1020A Verification Checkout

Verify Pump Calibration

___ Ensure that acid pump is delivering 100ul per injection.

___Ensure that chase pump is delivering 100ul per injection.

Model 1020A Leak Test

___ Perform leak test at 12psi for 2min. +/-0.5psi verifying system is leak free.

1020 Flow Rates

Verify the following flows:

Gas Pressure 18psi (16-20psi) ______

Injector Flow port 30ml+/- 3ml ______

Alternate Flow port 30ml+/-3ml ______

IR Purge Flow 30ml+/- 3ml ______

Drier (Nafion) Flow 300ml+/-25ml ______

Carrier Flow (side of inj cap)95ml+/-5ml _____

NDIR Outlet Flow 150ml+/-10ml ______

If 1051 Autosampler is used

___ Verify septum flow is 135ml(+/-15ml) ______

Set the furnace to 680 degrees C.

TC Offset Value ______

Verify sample loop is calibrated

50ul +/-5ul ______

100ul +/-10ul ______

200ul +/-10ul ______

Verify drain and needle alignment

___Fill the TIC chamber with 100 phosphoric injections and drain. Verify drain in

<25 seconds.

___ Verify injection needle alignment is centered.

LIST Coefficients found on IR Detector

Coefficients

C0______e______

C1______e______

C2______e______

C3______e______

C4______e______

C5______e______

1020A Cleanup

___ Run TC water blanks until area counts are <500cts. Run TIC water Blanks until area counts are <300cts.

TC Blank Value

Once the system has stabilized and cleaned up. Run 10 replicates of clean DI water, manually average the last 3 replicates. The average will be entered as the TC blank value.

TC Blank Value ______

TC CALIBRATION

___ Run a multi point calibration with 100ul loop at 3 reps.

TC Standards (KHP) / Acceptance Criteria / Actual %RSD
0ppm KHP / <300 counts
10ppm KHP / <2.0%RSD
100ppm KHP / <2.0%RSD
1000ppm KHP / <2.0%RSD
RF / 0.15-0.19
Offset / 0ppm +/-50%
R2 (Correlation Coeff.) / >0.9990

____Run TC Water blanks <300cts.

TC CHECK STANDARDS

___ Run multi point check standards with a 100ul loop at 3 reps each.

TC CHK STD / Acceptance Criteria / Actual %RSD / Reported PPM
0ppm TC CHK / <300 counts
10ppm TC CHK / <2.0% RSD, +/-.4ppm
100ppm TC CHK / <2.0% RSD, +/-4ppm
1000ppm TC CHK / <2.0% RSD, +/-40ppm

___ Run DI water cleanup until counts are <300 for TC.

If running 1051 Autosampler perform the following.

1051 Autosampler Verification

___ Verify needle wash pump is delivering 1.00ml per injection.

___ Verify Pre-Acid pump is delivering 100ul +/-5 per injection.

___ Calibrate Carousel Home position and verify needle depth at 95%.

___ Analyze the following samples with the 1020A/1051/Wintoc.

___ Vial 1- DI water at 3 reps

___ Vial 20 – 100ppm KHP at 3 reps each

TC 96-104ppm, <2.5%RSD

Actual ______ppm

______%RSD

___ Vial 53 – DI water at 3 reps each