TOPCHEM® GOP – BIOSTATIC CONTROL LIQUID FOR COOLING BATHS
Prepared on: 2012-08-28
Revised on: 2014-03-01
MATERIAL SAFETY DATA SHEET FOR A CHEMICAL MIXTURE
prepared in accordance with Regulation (EU) No. 1907/2006 of the European Parliament, Annex II of 18 December 2006, concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) and Regulation (EC) 1272/2008 (CLP)
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SECTION 1: IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY
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1.1 Product identifier
GOP – BIOSTATIC CONTROL LIQUID FOR COOLING BATHS
1.2 Relevant identified uses of the mixture and uses advised against
Identified uses:preparation for the biostatic control of cooling baths for laser cutting
Uses advised against:none specified.
1.3 Details of the supplier of this Safety Data Sheet
Zakład Chemii Technicznej TOPCHEM
ul.Barytowa 12
25-756 Kielce
Tel.: +48 413454747
Fax: +48 413454747
E-mail of the person in charge of this Safety Data Sheet:
1.4 Emergency telephone number
Emergency telephone in Poland (from 7:00 a.m. to 03:00 p.m.): 112 or 601 439104
Prepared on / Revised on: 2012-08-28/
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SECTION 2: HAZARDS IDENTIFICATION
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2.1 Classification of the mixture
Classification according to Regulation (EC) 1272/2008 (CLP/GHS)
Harmful and irritant preparation. H302; H315; H319;
Environmental hazards:
Toxic to aquatic life.
Harmful effects on humans:Harmful and irritant preparation.Harmful in contact with skin and if swallowed
Fire hazards:
Non-flammable mixture.
2.2 Label elements
Hazards identification:
Signal word:CAUTION:
Hazard class and risk category codes (CLP/GHS)
H302 Toxic if swallowed.
H315 Irritating to skin.
H319Irritating to eyes.
H412Toxic to aquatic life, causing long-term effects.
Precautions for safe handling (P)
Protective measuresP261Avoid breathing vapour or mist.
P264Wash hands after use.
P270Do not eat, drink or smoke when using the product.
P273 Avoid release to the environment.
P280Wear suitable protective gloves and eye/face protection.
Response.P301+312If swallowed, consult a physician.
2.3 Other hazards:None
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SECTION 3:COMPOSITION / INFORMATION ON INGREDIENTS
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Name of substance / CAS identifiers / % / Classification acc. to Directive 67/548/EEC of the Council / Classification acc. to Regulation (CE) 1272/2008 / TypeHazard class and risk category codes / Hazard codes
2,2’,2’’-nitrilotriethanol / 102-71-6 / 30 / Xn; R48/22
Xi; R36/38 / Acute Tox. 4
Skin Irrit. 2
Eye Irrit. 2
STOT RE 2 / H302
H315
H319
H373 / (A)
3,3’Methylenebis[5-methyloxazolidine] / 66204-44-2 / 10 / C;R34
Xn; R21/22; R52 / H318
H312
H317 / (C)
The mixture contains no components classified as PBT or vPvB.
Type
(A) Component
(B) Contaminant
(C) Stabilizer
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SECTION 4:FIRST-AID MEASURES
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4.1 Description of first-aid measures
InhalationRemove victim from place of exposure, keep calm in a comfortable, semi-recumbent position.If victim does not breathe, apply artificial respiration (the mouth-to-mount method can be dangerous).Obtain medical assistance.
Skin contact:Rinse immediately with plenty of water. Remove contaminated clothing. Wash skin with plenty of water and soap.Obtain medical attention and have a dressing applied, if necessary.
Eye contact:Rinse immediately with plenty of lukewarm, preferably running, water for at least 10 minutes.Remove any contact lenses.Consult an ophthalmologist immediately.
Ingestion:If swallowed, obtain medical attention immediately.Do not induce vomiting.Have the victim rinse mouth with water, then drink a small amount of water.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms:
Eye contact:Irritating to eyes.
InhalationNo reports on undesirable effects exist.
Skin contact:Irritating to skin.
IngestionHarmful if swallowed.Irritant to the mouth, throat and stomach.
Symptoms resulting from overexposure
Inhalation:No clear symptoms.
Skin contact:Reddening may occur.
Eye contact:Pain, reddening and watering of the eyes may occur.
Ingestion.Pain in the stomach may occur.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.If swallowed, consult a poisoning treatment specialist.
If splashes have got in the eyes, rinse with water immediately.
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SECTION 5:FIRE-FIGHTING MEASURES
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5.1Extinguishing media
Suitable extinguishing media:adequate to the surroundings on fire
Unsuitable extinguishing media:none
5.2Special hazards arising from the substance or mixture
Rupture of packaging and release of formaldehyde due to thermal decomposition.
5.3Advice for fire fighters
Use a self-contained breathing apparatus.Where possible, remove mixture containers away from hazard area.Non-flammable mixture.
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SECTION 6:ACCIDENTAL RELEASE MEASURES
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6.1 Personal precautions, protective equipment and emergency procedures
Production personnel:Evacuate all personnel from hazard area.Do not touch or walk on released mixture.Avoid breathing vapour or mist.Provide good ventilation.
Emergency personnel:Wear special clothing – see Section 8.
6.2 Environmental precautions
Prevent entry into sewers, surface water and ground water.Absorb with suitable absorbent material.
6.3 Methods and material for containment and cleaning up
Prevent entry into drains.Put any damaged packaging in a replacement packaging.Absorb with neutral absorbent material (sand, diatomaceous earth), put in tightly closed containers for disposal by authorized recyclers.Rinse contaminated surface with water.
Use nitrile gloves when handling any damaged packaging.
6.4 Reference to other Sections
Personal protection equipment is described in Section 8.
Waste disposal methods are described in Section 13.
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SECTION 7:HANDLING AND STORAGE
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7.1 Precautions for safe handling
Wear suitable protective equipment – see Section 8. Avoid contact with the eyes, skin or clothing.Avoid breathing vapour or mist.Keep unused product in original packaging.Do not smoke or eat in the places where product is used.Wash hands and face after use.
7.2 Conditions for safe storage, including any incompatibilities
Keep in vertical position in original, properly marked, tightly sealed packaging. Keep in a cool, dry, well ventilated storage room.Protect from sunlight.
7.3 Specific end use(s)
No information on other uses than those specifically referred to in item 1.2.
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SECTION 8:EXPOSURE CONTROLS / PERSONAL PROTECTION
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8.1 Control parameters
Permissible exposure limit values
Exposure limit values for either component are not available.
Recommended monitoring procedures
As described in EN 689.
Derived effect levels
DEL values are not available
Predicted effect concentrations
PEC values are not available
8.2 Exposure controls
Engineering measures
Provide general ventilation in workplace.
Personal protective equipment
Working safety and hygiene:Remove contaminated clothing after use.Wash hands and face before breaks from work.Do not eat, drink or smoke when using the product.Wash contaminated clothing before reuse.Make sure an emergency eye wash is available in workplace.
Eye protection:Use tight-fitting safety glasses.
Skin protection:Use a protective apron and protective gloves made of nitrile rubber for minor jobs.
Respiratory tractNo special requirements.
Environmental controls
No requirements.
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SECTION 9:PHYSICAL AND CHEMICAL PROPERTIES
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9.1 Information on basic physical and chemical properties
Appearance:Yellow, fluorescent liquid
Odour:Slightly amine.
pH:10
Melting/freezing point:ab. 0oC
Boling point/range:above 100oC
Flash point:Non-flammable product.
Vapour pressure:Data not available.
Density~ 1,12kg/m3
Solubility in waterunlimited
Self-ignition temperature:not applicable
Degradation temperatureData not available.
Viscositydata not available
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SECTION 10:STABILITY AND REACTIVITY
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10.1 Reactivity
May react with strong oxidizers.
10.2 Chemical stabilityStable under normal conditions of use.
10.3 Possibility of hazardous reactionsNot known under normal conditions of use.
10.4 Conditions to avoidTemperatures below 0oC
10.5 Incompatible materialsData not available.
10.6 Hazardous decomposition productsFormaldehyde, nitrogen oxide
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SECTION 11:TOXICOLOGICAL INFORMATION
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11.1 Information on toxicological effects
Acute toxicity:Harmful if swallowed.
For 3,3-methylenebis[5-methyloxazolidine]
LD50900mg/kg (rat) - oral
LD501207-1629mg/kg (rabbit) - skin
11.2 Information on possible routes of exposures
Eye contactcauses eye irritation
InhalationNone under normal working conditions.
Skin contactMay cause irritation.
IngestionCauses irritation of the mouth, throat and stomach.
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SECTION 12:ECOLOGICAL INFORMATION
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12.1 Toxicity
For 3,3-methylenebis[5-methyloxazolidine]
EC5044mg/l (bacteria)
EC50(48h)37.9mg/l (Daphnia magna)
EC50(72h)5.7mg/l (Scenedesmus subspicatus)
12.2 Persistence and degradability
Biodegradable
12.3 Bioaccumulative potential
None.
12.4 Mobility in soil
Data not available.
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SECTION 13:DISPOSAL CONSIDERATIONS
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Waste disposal methods
Waste code – 15 01 10 (commercial packaging containing residues)
Waste code – 16 03 05 (for residues in packaging)
Have packaging waste disposed of by combustion by authorized recyclers.
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SECTION 14:TRANSPORT INFORMATION
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14.1 UN number
UN 2735
14.2 Proper shipping name (UN)
Amines
14.3 Transport hazard class(es) according to ADR /RID – not applicable.
14.4 Packing group
III
14.5 Additional information
Limited quantity –
Hazard identification number -
Transport in bulk – not applicable
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SECTION 15:REGULATORY INFORMATION
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15.1 Safety, health and environmental regulation/legislation specific for the mixture
Regulation (EC) 1907/2006 of the European Parliament and the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Regulation of the Council (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94, as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (Official Journal of the European Union, serial number L 396 of 30 December 2006 as amended).
Regulation of the European Parliament and of the Council (EC) No. 1272/2008 of 16 December 2008 concerning the Classification, Labelling, and Packaging of Substances and Mixtures.
Regulation of the Minister of Economy, Labour and Social Policy of 31 March 2003 concerning essential requirements for personal protection measures (Dz.U.03.80.725) as amended)
Regulation of the Minister of Economy, Labour and Social Policy of 21 December 2005 concerning essential requirements for personal protection measures (Dz.U.05.259.2173)
Regulation of the Minister of Economy, Labour and Social Policy of 29 November 2002 concerning the maximum permissible occupational exposure limit values or harmful factors (Dz.U.02.217.1833 as amended)
Regulation of the Minister of the Environment of 27 September 2001 concerning the waste catalogue (Dz.U.01.112.1206 as amended)
Regulation of the Minister of Health of 2 September 2003 concerning the criteria and method for the classification of chemical substances and preparations (Dz.U.03.171.1666 as amended)
Regulation of the Minister of Health of 20 April 2006 concerning the testing and measurement of occupational exposure limits and harmful factors (Dz.U.05.73.645) as amended)
Regulation of the Minister of Health of 30 December 2004 concerning working safety and hygiene relating to the presence of chemical factors in workplace (Dz.U.05.11.86) as amended
Regulation of the Minister of Health of 5 March 2009 concerning the labelling of packaging of hazardous substances and hazardous preparations and certain chemical preparations (Dz.U.09.53.439 as amended)
The Waste Law of 5 October 2010 (Dz.U.10.185.1243) as amended
The Waste and Waste Packaging Law of 11 May 2001 (Dz.U.01.63.638) as amended
The Law of 25 February 2011 concerning chemical substances and mixtures thereof (Dz.U. 11.63.322)
15.2 Chemical Safety Assessment
The product contains a substance for which the chemical safety assessment continues to be required.
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SECTION 16:OTHER INFORMATION
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Full text of H phrases
H302 – Harmful if swallowed
H312 – Toxic (acute toxicity) in contact with skin.Cat.4
H315 – Causes skin irritation.
H317 – Causes an allergic skin reaction.Cat.1
H318 – Causes serious eye damage/eye irritation.Cat. 1
H319 – Causes eye irritation.
H373 – May cause damage to organs through prolonged or repeated inhalation.
This Safety Data Sheet is based on current knowledge and information contained in the safety data sheets of mixture components and data bases, available on the Internet.Polish Classification of Goods and Services – No. 24.66.46-20.00