The (Na,Li)FeGe2O6 clinopyroxene-type series: A temperature dependent single crystal X-ray diffraction and 57Fe Mössbauer spectroscopic study
Günther J. Redhammer, Gerold Tippelt
Division of Mineralogy, Department of Materials Science & Physics, University of Salzburg, Hellbrunnerstr. 34/ III, 5020 Salzburg, Austria
Supplementary Material
Figure S1: Difference thermal analysis curves for synthetic samples of the Li1-xNaxFeGe2O6, series. The thin blue line is a re-measurement of the powder sample of Li0.9Na0.1FeGe2O6, synthesized at 1273 K; while the composition of the same sample, sintered at 1373 K for additional 32 days, turned out to have different composition Li0.85Na0.15FeGe2O6 (from SC-XRD) and also has different DTA behaviour.
Figure S2: Electron density map at the M2 site in Li0.5Na0.5FeGe2O6.
Figure S3: Variation of lattice parameters of Na0.60Li0.40FeGe2O6, data below 298 K are from single crystal X-ray diffraction, while data above 298 K are from powder X-ray diffraction data.
Figure S4: Graphical representation of the meaning of the chain shift in C2/c (a) and P21/c (b)
(i) = x, 0.5-y, -0.5+z
(ii) = 1-x, -0.5+y, 0.5-z
Table S1: Temperature dependent lattice parameters of selected compound of the Li1-xNaxFeGe2O6 solid solution series. Estimated standard deviations are smaller than 0.0008 Å for a andb, smaller than 0.0006 Å for c and smaller than 0.01° for the monoclinic angle.
Na0.10Li0.90FeGe2O6T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 9.9022 / 8.8223 / 5.4007 / 108.797 / 446.64
50 / 9.9053 / 8.8244 / 5.4020 / 108.786 / 447.03
100 / 9.9132 / 8.8289 / 5.4066 / 108.791 / 447.97
150 / 9.9197 / 8.8305 / 5.4115 / 108.792 / 448.76
200 / 9.9280 / 8.8326 / 5.4181 / 108.826 / 449.69
250 / 9.9337 / 8.8339 / 5.4243 / 108.831 / 450.52
300 / 9.9398 / 8.8367 / 5.4289 / 108.820 / 451.35
350 / 9.9445 / 8.8369 / 5.4339 / 108.835 / 451.95
400 / 10.0791 / 8.7436 / 5.5348 / 109.681 / 459.28
450 / 10.0906 / 8.7484 / 5.5347 / 109.654 / 460.12
500 / 10.0911 / 8.7545 / 5.5354 / 109.617 / 460.63
550 / 10.0931 / 8.7637 / 5.5365 / 109.598 / 461.35
600 / 10.0936 / 8.7707 / 5.5381 / 109.566 / 461.97
650 / 10.0944 / 8.7776 / 5.5391 / 109.539 / 462.52
700 / 10.0952 / 8.7892 / 5.5401 / 109.523 / 463.30
750 / 10.0963 / 8.7970 / 5.5411 / 109.485 / 463.96
800 / 10.0974 / 8.8078 / 5.5422 / 109.448 / 464.78
25 / 9.9039 / 8.8111 / 5.3971 / 108.757 / 445.96
Na0.30Li0.70FeGe2O6
T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 9.9424 / 8.8569 / 5.4463 / 108.692 / 454.29
50 / 9.9452 / 8.8574 / 5.4492 / 108.667 / 454.76
100 / 9.9521 / 8.8589 / 5.4559 / 108.598 / 455.90
150 / 9.9568 / 8.8597 / 5.4706 / 108.576 / 457.44
200 / 10.0434 / 8.7968 / 5.5540 / 109.213 / 463.36
250 / 10.0449 / 8.8009 / 5.5551 / 109.157 / 463.90
300 / 10.0460 / 8.8090 / 5.5565 / 109.095 / 464.66
350 / 10.0483 / 8.8153 / 5.5579 / 109.085 / 465.25
400 / 10.0497 / 8.8240 / 5.5597 / 109.040 / 466.05
450 / 10.0520 / 8.8315 / 5.5603 / 108.979 / 466.78
500 / 10.0532 / 8.8391 / 5.5624 / 108.970 / 467.44
550 / 10.0549 / 8.8488 / 5.5637 / 108.912 / 468.30
600 / 10.0567 / 8.8538 / 5.5659 / 108.906 / 468.86
650 / 10.0581 / 8.8624 / 5.5668 / 108.892 / 469.49
700 / 10.0600 / 8.8682 / 5.5684 / 108.841 / 470.16
750 / 10.0622 / 8.8794 / 5.5696 / 108.826 / 471.00
800 / 10.0640 / 8.8846 / 5.5706 / 108.790 / 471.54
Na0.50Li0.50FeGe2O6
T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 10.0393 / 8.8206 / 5.5324 / 108.912 / 463.47
50 / 10.0401 / 8.8224 / 5.5327 / 108.902 / 463.65
100 / 10.0423 / 8.8283 / 5.5338 / 108.874 / 464.23
150 / 10.0445 / 8.8373 / 5.5349 / 108.845 / 464.98
200 / 10.0460 / 8.8423 / 5.5356 / 108.825 / 465.42
250 / 10.0481 / 8.8515 / 5.5368 / 108.792 / 466.20
300 / 10.0492 / 8.8562 / 5.5378 / 108.764 / 466.66
350 / 10.0509 / 8.8647 / 5.5387 / 108.731 / 467.35
400 / 10.0522 / 8.8689 / 5.5392 / 108.712 / 467.73
450 / 10.0545 / 8.8752 / 5.5404 / 108.690 / 468.33
500 / 10.0561 / 8.8810 / 5.5410 / 108.678 / 468.79
550 / 10.0571 / 8.8876 / 5.5420 / 108.658 / 469.33
600 / 10.0588 / 8.8941 / 5.5429 / 108.632 / 469.91
650 / 10.0607 / 8.9005 / 5.5439 / 108.612 / 470.47
700 / 10.0631 / 8.9091 / 5.5451 / 108.595 / 471.19
750 / 10.0651 / 8.9156 / 5.5460 / 108.576 / 471.75
800 / 10.0669 / 8.9215 / 5.5469 / 108.548 / 472.30
25 / 10.0402 / 8.8226 / 5.5327 / 108.900 / 463.67
Na0.60Li0.40FeGe2O6
T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 10.0296 / 8.8427 / 5.5315 / 108.672 / 464.76
50 / 10.0308 / 8.8454 / 5.5319 / 108.663 / 465.02
100 / 10.0332 / 8.8507 / 5.5326 / 108.642 / 465.53
150 / 10.0347 / 8.8555 / 5.5333 / 108.623 / 465.95
200 / 10.0371 / 8.8625 / 5.5342 / 108.590 / 466.60
250 / 10.0398 / 8.8705 / 5.5350 / 108.552 / 467.32
300 / 10.0419 / 8.8758 / 5.5361 / 108.528 / 467.86
350 / 10.0447 / 8.8812 / 5.5370 / 108.507 / 468.41
400 / 10.0484 / 8.8883 / 5.5379 / 108.480 / 469.10
450 / 10.0513 / 8.8961 / 5.5384 / 108.461 / 469.75
500 / 10.0544 / 8.9013 / 5.5396 / 108.439 / 470.32
550 / 10.0567 / 8.9072 / 5.5405 / 108.417 / 470.88
600 / 10.0579 / 8.9122 / 5.5412 / 108.398 / 471.32
650 / 10.0612 / 8.9215 / 5.5423 / 108.377 / 472.12
700 / 10.0652 / 8.9277 / 5.5433 / 108.350 / 472.79
750 / 10.0669 / 8.9346 / 5.5439 / 108.348 / 473.29
800 / 10.0703 / 8.9412 / 5.5450 / 108.349 / 473.89
25 / 10.0286 / 8.8427 / 5.5317 / 108.630 / 464.85
Na0.74Li0.26FeGe2O6
T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 10.0221 / 8.8694 / 5.5274 / 108.384 / 466.25
50 / 10.0237 / 8.8729 / 5.5275 / 108.373 / 466.55
100 / 10.0266 / 8.8792 / 5.5290 / 108.347 / 467.22
150 / 10.0294 / 8.8852 / 5.5303 / 108.325 / 467.83
200 / 10.0316 / 8.8912 / 5.5309 / 108.302 / 468.36
250 / 10.0347 / 8.8974 / 5.5320 / 108.278 / 468.99
300 / 10.0389 / 8.9027 / 5.5332 / 108.258 / 469.62
350 / 10.0422 / 8.9088 / 5.5344 / 108.235 / 470.27
400 / 10.0443 / 8.9145 / 5.5355 / 108.207 / 470.83
450 / 10.0487 / 8.9207 / 5.5370 / 108.198 / 471.52
500 / 10.0527 / 8.9270 / 5.5388 / 108.186 / 472.23
550 / 10.0557 / 8.9324 / 5.5401 / 108.178 / 472.78
600 / 10.0581 / 8.9385 / 5.5410 / 108.161 / 473.34
650 / 10.0608 / 8.9429 / 5.5419 / 108.148 / 473.81
700 / 10.0640 / 8.9489 / 5.5432 / 108.124 / 474.47
750 / 10.0679 / 8.9553 / 5.5440 / 108.114 / 475.09
800 / 10.0722 / 8.9614 / 5.5458 / 108.096 / 475.81
25 / 10.0206 / 8.8656 / 5.5263 / 108.350 / 465.99
Na0.90Li0.10FeGe2O6
T (°C) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)
25 / 10.0121 / 8.9133 / 5.5206 / 107.785 / 469.12
50 / 10.0143 / 8.9159 / 5.5215 / 107.786 / 469.43
100 / 10.0186 / 8.9211 / 5.5227 / 107.763 / 470.07
150 / 10.0226 / 8.9273 / 5.5244 / 107.754 / 470.75
200 / 10.0271 / 8.9325 / 5.5263 / 107.743 / 471.43
250 / 10.0316 / 8.9386 / 5.5288 / 107.737 / 472.19
300 / 10.0356 / 8.9458 / 5.5298 / 107.725 / 472.87
350 / 10.0404 / 8.9525 / 5.5321 / 107.715 / 473.68
400 / 10.0452 / 8.9583 / 5.5335 / 107.711 / 474.35
450 / 10.0487 / 8.9661 / 5.5358 / 107.701 / 475.15
500 / 10.0537 / 8.9723 / 5.5365 / 107.692 / 475.80
550 / 10.0603 / 8.9788 / 5.5388 / 107.682 / 476.68
600 / 10.0642 / 8.9849 / 5.5401 / 107.668 / 477.34
650 / 10.0694 / 8.9933 / 5.5423 / 107.655 / 478.26
700 / 10.0728 / 8.9990 / 5.5431 / 107.652 / 478.79
750 / 10.0776 / 9.0021 / 5.5454 / 107.639 / 479.42
800 / 10.0832 / 9.0102 / 5.5472 / 107.628 / 480.30
25 / 10.0141 / 8.9162 / 5.5221 / 107.791 / 469.47
Table S2: Relative changes (%) in lattice parameters at the C2/c - P21/c phase transition in some selected pyroxenes
T – range / a (%) / b (%) / c (%) / β (%) / V (%)LiFeGe2O6 / 783 - 837 / 1.56 / -1.28 / 2.10 / 0.85 / 1.79
Li0.9Na0.1FeGe2O6 / 350 - 400 / 1.36 / -1.06 / 1.86 / 0.78 / 1.62
Li0.7Na0.3FeGe2O6 / 250 - 200 / 0.87 / -0.71 / 1.53 / 0.59 / 1.30
Li0.4Na0.6FeGe2O6 / 155 - 205 / 0.44 / -0.38 / 0.67 / 0.31 / 0.52
LiCrGe2O6 / 1023 - 1083 / 1.14 / -0.34 / 1.74 / 0.93 / 1.64
Table S3: Formulas used to calculate the contributions along [0 1 0] as well as to calculate the tetrahedral chain shift.
C2/c / P21/cM1 width // b / /
M2 width // b / /
T width // b / /
chain shift
(M2 shift of Benna et al. 1988) /
/
Symmetry codes:
(i) = x, 0.5-y, -0.5+z
(ii) = 1-x, -0.5+y, 0.5-z
Formulas used to calculate distortion parameters:
withi = O-M-O bonding angle,
. where lo = central to vertex distance for a regular octahedron whose volume is equal to that of the undistorted tetrahedron with bond length li ,
BLD =
withi = O-T-O bonding angle,
. where lo = central to vertex distance for a regular tetrahedron whose volume is equal to that of the undistorted octahedron with bond length li (all formula Robinson et al. 1971).
Table S4: Low temperature lattice parameters for composition Na0.60Li0.40FeGe2O6, as determined from single crystal X-ray diffraction data. Standard deviations are given in the CIF Files.
Temp. (K) / a (Å) / b (Å) / c (Å) / β (°) / V (Å3)105 / 9.9707 / 8.8595 / 5.4835 / 108.356 / 459.74
115 / 9.9727 / 8.8601 / 5.4851 / 108.362 / 459.98
125 / 9.9768 / 8.8626 / 5.4881 / 108.375 / 460.52
135 / 9.9776 / 8.8626 / 5.4892 / 108.375 / 460.65
145 / 9.9808 / 8.8652 / 5.4909 / 108.388 / 461.04
155 / 9.9816 / 8.8642 / 5.4923 / 108.392 / 461.13
165 / 9.9835 / 8.8641 / 5.4938 / 108.398 / 461.32
175 / 9.9867 / 8.8635 / 5.4962 / 108.412 / 461.60
180 / 9.9927 / 8.8636 / 5.5005 / 108.433 / 462.19
185 / 9.9987 / 8.8554 / 5.5060 / 108.499 / 462.32
190 / 10.0065 / 8.8453 / 5.5133 / 108.581 / 462.55
195 / 10.0175 / 8.8433 / 5.5210 / 108.635 / 463.45
205 / 10.0251 / 8.8306 / 5.5289 / 108.729 / 463.54
220 / 10.0267 / 8.8325 / 5.5299 / 108.722 / 463.82
230 / 10.0280 / 8.8342 / 5.5307 / 108.716 / 464.05
240 / 10.0286 / 8.8358 / 5.5307 / 108.712 / 464.18
250 / 10.0283 / 8.8367 / 5.5305 / 108.704 / 464.21
260 / 10.0302 / 8.8392 / 5.5320 / 108.695 / 464.59
270 / 10.0289 / 8.8389 / 5.5309 / 108.692 / 464.42
280 / 10.0291 / 8.8405 / 5.5310 / 108.685 / 464.54
298 / 10.0297 / 8.8427 / 5.5315 / 108.672 / 464.77
Table S5: Selected low temperature structural parameter for Na0.60Li0.40FeGe2O6, as determined from single crystal X-ray diffraction data. Standard deviations are given in the CIF Files.
Temp.(K) / Fe-O2Av
(Å) / Fe-O2Bvii
(Å) / Fe-O1Avi
(Å) / Fe-O1Bii
(Å) / Fe-O1Av
(Å) / Fe-O1B
(Å) / Fe-O>
(Å)
298 / 1.915 / -- / 2.057 / -- / 2.103 / -- / 2.025
280 / 1.917 / -- / 2.059 / -- / 2.107 / -- / 2.027
270 / 1.913 / -- / 2.059 / -- / 2.102 / -- / 2.025
260 / 1.919 / -- / 2.053 / -- / 2.106 / -- / 2.026
250 / 1.911 / -- / 2.055 / -- / 2.105 / -- / 2.024
240 / 1.914 / -- / 2.056 / -- / 2.103 / -- / 2.024
230 / 1.921 / -- / 2.056 / -- / 2.104 / -- / 2.027
220 / 1.914 / -- / 2.055 / -- / 2.103 / -- / 2.024
205 / 1.914 / -- / 2.053 / -- / 2.108 / -- / 2.025
195 / 1.911 / 1.929 / 2.041 / 2.061 / 2.106 / 2.110 / 2.026
190 / 1.913 / 1.929 / 2.045 / 2.048 / 2.106 / 2.111 / 2.025
185 / 1.911 / 1.931 / 2.044 / 2.052 / 2.107 / 2.120 / 2.028
180 / 1.911 / 1.937 / 2.047 / 2.050 / 2.113 / 2.116 / 2.029
175 / 1.911 / 1.938 / 2.046 / 2.061 / 2.107 / 2.117 / 2.030
165 / 1.915 / 1.935 / 2.042 / 2.054 / 2.109 / 2.123 / 2.030
155 / 1.915 / 1.930 / 2.040 / 2.051 / 2.111 / 2.116 / 2.027
145 / 1.917 / 1.936 / 2.044 / 2.058 / 2.118 / 2.118 / 2.032
135 / 1.917 / 1.934 / 2.037 / 2.054 / 2.117 / 2.123 / 2.030
125 / 1.918 / 1.940 / 2.032 / 2.048 / 2.112 / 2.114 / 2.027
115 / 1.920 / 1.934 / 2.033 / 2.050 / 2.121 / 2.126 / 2.031
105 / 1.920 / 1.931 / 2.032 / 2.051 / 2.121 / 2.122 / 2.029
Temp / M2-O3A
(Å) / M2-O1Bii
(Å) / M2-O2Biv
(Å) / M2-O1Ai
(Å) / Li-O2Av
(Å) / Li-O3Biii
(Å) / Li-O3B
(Å) / <Li-O>
(Å)
298 / 2.325 / 2.320 / 2.537 / -- / -- / -- / -- / 2.394
280 / 2.326 / 2.319 / 2.538 / -- / -- / -- / -- / 2.394
270 / 2.326 / 2.322 / 2.537 / -- / -- / -- / -- / 2.395
260 / 2.320 / 2.315 / 2.533 / -- / -- / -- / -- / 2.389
250 / 2.323 / 2.316 / 2.537 / -- / -- / -- / -- / 2.392
240 / 2.320 / 2.317 / 2.538 / -- / -- / -- / -- / 2.391
230 / 2.315 / 2.314 / 2.531 / -- / -- / -- / -- / 2.387
220 / 2.321 / 2.310 / 2.535 / -- / -- / -- / -- / 2.389
205 / 2.315 / 2.316 / 2.534 / -- / -- / -- / -- / 2.388
195 / 2.271 / 2.296 / 2.453 / 2.336 / 2.561 / 2.450 / 2.879 / 2.395
190 / 2.248 / 2.305 / 2.436 / 2.325 / 2.548 / 2.495 / 2.815 / 2.393
185 / 2.246 / 2.303 / 2.393 / 2.330 / 2.566 / 2.556 / 2.735 / 2.399
180 / 2.247 / 2.298 / 2.363 / 2.340 / 2.557 / 2.588 / 2.678 / 2.399
175 / 2.250 / 2.300 / 2.354 / 2.344 / 2.559 / 2.598 / 2.668 / 2.401
165 / 2.253 / 2.296 / 2.348 / 2.343 / 2.556 / 2.609 / 2.654 / 2.401
155 / 2.244 / 2.297 / 2.345 / 2.343 / 2.557 / 2.614 / 2.651 / 2.400
135 / 2.243 / 2.295 / 2.329 / 2.337 / 2.556 / 2.632 / 2.657 / 2.399
145 / 2.243 / 2.296 / 2.346 / 2.329 / 2.543 / 2.636 / 2.656 / 2.399
125 / 2.249 / 2.288 / 2.333 / 2.347 / 2.533 / 2.635 / 2.648 / 2.397
115 / 2.247 / 2.283 / 2.341 / 2.343 / 2.537 / 2.625 / 2.653 / 2.396
105 / 2.236 / 2.293 / 2.338 / 2.344 / 2.539 / 2.619 / 2.649 / 2.395
Temp.
(K) / GeA-O2A
(Å) / GeA-O3A
(Å) / GeA-O1A
(Å) / GeA-O3A
(Å) / GeA-O>
(Å) / GeA-Obr
(Å) / GeA-Onbr
(Å) / O3A-O3A-O3A
(°) / O3A-O3A
(Å)
298 / 1.721 / 1.746 / 1.755 / 1.759 / 1.745 / 1.753 / 1.738 / 184.70 / 2.768
280 / 1.722 / 1.744 / 1.751 / 1.761 / 1.745 / 1.753 / 1.736 / 184.29 / 2.767
270 / 1.724 / 1.743 / 1.752 / 1.762 / 1.745 / 1.752 / 1.738 / 184.28 / 2.767
260 / 1.717 / 1.745 / 1.753 / 1.758 / 1.743 / 1.751 / 1.735 / 184.90 / 2.768
250 / 1.723 / 1.746 / 1.754 / 1.758 / 1.745 / 1.752 / 1.738 / 184.80 / 2.768
240 / 1.723 / 1.744 / 1.756 / 1.762 / 1.746 / 1.753 / 1.739 / 184.49 / 2.768
230 / 1.716 / 1.748 / 1.750 / 1.764 / 1.744 / 1.756 / 1.733 / 185.06 / 2.768
220 / 1.721 / 1.747 / 1.754 / 1.763 / 1.746 / 1.755 / 1.737 / 184.87 / 2.767
205 / 1.724 / 1.745 / 1.751 / 1.763 / 1.746 / 1.754 / 1.737 / 184.78 / 2.767
195 / 1.720 / 1.756 / 1.755 / 1.757 / 1.747 / 1.757 / 1.737 / 190.72 / 2.773
190 / 1.720 / 1.756 / 1.761 / 1.759 / 1.749 / 1.757 / 1.741 / 192.53 / 2.773
185 / 1.723 / 1.752 / 1.761 / 1.760 / 1.749 / 1.756 / 1.742 / 193.83 / 2.773
180 / 1.726 / 1.751 / 1.756 / 1.761 / 1.748 / 1.756 / 1.741 / 194.65 / 2.773
175 / 1.725 / 1.747 / 1.751 / 1.758 / 1.745 / 1.753 / 1.738 / 194.37 / 2.770
165 / 1.720 / 1.745 / 1.758 / 1.757 / 1.745 / 1.751 / 1.739 / 194.73 / 2.770
155 / 1.717 / 1.749 / 1.756 / 1.755 / 1.744 / 1.752 / 1.736 / 195.54 / 2.772
135 / 1.719 / 1.747 / 1.753 / 1.761 / 1.745 / 1.754 / 1.736 / 195.37 / 2.770
145 / 1.717 / 1.749 / 1.750 / 1.757 / 1.743 / 1.753 / 1.734 / 195.10 / 2.770
125 / 1.716 / 1.743 / 1.748 / 1.756 / 1.740 / 1.749 / 1.732 / 195.61 / 2.770
115 / 1.710 / 1.747 / 1.747 / 1.752 / 1.739 / 1.750 / 1.728 / 194.95 / 2.766
105 / 1.708 / 1.744 / 1.750 / 1.752 / 1.738 / 1.748 / 1.729 / 195.67 / 2.768
Temp / GeB-O2B
(Å) / GeB-O3B
(Å) / GeB-O1B
(Å) / GeB-O3B
(Å) / GeB-O>
(Å) / GeB-Obr
(Å) / GeB-Onbr
(Å) / O3B-O3B-O3B
(°) / O3B-O3B
(Å)
195 / 1.717 / 1.729 / 1.758 / 1.766 / 1.743 / 1.748 / 1.737 / 173.12 / 2.766
190 / 1.717 / 1.734 / 1.758 / 1.760 / 1.742 / 1.747 / 1.737 / 170.03 / 2.767
185 / 1.718 / 1.740 / 1.756 / 1.765 / 1.745 / 1.753 / 1.737 / 165.05 / 2.777
180 / 1.722 / 1.752 / 1.760 / 1.762 / 1.749 / 1.757 / 1.741 / 162.81 / 2.782
175 / 1.720 / 1.739 / 1.760 / 1.770 / 1.747 / 1.754 / 1.740 / 161.49 / 2.784
165 / 1.721 / 1.748 / 1.753 / 1.762 / 1.746 / 1.755 / 1.737 / 161.16 / 2.785
155 / 1.726 / 1.749 / 1.759 / 1.763 / 1.749 / 1.756 / 1.743 / 161.08 / 2.784
135 / 1.715 / 1.742 / 1.753 / 1.763 / 1.743 / 1.752 / 1.734 / 160.30 / 2.786
145 / 1.723 / 1.740 / 1.751 / 1.761 / 1.744 / 1.751 / 1.737 / 160.00 / 2.788
125 / 1.723 / 1.753 / 1.767 / 1.759 / 1.751 / 1.756 / 1.745 / 159.58 / 2.788
115 / 1.730 / 1.753 / 1.756 / 1.754 / 1.749 / 1.754 / 1.743 / 159.33 / 2.788
105 / 1.725 / 1.743 / 1.755 / 1.767 / 1.747 / 1.755 / 1.740 / 158.72 / 2.790