Expression of borage Δ6 desaturase in Saccharomyces cerevisiae and oilseed crops

ArticleinCanadian Journal of Botany 80(1)·February 2011

Impact Factor: 1.40 · DOI: 10.1139/b01-130

Xiao Qiu

30.38 · University of Saskatchewan

Haiping Hong

12.78 · BASF Corporation

12.78

5 publications 287 citations

Haiping Hong

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BASF Corporation

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GB Development

Nagamani Datla

4 publications 282 citations

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Samuel L MacKenzie

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David Taylor

32.83 · National Research Council Canada

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Terry L Thomas

37.70 · Texas A&M University

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Terry L Thomas

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Abstract

The borage Δ6 desaturase is a modular protein that contains a cytochrome b5-like domain attached to the N-terminus of the main catalytic domain. When the full-length open reading frame was expressed in two types of Saccharomyces cerevisiae strains, the endogenous cytochrome b5-disrupted strain and the cytochrome b5-competent wild type strain, the expressed enzyme introduced a double bond at the Δ6 position into the endogenous substrates 16:1(9) and 18:1(9), and also into the exogenously fed fatty acid substrates 18:2(9,12) and 18:3(9,12,15). However, the preferred substrates of the enzyme when expressed in yeast were 18:2(9,12) and 18:3(9,12,15), whereas 16:1(9) and 18:1(9) were relatively poor substrates. When the partial desaturase sequence with a deletion of the cytochrome b5-like domain at the N-terminus was introduced into the yeast strains, the truncated enzyme could not desaturate any of the supplied substrates. Introduction of the full-length cDNA into flax (Linum usitatissimum L.) under the control of a constitutive (35S) promoter resulted in accumulation of the two Δ6 desaturated fatty acids (18:3(6,9,12) and 18:4(6,9,12,15)), in one elite line, forming up to 22% of the total fatty acids in the stem, 19% in the root, and 11% in the leaf. Introduction of the desaturase into Brassica juncea (L.) Czern. under the control of the Brassica napus L. napin promoter resulted in accumulation of the Δ6 desaturated fatty acids at levels of up to 13% of the total fatty acids in mature seeds.Key words: borage, Δ6 desaturase, γ-linolenic acid, stearidonic acid, Brassica juncea, flax.

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Haiping Hong

12.78 · BASF Corporation

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