A list of topics and subtopics to study for CHEM 231 final exam

The most important topics; those which are emphasized or are vital for subsequent understanding are marked *.

Exam 1 Topics

Compounds, elements, mixtures (heterogeneous & homogeneous)

Names and symbols of elements*

Unit conversions; compound units*

Density problems

Atomic structure*

Electrons, protons, neutrons

Isotopes

Average atomic weights

Classic experiments: Rutherford, Millikan, etc.

Periodic table*

Names of groups

Other divisions: metals, main groups, transition elements

Ions: names and charges

Monatomic ions from periodic table

Polyatomic ions

Names and formulas*

Ionic compounds

Simple common covalent compounds and diatomic elements

Acids

Simple organic compounds (including structures)

Exam 2 Topics

Chemical equations*

Reactant, product, phase notation

Balancing

Empirical formulas; mass percents of elements

Formula weights*

Avogadro number and molar quantities

Stoichiometry*

Relating reaction masses

Limiting reactants

Solutions; solvents and solutes

Electrolytes: ions in aqueous solution*

Reaction types*

Oxidation-reduction; acid-base

Decomposition; combination

Solution reactions*

Double displacement type: Precipitation and acid-base (hydroxides, carbonates)*

Single displacement: Oxidation of metals by metal ions or acids*

Net ionic equations; spectator ions

Other reactions: Combustion, e.g.

Solution concentrations*

Units: Percent, molarity

Makingsolutions & diluting

Solution stoichiometry

Titrations

Exam 3 Topics

1st law of Thermodynamics

Work, heat, energy, enthalpy

Energy units: J, cal, eV, kJ/mole

Heat & temperature*

Heat capacity, specific heat & molar heat capacity

Reaction enthalpies*

Hess’s Law

Heat of formation & combustion

Using tabulated thermodynamic data

Thermochemical equations & stoichiometry

Energy conversions

Bond energies

Electromagnetic spectrum*

Wavelength, frequency, photon energy

Regions of spectrum & processes

Matter waves; uncertainty principle

Energy levels and wave functions for atoms and molecules*

Photon absorption and emission; calculate wavelengths

Electron states of hydrogen: shells, subshells, orbitals & quantum numbers

Electron structure of many-electron atoms*

Electron spin and Pauli principle

Electron configurations; relation to periodic table

Exam 4 Topics

Energies of electrons in atoms

Inner shell & valence electrons

Effective nuclear charge; shielding

Periodic trends of atomic properties

Size of atoms

Ionization energy & electron affinity

Electronegativity

Metallic nature of elements

Lattice energies & Born-Haber cycles

Lewis electron dot structures*

Atoms and atomic ions

Simple molecules; counting valence electrons

Octet rule

Formal charges & oxidation numbers

Violations of octet rule

Resonance structures

Reactions

Oxidation of metals (by acid, water, other metal ions, halogens)

Metal oxides as bases

Nonmetal oxides as acids

Activities of metals

Unit 5 Topics

Predicting geometry from Lewis structures*

Electron domains

Molecular geometries

Bond angles

Dipole moments

Hybridization

Double and triple bonds

Sigma and pi bonds

Delocalized pi orbitals

Gas laws*

Boyle’s, Charles’ , Avogadro’s Laws

Ideal gas law

Stoichiometry involving gases*

Kinetic theory of gases

Assumptions of the model

Explanations of gas behavior

Emphasized throughout

Estimating numerical answers*

Language of chemistry: translating words into chemical equations*

Unit analysis*