PUBLICATIONS - Didier ASTRUC: 2000- 2005

And Selected Reviews: 1983-2000

2005

271The Metathesis Reactions: From Historical Perspective to Recent Development

D. Astruc

New .J. Chem., 2005, 29, 42-56.

272Dendritic Phosphonates and the in situ Assembly of Polyoxophosphotungstates: Synthesis and Catalytic Epoxidation with Hydrogen Peroxide.

M. V. Vasylyev, D. Astruc, R. Neumann

Adv. Synth. Catal. 2005, 347, 39-43.

273Mo6Br8-Cluster-cored Organometallic Stars and Dendrimers

D. Méry, C. Ornelas, J. Ruiz, J. Rodriguez, D. Astruc, S. Cordier, K. Kiraki, C. Perrin

C. R. Chimie, special issue on “New molecular architectures built from metallic nanoclusters”, C. Perrin, A. Perrin, D. Fenske Eds, 2004, 8, 1789-1797.

274La catalyse métallodendritique: une contribution efficace à la chimie verte

D. Astruc

C. R. Chimie, 2005, 8, 1101-1107, (special Francis Sécheresse issue)

275Giant Dendrimer Construction: Hydroboration vs. Hydrosilylation as a Growth Strategy

J. Ruiz, G. Lafuente, S. Marcen, C. Ornelas, S. Lazarre, E. Cloutet, J.-C. Blais,

D. Astruc

ACS Sym. Series N°XXX, Recent Advances in Main-Group Chemistry, accepted for publication on October 15, 2004 (special issue dedicated to Alan H. Cowley)

276Metallodendritic Catalysis for Redox and C-C Bond Formation Reactions: A Step towards Green Chemistry

D. Astruc, K. Heuze, S. Gatard, D. Méry, S. Nlate, L. Plault

Advan Syn. Catal., 2005, 347, 329-338 (special Richard R. Schrock issue)

277Gold-nanoparticule-cored Polyferrocenyl Dendrimers: Modes of Synthesis and Functions as Exoreceptors of Biologically Important Anions and Re-usable Redox Sensors

M.- C. Daniel, J. Ruiz, S. Nlate, D. Astruc

J. Inorg. Organomet. Polym. Mat., 2005, 15 (1) 107-119

278Inhibition of the electrochemistry of ferrocenes by polyamine dendrimers and the key role of hydrogen-bonding with hydroxy groups

M.-C. Daniel, J. Ruiz, D. Astruc

Chem. Commun. 2005, 1569-1571

279Metallocenes as references for the determination of redox potentials by cyclic voltammetry: permethylated iron and cobalt sandwich complexes, inhibition by polyamine dendrimers and the role of hydroxy-containing ferrocenes

J. Ruiz , M.-C. Daniel, D. Astruc, Can. J. Chem., 2005 In press (special Arthur Carty issue)

280The Simple Hexapyridine Cluster [Mo6Br8Py6][OSO2CF3]4 and Substituted Hexapyridine Clusters Including a Cluster-cored Polyolefin Dendrimer

D. Méry, L. Plault, S. Nlate, D. Astruc, S. Cordier, K. Kirackci, C. Perrin,

Z. Anorg.. Allgem. Chem. 2005, 631, 2746-2750 (special Herbert Roesky issue).

281Efficient Dendritic Diphosphino Pd(II) Catalysts for the Suzuki Reaction of Choroarenes

J. Lemo, K. Heuzé, D. Astruc

Org. Letters, 2005, 7 (11) 2253-2256.

282Synthesis of 9- and 27-Armed Tetrakis(diperoxotungsto)phosphate-cored Dendrimers and their Use as Recoverable and Re-usable Catalysts in the Oxidation of Alkenes, Sulfides and Alcohols with Hydrogen Peroxide

S. Nlate, L. Plault, D. Astruc

Chem. Eur. J., 2005, ASAP

283Inorganic Mo6X14 clusters and their functionalization

S. Cordier, K. Kirackci, C. Perrin, D. Méry, D. Astruc,

Inorg. Chim. Acta, 2005, In press (special Gérard van Koten issue)

284Nanoparticles as Recyclable Catalysts: the Fast-growing Frontier between Homogeneous and Heterogeneous Catalysts

D. Astruc, F. Lu, J. Ruiz Aranzaes

Angew. Chem. 2005 , 117, 000; Angew. Chem. Int. Ed., 2005, 44, ASAP

285Mono-and Bifunctionalization of Polyallyl Dendrimers by Metathesis

C. Ornelas, D. Méry, J. Ruiz, J.-C. Blais, E. Cloutet, D. Astruc

D. Astruc, F. Lu, J. Ruiz Aranzaes

Angew. Chem. 2005 , 117, 000; Angew. Chem. Int. Ed., 2005, 44, ASAP

286Assembly of Dendrimers with Redox-ActiveClusters [CpFe(3-CO)]4 at the Peripheryand Application to Oxo-anion and Adenosyne-5’-Triphosphate (ATP) Sensing

J. Ruiz Aranzaes, C. Belin, D. Astruc,

Angew. Chem. 2005 , 117, 000; Angew. Chem. Int. Ed., 2005, 44, ASAP

287Synthesis of Ferrocenylazobenzene-attached Dendrimers and Light-induced Redox-Activity Control of Their Modified Electrodes

M.-C. Daniel, J. Ruiz, D. Astruc, A. Sakamoto, H. Nishihara

Chem. Lett., in press

288 Metallodendritic Catalysis: Major Concepts and Recent Progress

D. Méry and D. Astruc

Coord. Chem. Rev. in press

2004

256Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-size Related Properties, and Applications towards Biology, Catalysis and Nanotechnology

M-C. Daniel, D. Astruc

Chem. Rev. 2004, 104, 293-346

257CpFe+-induced Hexafunctionalzation of Hexamethylbenzene in [FeCp(6-C6Me6)][PF6] using Dendronized Benzyl Bromide Derivatives at Room Temperature for the Direct Synthesis of Metallodendrimers

S. Nlate, J.-C. Blais, D. Astruc

Inorg. Chim. Acta, 2004, 357, 1670-1674 (special issue dedicated to Helmut Werner).

258Coupling Multiple Benzylic Activation of Simple Arenes by CpFe+ with Multiple Alkene Metathesis using Grubbs Catalysts: An Efficient Carbon-Carbon Bond Formation Strategy Leading to Polycycles, Cyclophanes, Capsules, and Polymeric Compounds and their CpFe+ Complexes.

V. Martinez, J.-C. Blais, G. Bravic, D. Astruc

Organometallics, 2004, 23, 861-874.

259Synthesis, Chemistry, DFT Calculations and ROMP Activity of Monomeric Benzylidene Complexes Containing a Chelating Diphosphine and of Four Generations of Metallodendritic Analogues. Positive and Negative Dendritic Effects and Formation of Dendritic Ruthenium-Polynorbornene Stars

S. Gatard, S. Kahlal, D. Méry, S. Nlate, E. Cloutet, J.-Y. Saillard, D. Astruc

Organometallics, 2004, 23, 1313-1324.

260Synthesis of Dendritic Polyoxometalate Complexes Assembled by Ionic Bonding and Their Function as Recoverable and Reusable Oxidation Catalysts

L. Plault A. Hauseler, S. Nlate, D. Astruc, Sylvain Gatard, Ronny Neumann

Angew. Chem. 2004, 116, 2984-2988; Angew. Chem. Int. Ed.2004, 43, 2924-2928.

.

261Copper-Free Monomeric and Dendritic Palladium Catalysts for the Sonogashira Reaction: Substituent Effects, Synthetic Applications, and the Recovery and Re-Use of the Catalysts

K. Heuzé, D. Méry, D. Gauss, J.-C. Blais, D. Astruc

Chem. Eur. J., 2004, 10, 3936-3944.

262Electrochemistry and Electron-Tranfer Chemistry of Metallodendrimers,

D. Astruc, M.-C. Daniel, N. Nlate, J. Ruiz

In Trends in Electrochemistry, Rédacteurs: A. J. L. Pombeiro, C. Amatore, Marcel Dekker, New York, 2004, pp. 283-310 (Chapter 9).

263La métathèse: de Chauvin à la chimie verte

D. Astruc

L’Actualité Chimique, March 2004, pp. 3-11, n° 273.

264Organoiron Activation Combined with Electron- and Proton Transfer: Implications in Biology, Organic Synthesis, Catalysis and Nanosciences.

D. Astruc

J. Organomet. Chem., 2004, 689, 4332-4344 (invited review article for the 40th birthday of JOM)

265Organometallic Syntheses of Hexa- and Nonanitrile Ligands and Their Ruthenium Complexes

C. Ornelas, J. Ruiz, J.-C. Blais, J. Rodrigues, D. Astruc

Organometallics, 2004, 23, 4271-4276

266Assemblies of Redox-Active Metallodendrimers Using Hydrogen Bonding for the Electrochemical Recognition of the H2PO4- and Adenosine-triphosphate (ATP2-) Anions

M.-C. Daniel, F. Ba, J. Ruiz, D. Astruc

Inorg. Chem., 2004, 43, 8649-8657

267Synhesis, Catalytic Activity in Oxidation Reactions, and Recyclability of Stable Polyoxometalate-Centred Dendrimers

S. Nlate, D. Astruc, R. Neumann

Adv. Synth. Catal. 2004, 346, 1445-1448

268Dendrimers and gold nanoparticles as exo-receptors sensing biologically important anions

D. Astruc, M.-C. Daniel, J. Ruiz

Chem. Commun (feature article), 2004, 2637-2649.

269Palladium-dodecanethiolate nanoparticles as stable and recyclable catalysts for the Suzuki-Miyaura reaction of aryl halides under ambient conditions

F. Lu, J. Ruiz, D. Astruc

Tetrahedron Lett. 2004, 9443-9445.

270Synthesis of Monomeric and Dendritic Ruthenium Benzylidene cis-bis-tertiobutyl phosphine Complexes that Catalyze the ROMP of Norbornene under Ambient Conditions

D. Méry, D. Astruc

J. Mol. Cat. A: Chemical, 2004, 227, 1-5.

2003

242Dendritic Stars by Ring-Opening-Metathesis Polymerization From Ruthenium-Carbene Dendrimers

S. Gatard, S. Nlate, E. Cloutet, G. Bravic, J.-C. Blais, D. Astruc

Angew. Chem. Int. Ed., 2003, 42, 452-456

243Organometallic Chemistry at the Nanoscale: Dendrimers for Redox Processes and Catalysis

D. Astruc

Pure Appl. Chem. 2003, 75, N° 4, 461-481.

(article relatif à la conférence plénière du XXème ICOM Corfu)

244Supramolecular H-bonded Assemblies of Redox-Active Metallodendrimers and Positive and Unusual Dendritic Effects on the Recognition of H2PO4-.

M.-C. Daniel, J. Ruiz, D. Astruc,

J. Am. Chem. Soc., 2003, 125, 1150-1151.

245Convergent Dendron Approach Using a Phenol Triallyl Building Block: Synthesis of a Phenol Dendron Containing 27 Allyl Termini

S. Nlate, J. -C. Blais, D. Astruc

New J. Chem., 2003, 27, 178-183.

246Nanoscopic Assemblies Between Supramolecular Redox Active Metallodendrons and Gold Nanoparticles: Syntheses, Charaterization and Selective Recognition of H2PO4-, HSO4- and Adenosine-5’-Triphosphate (ATP2-) Anions

M.-C. Daniel, J. Ruiz, S. Nlate, J.-C. Blais, D. Astruc

J. Am. Chem. Soc., 2003, 125, 2617-2628

247Redox-Robust Pentamethylamidoferrocenyl Metallodendrimers that Cleanly and Selectively Recognize the H2PO4- Anion.

J. Ruiz, M.-J. Ruiz-Medel, M.-C. Daniel, J.-C. Blais, D. Astruc

Chem. Commun., 2003, 464-465.

248Construction of Giant Dendrimers Using a Tripodal Buiding Block

J. Ruiz, G. Lafuente, S. Marcen, C. Ornelas, S. Lazare, E. Cloutet, J.-C. Blais,

D. Astruc

J. Am. Chem. Soc., 2003, 125, 7250-7257.

249Synthesis of Five Generations of Redox Stable Pentamethylamidoferrocenyl Dendrimers and Compared Use of Amidoferrocenyl- and Pentamethylamidoferrocenyl Dendrimers As Electrochemical Exoreceptors for the Selective Recognition of H2PO4-, HSO4- and Adenosyl-5’-Triphosphate (ATP) Anions. Stereoelectronic and Hydrophobic Roles of the Cp Permethylation.

M.-C. Daniel, J.Ruiz, J.-C. Blais, N. Daro, D. Astruc

Chemistry, Eur. J. 2003, 9, 4371-4379.

250Nano-scale Metallodendritic Complexes In Electron-Transfer Processes and Catalysis

D. Astruc, J.-C. Blais, M.-C. Daniel, V. Martinez, S. Nlate and J. Ruiz

Macromolecular Symposia, rédacteur: A. Abd-El-Aziz Ed., Kluwer, Dordrecht,2003, 196 (1), 1-25.

251Metallodendrimers and Dendronized Gold Colloids as Nanocatalysts, Nanosensors and Nanomaterials for Molecular Electronics

D. Astruc, J.-C. Blais, M.-C. Daniel, S. Gatard, S. Nlate andJ. Ruiz

Comptes Rendus Chimie, In Dendrimers and Nanosciences, D. Astruc Guest Ed.,2003, 6, 1117-1127.

252A Very Efficient, Copper-free Palladium Catalyst for the Sonogashira Reaction with Aryl Halides:

D. Mery, K. Heuzé, D. Astruc

Chem. Commun.,2003, 1934-1935.

253A fast organometallic route from p.xylene, mesitylene and p.diisopropylbenzene to organoiron and polycyclic aromatic cyclophane capsules and polymers.

V. Martinez, J.-C. Blais, D. Astruc

Angewandte Chem., 2003, 42, 4366-4369.

254 Copper-free Recoverable Dendritic Catalysts for the Sonogashira Reaction

K. Heuze, D. Mery, D. Gauss, D. Astruc

Chem. Commun., 2003,2274-2275.

282Química Organometálica

Didier Astruc

Traduction espagnole et mise à jour de “Chimie Organométallique”.

Editorial Reverté, Barcelone (550 pp), 2003

2002

230 CpFe+-Induced Hexafunctionalization of Hexamethylbenzene with Dendrons for the Direct Synthesis of Redox-Active Iron-Centered Metallodendrimers

Sylvain Nlate, Yolanda Nieto, Jean-Claude Blais, Jaime Ruiz, Didier Astruc

Chemistry, A European Journal, 2002, 8, 171-176

231Heterodinuclear Iridium Cyclooctadiene Complexes with the

(5-C5H5)Fe(6(1,1-di(2-propenyl)-3–butenyl)benzene)]+ ligand

S. Marcen, M. V. Jimenez, I. T. Dobrinovitch, F. Lahoz, L. Oro, J. Ruiz, D. Astruc

Organometallics, 2001, 20, 626-630.

232General Route from Simple Methyl, Alkyl and Cycloalkyl Arenes to Polycyclic Cyclopentenyl Aryl Derivatives. The CpFe+ as an Activator and Tag

V. Martinez, J.-C. Blais, D. Astruc

Organic Letters, 2002, 4 , 651-654.

233Successive Activation and Perfunctionnalization of Arenes by p-Complexation to CpFe+ and Cp*Ru+ for the Construction of Organometallic Stars and Dendrimers

B. Alonso, J.-C. Blais, D. Astruc

Organometallics, 2002, 21, 1001-1003.

234Dendrimers Containing Ferrocenyl- or Other Transition-Metal Sandwich Groups

B. Alonso, E. Alonso, D. Astruc, J.-C. Blais, L. Djakovitch, J.-L. Fillaut, S. Nlate., F. Moulines, S. Rigaut, J. Ruiz, V. Sartor, C. Valério

Advances. in Dendritic Macromolecules; Newkome, G. Ed.; Elsevier.: Amsterdam, Vol. 5, 2002, pp. 89-127.

235Green Organometallic Chemistry: CpFe+-induced Amination of Chloroarenes in Water

F. Moulines, M. Kalam-Alami, V. Martinez, D. Astruc

J. Organomet. Chem., 2002, 643-644, 125-129.

236Supramolecular Gold Nanoparticles for the Redox Recognition of Oxoanions: Syntheses, Titrations, Stereoelectronic Efects, and Selectivity

A. Labande, J. Ruiz, D. Astruc,

J. Am. Chem. Soc. 2002, 124, 1782-1789.

237Molecular batteries: synthesis and characterization of a dendritic 19-electron Fe(I) complex that reduces C60 to its mono-anion.

J. Ruiz, C. Pradet, D. Varret, D. Astruc

Chem. Commun., 2002, 1108-1109

238Water-soluble Mono- and Star-shaped Hexanuclear Functional Organometallic Catalysts for Nitrate and Nitrite Reduction in Water: Syntheses and Electroanalytical Study

S. Rigaut, M.-H. Delville, J. Losada, D. Astruc

Inorg. Chim. Acta, 2002, 334, 225-242.

239Arene Chemistry: from Historical Notes to the State of the Art

D. Astruc,

DansModern Arene Chemistry. Rédacteur: D. Astruc, Wiley-VCH, Weinheim, 2002, pp 1-19

240CpFe+ Induced Activation of Simple Arenes for the Synthesis of Dendritic Molecular Batteries

D. Astruc, S. Nlate, J. Ruiz,

DansModern Arene Chemistry. Rédacteur: D. Astruc, VCH, Weinheim, 2002,

pp. 400-434.

282Homogeneous Electrocatalysis

D. Astruc

Dans le Handbook “Applied Homogeneous Catalysis with Organometallic Compounds”, 2ème Ed., Rédacteur: B. Cornil, W. A. Herrmann, Wiley-VCH, 2002, Ch. 3.2, pp. 1046-1059.

2001

225Electron-Transfer Reactions of Organometallic Electron-Reservoir Complexes and Other Redox Reagents in Transition-Metal Chemistry

D. Astruc

Dans Handbook Electron Transfer in Chemistry, V. Rédacteur: Balzani Ed.; VCH-Wiley, New York; 2001, Vol 2, Rédacteurs associés: P. Mattay, D. Astruc; Section 2: f Inorganic and Organometallic Coumpounds; Chapitre 4, pp. 714-803.

226Metallodendrimers towards Enzyme Mimics and Molecular Electronics: New-Generation Catalysts, Sensors and Molecular Batteries †

B. Alonso, D. Astruc, J.-C. Blais, S. Nlate, S. Rigaut, J. Ruiz, V. Sartor, C. Valério

C. R. Acad. Sci., Paris, Série II c, 2001, 4, 173-180, numéro dédié à Olivier Kahn

227Des réservoirs d’électron aux dendrimères: multiples facettes et applications

D. Astruc,

L’Actualité Chimique, 2000, juillet-août, 3-12.

228Dendritic Catalysts and Dendrimers in Catalysis

D. Astruc, F. Chardac

Chem. Rev., 2001, 101, 2991-3031

229Gold Nanoparticles Containing Redox-Active Supramolecular Dendrons

that Recognize H2PO4-

M.-C. Daniel, J. Ruiz, S. Nlate, J. Palumbo, J.-C. Blais, D. Astruc

Chem. Commun., 2001, 2000-2001.

2000

212Synthesis and X-ray Crystal Structure of Decamethylrhodocenium Hexafluorophosphate

D. Buchholz, L. Zsolnai, G. Huttner, D. Astruc

J. Organomet. Chem., 2000, 593-594, 494-496, numéro dédié à Fausto Calderazzo

213Dendrimers: Introduction to an Exploding Field

D. Astruc

Education in Advanced Chemistry, vol.7, Perspectives in Coordination Chemistry, A. Rédacteurs: Trzeciak, P. Sobota, J. J. Ziolkowski, Wydawnictwo Poznanskie, Poznan,-Wroclaw, 2000, 107-157.

214The First Organometallic Dendrimers: Design and Redox Functions.

D. Astruc, J.-C. Blais, E. Cloutet, L. Djakovitch, S. Rigaut,J. Ruiz, V. Sartor,

C. Valério

Top. Curr. Chem., Dendrimers II, F. Vögtle Ed., 2000, vol 120, 210, 229-259.

215Functionalization of the Cluster [FeCp(3-CO)]4

E.Alonso, J. Ruiz, D. Astruc

C. R. Acad. Sci., Paris, 2000, Série IIc, 3, 189-192, numéro dédié à Yves Jeannin.

216Electron- and Proton Reservoir Complexes: Thermodynamic Basis for C-H Activation and Applications in Redox- and Dendrimer Chemistry

D. Astruc

Acc. Chem. Res., 2000, 33, 287-298.

217Introduction of the Cluster Fragment Ru3(CO)11 at the Periphery of Phosphine Dendrimers Catalyzed by the Electron-Reservoir Complex [FeICp(C6Me6)]

E. Alonso, D. Astruc

J. Am. Chem. Soc, 2000, 122, 3222-3223.

218Ferrocenylsilylation of Dendrons: a Fast Convergent Route to Redox-Stable Ferrocene Dendrimers

S. Nlate, J. Ruiz, J.-C. Blais, D. Astruc

Chem. Commun, 2000, 417-418.

219Molecular batteries.Ferrocenylsilylation of Dendrons, Dendritic Cores and Dendrimers: New Convergent and Divergent Routes to Ferrocenyl Dendrimers with Stable Redox Activity

S. Nlate, J. Ruiz, V. Sartor, R. Navarro, J.-C. Blais, D. Astruc

Chemistry, Eur. J., 2000, 6, 2544-2553

220Regiospecific Chlorocarbonylation of Polybenzyl Cores and Functionalization Using Dendritic and Organometallic Nucleophiles

C. Valério, F. Moulines, J. Ruiz, J.-C. Blais, D. Astruc

J. Org. Chem., 2000, 65, 1996-2002.

221Activation of Aryl Ethers and Aryl Sulfides by the Fe(5-C5H5)+ group for the Synthesis of Phenol Dendrons and Arene-Centered Poly-Olefin Dendrimers

V. Sartor, S. Nlate, J.-L. Fillaut, L. Djzakovitch, F. Moulines, V. Marvaud, F. Neveu, J.-C. Blais New J. Chem., 2000, 24, 351-370.

222A DFT investigation of the molecular and electronic structures of 19-electron transition-metal sandwich complexes

F. Ogliaro, D. Astruc, J.-F. Halet, J.-Y. Saillard.

New J. Chem , 2000, 24, 257-259.

223Colloids as Redox Sensors: Recognition of H2PO4- and HSO4- by Amidoferrocenylalkylthiol-Gold-Nanoparticles

A. Labande, D. Astruc

Chem. Commun, 2000, 1007-1008.

224 Chimie organométallique (livre en 19 chapitres avec exercices corrigés)

D. Astruc

EDP-Sciences, Les Ulis, 2000, 550p., ISBN 2-86883-493-0.

Selected Reviews: 1983-2000

Organo-Iron Complexes of Aromatic Compounds. Applications in Synthesis.

Astruc, D.

Tetrahedron Report n° 157, Tetrahedron, 1983, 39, 4027-4095.

Organometallic Electron, H-Atom, and Hydride Reservoirs : Single Electron or H-atom Transfers in the Reduction of Iron Sandwich Complexes by Hydrides or H2/Pd/C ; Reduction of Isolobal Carbonyl Complexes, a Model System for the Fisher-Tropsch Synthesis.

Michaud, P. ; Lapinte, C. ; Astruc, D.

Annals New-York Acad. Sciences, 1983, 415, 97-110.

Activation of Dioxygen and of Other Small Molecules Using Organometallic Electron-Reservoir Complexes.

Astruc, D. ; Román, E. ; Hamon, J.-R. ; Madonik, A.M. ; Desbois, M.-H. ; Guerchais, V. Michaud,P.; Lacoste,M.

Bol. Soc. Chil. Quim., 1985, 1-15.

Organoiron Electron Reservoir Complexes.

Astruc, D.

Acc. Chem. Res., 1986, 19, 377-383.

New Entries to Organo-Iron Chemistry: The Pentamethylcyclopenta-dienyl Complexes.

Manriquez, J.M. ; Astruc, D.

Bol. Soc. Chil. Quim., 1986, 31, 161-169.

Thermally Stable 19 Electron Fe(I) and Related Complexes (Experimental).

Astruc, D. ; Hamon, J.-R. ; Lacoste, M. ; Desbois, M.-H. ; Román,E.

"Organomet. Synthesis", R.B.King Ed., Vol. IV, 1988, 172-187.

Electron-Transfer Chain Catalysis in Organo-Transtion-Metal Chemistry.

Astruc, D.

Angew. Chem. Int. Ed. Engl., 1988, 27, 643-660; Angew. Chem., 1988, 100, 662-680.

Nineteen-Electron Organometallic Complexes and their Role in Organometallic Mechanisms.

Astruc, D.

Chem. Rev., 1988, 88, 1189-1216.

The Role of Transition Metal-Centered Radicals in Inorganic and Organometallic Chemistry.

Román, E. ; Astruc, D.

Bol. Soc. Chil. Quim., 1989, 34, 39-58.

Aspects of Aromatic Iron Sandwichs : Application to Organic and Organometallic Synthesis.

Astruc, D. ; Hamon, J.-R. ; Mandon, D. ; Moulines, F.

Pure Appl. Chem, 1990, 62, 1165-1168.

Iron-Sandwichs as Molecular Reservoir Materials : Design, Electronic Properties and Prospects.

Astruc, D. ; Desbois, M.-H. ; Lacoste, M. ; Moulines, F.

Polyhedron, 1990, 2727-2732.

Transition Metal Radicals : Chameleon Structure and Catalytic Function.

Astruc, D.

Acc. Chem. Res., 1991, 24, 36.

Organo-Iron Complexes in Aromatic Synthesis.

Astruc, D. ; Desbois, M.-H. ; Gloaguen, B. ; Moulines F. ; Hamon, J.-R.

"Organic Synthesis via Organometallics", K.H. Dötz, R.W. Hoffmann Eds. Vieweg Braunschweig 1991, 63-75.

The Transformation of Aromatics int Regio- and Stereocontrolled Heterobifunctional Cyclohexadienes Mediated by Temporary Sandwich Complexation. Role of Electron, Proton, Hydride and Hydrogen-Atom Transfers.

Astruc,D.

Synlett, 1991, 369-380.

The Use of -Organoiron Sandwiches in Aromatic Chemistry.

Astruc, D.

Top. Curr. Chem., 1991, 160, 47-95.

Salt Effects Resulting from Exchange between Two Ions Pairs.

Loupy, A. ; Tchoubar, B. ; Astruc, D.

Chem. Rev., 1992, 92, 1141-1165.

Electron-Transfer-Chain Catalysis : Role of Transition-Metal Radicals, Side Reactions and Coupling with Organometallic Catalysis.

Astruc, D. ; Delville, M.-H. ; Ruiz, J.

In "Molecular Electochemistry of Inorganic, Bioinorganic and Organometallic Compounds", Pombeiro, A.J. L. ; Mc Cleverty, J.M. Eds., NA ASISeries, Vol 385, Kluwer, Dordrecht, pp 277-294.

The Magic Salt Effects of Sodium Hexafluorophosphate

Astruc, D. ; Delville-Desbois, M.-H. ; Lacoste, M. ; Ruiz, J. ; Moulines, F. ; Hamon,J.-R.

dans "Recent Advances in the Chemistry of the Main-Group Elements" Hosmane, N. Ed., Phosphorus, Sulfur, Silicon and the Related Elements, 1994, 87, 11-22.

The Molecular Trees : from Syntheses towards Applications.

Ardoin, N. ; Astruc, D.

Bull. Soc. Chim. Fr. 1995, 132, 875-909

Homogeneous Electrocatalysis

Astruc, D. “Applied Homogeneous Catalysis with Organometallic Compounds” Cornils, B. ; Herrmann, W.A. Eds., VCH, Weinheim, 1996, Chapitre 3.2.8.

Electron-Reservoir Sandwich Complexes : From Mono- and Bimetallic Complexes to Molecular Trees

Astruc, D. ; Valério, C. ; Fillaut, J.-L. ; Ruiz, J. ; Hamon, J.-R. ; Varret, F.

“Supramolecular Magnetism” Kahn, O. Ed. NATO ASAI Séries, Kluwer, Dordrecht, 1996, 107-127.

Research Avenues on Dendrimers Towards Molecular Biology :

from Biomimetism to Medicinal Engineering

Astruc, D.

C. R. Acad. Sci. 1996, 322, Série II b, 757-766.

Transferts d’Electrons à l’aide de Molécules Réservoirs : Matériaux, Activation et Catalyse

Astruc, D.

L’Actualité Chimique 1996, 7, 69-74.

From Organotransition-Metal Chemistry toward Molecular Electronics : Electronic Communication between ligand- Bridged Metals

Astruc, D.

Acc. Chem. Res. 1997, 30, 383-391

Organo-Transition Metal Dendrimers.

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