalexhaustventilation,capturingsubstancesatthesource,orothermethods.Ifyoubelieveairborneconcentrationofmists,dustorvapourarehigh,youareadvisedtomodifytheprocessorenvironmenttoreducetheproblem.

PersonalProtection:

ProtectiveGloves:Impermeableprotectiveglovesmustbewornwhenyouareusingthisproduct.Failuretodoso

willleadtoburnstotheskin,andlikelyscarring.Allskinareasmustbecoveredwhenyouareusingthisproduct.Gloveselectioncanbemadeonthebasisofthefollowingresistanceforsodiumhydroxidebasedproducts.Neoprene:Excellent,Rubberexcellentnitrile;excellentButyl:excellentforhelpinselectingequipmentconsultAS

2161.

EyeProtection:Youreyesmustbecompletelyprotectedfromthisproduct.Allsurroundingskinareasmustbecovered.Eyecontactwillproveatbeatpainfulanwillprobablycauseirreversibledamageifcontactisotherthan

brief.ConsultAS1336andAS/NZS1337foradviceonindustrialeyeprotection..Emergencyeyewashfacilitiesmust

alsobeavailableinanareaclosetowherethisproductisbeingused.

SkinProtection:Becauseofthedangerousnatureofthisproduct,makesurethatallskinareasarecompletelycoveredbyimpermeablegloves,overalls,haircovering,andapronandfaceshield.Seebelowforsuitablematerial

types.

ClothingProtectiveMaterialTypes:Cleanimpermeableoverallsorprotectiveclothingshouldbeworn,

preferablywithanapron.Ifcontaminated,laundryshouldbeadvisedofthenatureofthecontamination,or,preferably,clothingshouldbedestroyed.ConsultAS2919foradviceonindustrialclothing.

Respirator:Becauseofthedangerofthisproducttotherespiratorysystem,itshouldonlybeusedwhen

theuserisequippedwithfullrespiratoryequipment,unlessusedinafumecupboardorotherpositivelyventilatedareadesignedfortheprotectionofusers.Forhelpselectingsuitableequipment,consultAS/NZS1715

SafetyBoots:Wearingsafetybootsinindustrialsituationisadvisory.ConsultAS/NZS2210foradviceon

occupationalprotectivefootwear.

Alwayswashhandbeforesmoking;eatingorusingthetoilet.Washcontaminatedclothingandotherprotectiveequipmentbeforestoringore-using.

Section9-PhysicalandChemicalProperties:

PhysicalDescriptioncolour: Clearliquid.

Odour: Sharpbutmildodour.

BoilingPointVapourPressure. Approximately100°Cat100kPa.

Freezing/MeltingPoint: Approximately0°C.

Volatiles: Watercomponent.

VapourDensity: Nodata.

SpecificGravity: Nodata.

WaterSolubility: Completelysoluble.pH: CorrosiveVolatility: Nodata.

OdourThreshold: Nodata.

EvaporationRate: Nodata.

CoeffOil/waterDistribution: Nodata

Autoignitiontemp: Notapplicable-doesnotburn.

Corrosiveness: corrosivetohumantissuesandtomanymetals

Section10-StabilityandReactivity

ConditionstoAvoid:Handleandopencontainerscarefully.

Incompatibilities:Bases

Polymerisation:Thisproductwillnotundergopolymerisationreactions.

Section11-ToxicologicalInformation

Section12-EcologicalInformation

Insufficientdatatobesureofstatus.

Section13-DisposalConsiderations

Disposal:Containersshouldbeemptiedascompletelyaspracticalbeforedisposal.Ifpossible,recyclecontainerseitherin-houseorsendtorecyclecompany.Ifthisisnotpractical,sendtoacommercialwastedisposalsite.PleasedoNOTdisposeintosewersorwaterways.

Section14-TransportInformation

HazchemCode:2xDangerousGoodsClass:Class8,CorrosiveSubstances.PackagingGroup:III

Class8CorrosiveSubstancesshallnotbeloadedinthesamevehicleorpackedinthesamefreightcontainerwithClasses1(Explosives),4.3(DangerousWhenWetSubstances),5.1(OxidisingAgents),5.2(OrganicPeroxides),6(ToxicSubstanceswheretheToxicSubstancesarecyanidesandtheCorrosivesareacids),7(RadioactiveSubstances),Foodstuffsandfoodstuffempties.TheymayhoweverbeloadedinthesamevehicleorpackedinthesamefreightcontainerwithClasses2.1(FlammableGases),2.2(Non-Flammable,Non-ToxicGases),2.3(PoisonousGases),3(Flammableliquids),4.1(FlammableSolids),4.2(SpontaneouslyCombustibleSubstances),6(ToxicSubstancesexceptwheretheToxicSubstancesarecyanidesandtheCorrosivesareacids)and9(MiscellaneousDangerousGoods).

Section15-RegulatoryInformation

AICS:AllofthesignificantingredientsinthisformulationaretobefoundinthepublicAICSDatabase.

Section16-OtherInformation

ThisMSDScontainsonlysafety-relatedinformation.Forotherdataseeproductliterature.

Acronyms:

ADGCode AustralianCodefortheTransportofDangerousGoodsbyRoadandRail

AICS AustralianInventoryofChemicalSubstances

CASNumber ChemicalAbstractsServiceRegistryNumber

HazchemCode Emergencyactioncodeofnumbersandlettersthatprovideinformationtoemergencyservicesespeciallyfirefighters

IARC InternationalAgencyforResearchonCancer

NOHSC NationalOccupationalHealthandSafetyCommission

NOS Nototherwisespecified

NTP NationalToxicologyProgram(USA)

R-Phrase RiskPhrase

SUSDP StandardfortheUniformSchedulingofDrugsPoisons

UNNumber UnitedNationsNumber

THISMSDSSUMMARISESOURBESTKNOWLEDGEOFTHEHEALTHANDSAFETYHAZARDINFORMATIONOFTHEPRODUCTANDHOWTOSAFELYHANDLEANDUSETHEPRODUCTINTHEWORKPLACE.EACHUSERMUSTREVIEWTHISMSDSINTHECONTEXTOFHOWTHEPRODUCTWILLBEHANDLEDANDUSEDINTHEWORKPLACE.

IFCLARIFICATIONORFURTHERINFORMATIONISNEEDEDTOENSURETHATANAPPROPRIATERISKASSESSMENTCANBEMADE,THEUSERSHOULDCONTACTTHISCOMPANYSOWECANATTEMPTTOOBTAINADDITIONALINFORMATIONFROMOURSUPPLIERS

OURRESPONSIBILITYFORPRODUCTSSOLDISSUBJECTTOOURSTANDARDTERMSANDCONDITIONS,ACOPYOFWHICHISSENTTOOURCUSTOMERSANDISALSOAVAILABLEONREQUEST.

Pleasereadalllabelscarefullybeforeusingproduct.ThisMSDSispreparedinaccordwiththeNOHSCdocument“NationalCodeofPracticeforthePreparationofMaterialSafetyDataSheets”2ndEdition[NOHSC:2011(2003)]

MATERIALSAFETYDATASHEET