Appendix C: The vibrationally unassigned bands of CuCl2
Supplementary material
Appendix C
Appendix C
Observations, assignments and residuals from the fits of the vibrationally unassigned bands of CuCl2
Table C.1: Measurements and assignments of individual lines in the (A) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 15541.2720cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15741.0016(9) / 15740.7368(-53)c
2 / 15740.7644(-19)
1 / 15741.0435(-20) / 15740.7822(4)
2½ / 4 / 15741.0783(-17) / 15740.7136(-30)
3 / 15741.0918(-19) / 15740.7298(8)
2 / 15741.1003(-44) / 15740.7368(-23)c
3½ / 5 / 15741.1431(-13) / 15740.6750(-16) / 15740.3216(1)c,d
4 / 15741.1521(-15) / 15740.6805(-46)
3 / 15741.1586(-28) / 15740.6895(-29)
2 / 15741.1641(-34)
4½ / 6 / 15741.1935(-20) / 15740.6218(-17) / 15740.1611(-15)c,d
5 / 15741.2006(-18) / 15740.6276(-23)
4 / 15740.6328(-29)
5½ / 15739.9880(-35)
6½ / 15739.8049(-33)
7½ / 15740.3943(10) / 15739.6123(-4)
8½ / 15740.2911(15) / 15739.4058(8)
9½ / 15739.1858(7)
10½ / 15741.2427(7) / 15740.0458(3) / 15738.9532(3)
11½ / 15741.2067(11) / 15738.7090(6)
12½ / 15741.1586(19) / 15739.7538(15) / 15738.4523(6)
13½ / 15741.0976(20) / 15739.5909(37) / 15738.1835(8)
14½ / 15741.0239(19) / 15737.9030(16)
15½ / 15740.9379(18) / 15739.2220(20) / 15737.6098(21)
16½ / 15740.8388(10) / 15739.0198(20) / 15737.3030(13)
17½ / 15740.7283(13) / 15736.9841(8)
18½ / 15740.6045(8) / 15738.5783(21) / 15736.6532(8)
19½ / 15740.4704(24) / 15738.3378(11) / 15736.3110(18)
20½ / 15740.3216(19) / 15735.9547(13)
21½ / 15740.1611(23) / 15735.5864(12)
22½ / 15735.2069(25)
23½ / 15734.8121(11)
24½ / 15734.4038(-13)
25½ / 15739.3901(15) / 15733.9847(-17)
26½ / 15739.1653(11) / 15733.5509(-42)
27½ / 15738.9280(10) / 15733.1142(31)
28½ / 15738.6760(-8) / 15732.6573(30)
29½ / 15738.4134(-4) / 15732.1871(25)
30½ / 15738.1369(-9) / 15731.7007(-14)
31½ / 15737.8481(-7) / 15731.2064(-3)
32½ / 15730.6983(0)
33½ / 15737.2291(-23) / 15730.1781(13)
35½ / 15729.0942(-5)
36½ / 15728.5324(-15)
40½ / 15726.1556(-20)
41½ / 15725.5317(17)
43½ / 15724.2395(56)
44½ / 15723.5710(56)
45½ / 15722.8905(74)
46½ / 15722.1930(61)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition.
Table C.2: Measurements and assignments of individual lines in the (A) 23/2 – (000) 23/2 band of 65Cu35Cl2, bandhead: 15543.2597cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15742.9788(-17)
15742.9655(1)c
2 / 15742.9970(-23)
15742.9853(-19)c
1 / 15743.0053(-37)
2½ / 4 / 15743.0571(-17) / 15742.4406(-12)
3 / 15743.0641(-20) / 15742.4318(12)
2 / 15743.0700(-16)
3½ / 5 / 15743.1216(-16) / 15742.6560(-16)d
4 / 15743.1258(-16)
3 / 15743.1288(-20)
4½ / 15743.1771(-8) / 15742.6047(7) / 15742.1346(2)
5½ / 15743.2158(-10) / 15742.5386(1) / 15741.9648(3)
6½ / 15743.2427(-10) / 15742.4615(4) / 15741.7835(7)
7½ / 15741.5887(-4)
8½ / 15741.3843(8)
9½ / 15741.1653(-7)
10½ / 15743.2322(-1) / 15742.0332(9) / 15740.9364(-2)
11½ / 15743.1994(-2) / 15741.8965(12) / 15740.6964(11)
12½ / 15743.1558(8) / 15741.7482(18) / 15740.4449(29)
13½ / 15743.0986(2) / 15740.1785(16)
14½ / 15743.0300(0) / 15739.9018(20)
15½ / 15742.9498(3) / 15739.6107(0)
16½ / 15742.8574(3) / 15741.0309(-4) / 15739.3095(-2)
17½ / 15742.7531(3) / 15740.8231(5) / 15738.9970(2)
18½ / 15742.6365(1) / 15740.6037(17) / 15738.6737(18)
19½ / 15742.5100(19) / 15738.3362(11)
20½ / 15742.3705(26) / 15737.9889(26)
21½ / 15742.2171(15) / 15737.6267(12)
22½ / 15742.0528(14) / 15737.2536(8)
23½ / 15741.8779(28) / 15736.8683(2)
24½ / 15741.6862(-7) / 15736.4708(-6)
25½ / 15741.4879(13) / 15736.0625(-2)
26½ / 15741.2754(11) / 15735.6409(-11)
27½ / 15741.0494(-6) / 15735.2079(-14)
28½ / 15740.8144(8) / 15734.7625(-21)
29½ / 15740.5635(-17) / 15734.3045(-34)
30½ / 15733.8356(-35)
31½ / 15740.0327(5) / 15733.3532(-51)
32½ / 15739.7462(-13) / 15732.8629(-25)
33½ / 15739.4493(-15) / 15732.3591(-14)
34½ / 15739.1410(-10) / 15731.8412(-23)
35½ / 15738.8220(9) / 15731.3133(-11)
36½ / 15738.4888(8) / 15730.7728(-5)
37½ / 15738.1472(44) / 15730.2218(18)
38½ / 15729.6561(15)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c F = 0 for this transition.
d Hyperfine structure was not resolved for this transition.
Table C.3: Measurements and assignments of individual lines in the (A) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 15542.6321cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
3½ / 15742.0375(-1) / 15741.6821(7)
4½ / 15741.9867(0) / 15741.5281(-6)
5½ / 15741.9243(-1) / 15741.3641(-5)
6½ / 15741.8503(-5)
7½ / 15741.7645(-14) / 15741.0003(-23)
8½ / 15740.8029(-17)
9½ / 15741.5615(-5) / 15740.5953(1)
10½ / 15742.6145(12) / 15741.4436(5) / 15740.3744(-5)
11½ / 15742.5862(14) / 15741.3128(0) / 15740.1428(3)
12½ / 15742.5464(16) / 15739.9005(14)
13½ / 15742.4956(21) / 15739.6452(8)
14½ / 15742.4327(19) / 15739.3796(14)
15½ / 15742.3583(16) / 15739.1020(12)
16½ / 15742.2731(19) / 15738.8132(13)
17½ / 15742.1763(20) / 15738.5129(13)
18½ / 15742.0678(19) / 15738.2003(3)
19½ / 15741.9478(16) / 15737.8781(12)
20½ / 15741.8155(6) / 15737.5437(12)
21½ / 15741.6730(7) / 15737.1963(-2)
22½ / 15741.5202(21) / 15736.8387(-5)
23½ / 15741.3520(-5) / 15736.4711(7)
24½ / 15741.1730(-23) / 15736.0895(-6)
25½ / 15740.9850(-17) / 15735.6975(-9)
26½ / 15740.7836(-29) / 15735.2951(0)
27½ / 15734.8789(-15)
28½ / 15740.3500(-14) / 15734.4504(-37)
29½ / 15740.1147(-18) / 15734.0118(-45)
30½ / 15739.8682(-19)
31½
32½ / 15739.3397(-25) / 15732.6343(9)
33½ / 15739.0585(-23) / 15732.1493(0)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place.
Table C.4: Measurements and assignments of individual lines in the (A) 23/2 – (000) 23/2 band of 65Cu35Cl37Cl, bandhead: 15542.3264cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
3½ / 15741.7605(22)
4½ / 15741.2541(46)c
5½ / 15741.6373(-24) / 15741.0840(10)
6½ / 15740.9065(18)
7½ / 15741.4717(-18) / 15740.7153(8)
8½ / 15741.3724(-2) / 15740.5149(25)
9½ / 15740.3001(17)
10½ / 15742.2965(-25) / 15741.1298(-54) / 15740.0732(6)
11½ / 15742.2633(-3) / 15740.9968(-18) / 15739.8327(-21)
12½ / 15742.2171(9)c / 15740.8497(-4) / 15739.5826(-26)
13½ / 15742.1580(10) / 15739.3208(-29)
14½ / 15742.0865(7) / 15739.0491(-11)
15½ / 15742.0041(14) / 15740.3355(23) / 15738.7648(0)
16½ / 15741.9107(31) / 15738.4678(3)
17½ / 15741.8002(-3) / 15739.9313(24) / 15738.1599(16)
18½ / 15741.6862(47)c / 15739.7072(-16) / 15737.8383(12)
19½ / 15741.5524(19) / 15737.5022(-18)
20½ / 15741.4095(20) / 15737.1582(-6)
21½ / 15741.2541(16)c / 15736.8011(-6)
22½ / 15736.4305(-21)
23½ / 15736.0510(-5)
24½ / 15735.6572(-12)
25½ / 15735.2521(-11)
26½ / 15734.8351(-9)
27½ / 15734.4056(-11)
28½ / 15733.9647(-6)
29½ / 15733.5137(18)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. c Weight =0.5 for this transition.
Table C.5: Measurements and assignments of individual lines in the (A) 23/2 – (100) 23/2 band of 63Cu35Cl2 bandhead: 15371.9108cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
4½ / 15370.8009(20)
5½ / 15370.6305(14)
6½ / 15370.4460(-13)
7½ / 15370.2532(-4)
8½ / 15370.9326(1) / 15370.0482(3)
9½ / 15370.8195(7) / 15369.8287(-15)
10½ / 15371.8882(-15) / 15369.5970(-35)
11½ / 15371.8573(14) / 15370.5578(24) / 15369.3585(-3)
12½ / 15371.8118(18) / 15370.4080(24) / 15369.1037(-13)
13½ / 15371.7528(7) / 15368.8377(-15)
14½ / 15371.6831(11) / 15370.0734(37) / 15368.5596(-17)
15½ / 15371.6005(8) / 15368.2706(-7)
16½ / 15371.5078(25) / 15367.9683(-9)
17½ / 15371.4015(28) / 15367.6547(-2)
18½ / 15371.2828(30) / 15369.2537(14) / 15367.3311(26)
19½ / 15371.1518(31) / 15366.9933(34)
20½ / 15371.0068(16) / 15366.6417(27)
21½ / 15370.8502(8) / 15366.2775(16)
22½ / 15370.6845(32) / 15365.9021(17)
23½ / 15370.5041(34) / 15365.5132(5)
24½ / 15370.3096(20) / 15365.1172(47)
25½ / 15370.1044(23) / 15364.6955(-45)
26½ / 15369.8869(29) / 15364.2739(-11)
27½ / 15369.6524(-10) / 15363.8390(15)
28½ / 15369.4091(-10) / 15363.3875(0)
29½ / 15369.1525(-16) / 15362.9271(22)
30½ / 15368.8834(-20) / 15362.4502(5)
31½ / 15368.6027(-12) / 15361.9619(1)
32½ / 15368.3062(-34) / 15361.4598(-14)
33½ / 15368.0008(-16) / 15360.9496(17)
34½ / 15367.6780(-43) / 15360.4194(-23)
35½ / 15367.3487(-4) / 15359.8812(-14)
36½ / 15359.3251(-55)
37½ / 15358.7620(-36)
38½ / 15358.1843(-33)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place.
Table C.6: Measurements and assignments of individual lines in the (A) 23/2 – (100) 23/2 band of 65Cu35Cl2 bandhead: 15373.9155cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
4½ / 15372.7862(-1)
5½ / 15372.6193(16)
6½ / 15372.4359(-16)
7½ / 15372.2469(13)
8½ / 15372.0418(-3)
9½ / 15371.8277(9)
10½ / 15373.8967(12)
11½ / 15373.8671(15) / 15371.3609(-4)
12½ / 15373.8252(13) / 15371.1108(-2)
13½ / 15373.7719(13)
14½ / 15373.7063(8) / 15370.5755(2)
15½ / 15373.6299(12) / 15370.2926(27)
16½ / 15373.5401(-1) / 15369.9944(16)
17½ / 15373.4394(-6) / 15369.6825(-16)
18½ / 15373.3299(18)
19½ / 15373.2033(-11) / 15369.0300(-14)
20½ / 15373.0671(-19) / 15368.6852(-22)
21½ / 15372.9211(-8) / 15368.3302(-16)
22½ / 15372.7634(4)
23½ / 15372.5933(10) / 15367.5829(-24)
24½ / 15372.4106(7) / 15367.1948(4)
25½ / 15372.2174(17) / 15366.7920(2)
26½ / 15372.0107(9) / 15366.3775(0)
27½ / 15371.7930(10) / 15365.9504(-10)
28½ / 15371.5622(-3)
29½ / 15371.3206(-5) / 15365.0673(35)
30½ / 15371.0668(-11) / 15364.5966(-57)
31½ / 15364.1253(-38)
32½ / 15370.5261(0) / 15363.6428(-12)
33½ / 15363.1483(12)
34½ / 15369.9366(-3)
35½ / 15369.6229(-16)
36½ / 15369.2994(-9)
37½
38½ / 15368.6148(-13)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place.
Table C.7: Measurements and assignments of individual lines in the (A) 23/2 – (100) 23/2 band of 63Cu35Cl35Cl bandhead: 15378.3861cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
3½ / 15378.2404(-8)c / 15377.4217(-53)
4½ / 15378.2913(-18) / 15377.2728(-25)
5½ / 15378.3332(-6)c / 15377.6691(-32)c / 15377.1105(-20)
6½ / 15376.9352(-35)
7½ / 15377.5144(-26)c / 15376.7515(-22)
8½ / 15377.4217(-9)c / 15376.5523(-53)
9½ / 15376.3495(-9)
10½ / 15378.3707(-2) / 15376.1309(-11)
11½ / 15378.3456(7) / 15375.9027(1)
12½ / 15378.3087(9) / 15375.6629(8)
13½ / 15378.2609(14) / 15375.4120(16)
14½ / 15378.2015(14) / 15375.1496(20)
15½ / 15378.1313(18) / 15374.8764(28)
16½ / 15378.0472(-6) / 15374.5905(20)
17½ / 15377.9536(-12) / 15374.2960(38)
18½ / 15377.8495(-12) / 15373.9871(24)
19½ / 15377.7342(-12) / 15373.6696(35)
20½ / 15377.6075(-13) / 15373.3347(-16)c
21½ / 15377.4699(-11) / 15372.9979(26)
22½ / 15377.3210(-10) / 15372.6449(18)
23½ / 15377.1609(-8) / 15372.2821(25)
24½ / 15376.9895(-7)
25½ / 15376.8061(-12)
26½ / 15376.6113(-19) / 15371.1225(7)
27½ / 15376.4051(-26) / 15370.7143(9)
28½ / 15376.1910(0)
29½ / 15375.9621(-8) / 15369.8647(21)
30½ / 15375.7228(-6)
31½ / 15375.4730(5) / 15368.9647(-18)
32½ / 15375.2102(-1) / 15368.4984(-31)
33½ / 15374.9369(3) / 15368.0232(-18)
34½ / 15374.6532(17) / 15367.5340(-32)
35½ / 15374.3568(19) / 15367.0370(-10)
36½ / 15374.0498(29) / 15366.5269(-5)
37½ / 15366.0094(41)
38½ / 15365.4745(27)c
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. c Weight = 0.5 for this transition.
Table C.8: Measurements and assignments of individual lines in the (B) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 15776.8261cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15776.4599(0)
1 / 15776.4280(-6)c
2½ / 4 / 15776.1763(6)c / 15775.9256(2)
3 / 15776.1599(17)c
2 / 15776.5177(32) / 15776.1246(24)c / 15775.7841(-28)
3½ / 5 / 15776.6101(2) / 15776.1357(-6)c / 15775.7720(-3)
4 / 15776.1246(16)c / 15775.7503(6)
3 / 15776.5904(16) / 15775.7123(23)
2 / 15776.0836(13)c
4½ / 6 / 15776.6701(-5) / 15775.6147(-6)
5 / 15776.6653(24) / 15775.6004(11)
4 / 15776.6540(15) / 15775.5779(13)
15775.6072(3)e
3 / 15775.5570(17)
15775.5895(66)e
5½ / 7 / 15776.7209(-9) / 15775.4499(-11)
6 / 15775.4399(15)
5 / 15776.7073(14) / 15775.4230(9)
4 / 15775.4063(4)
6½ / 8 / 15776.7625(-10) / 15775.2775(-6)
7 / 15775.2693(17)
6 / 15775.2559(10)
5 / 15775.2417(-1)
7½ / 9 / 15776.7964(9) / 15775.0941(-20)
8 / 15775.0872(0)
7 / 15775.0768(2)
6 / 15775.0649(-8)
8½ / 10 / 15774.9015(-33)
8 / 15774.8885(5)
7 / 15774.8769(-17)
9½ / 11 / 15774.7009(-30)
9 / 15774.6891(-1)
8 / 15774.6789(-21)
10½ / 12 / 15774.4897(-38)
10 / 15774.4800(-4)
9 / 15774.4714(-17)
11½ / 13 / 15774.2696(-39)
11 / 15774.2623(7)
10 / 15774.2533(-18)
12½ / 14 / 15774.0396(-42)
12 / 15774.0321(-8)
11 / 15774.0243(-27)
13½ / 15 / 15776.7821(41)d / 15773.8009(-35)c
14 / 15773.8009(14)c
12 / 15773.7860(-29)
14½ / 16 / 15776.7451(29)d / 15773.5518(-34)c
15 / 15773.5518(11)c
13 / 15773.5393(-16)
15½ / 17 / 15776.6988(23)d / 15773.2924(-39)c
16 / 15773.2924(3)c
14 / 15773.2813(-17)
16½ / 18 / 15776.6428(17)d / 15773.0235(-41)c
17 / 15773.0235(-2)c
15 / 15773.0133(-19)
17½ / 15776.5776(18)
18½ / 15776.5022(15)
19½ / 15776.4173(16)
20½ / 15776.3221(11)
21½ / 15776.2173(9)
22½ / 15776.1026(7)
23½ / 15775.9785(8)
24½ / 15775.8440(5)
25½ / 15775.6997(1)
26½ / 15775.5458(0)
27½ / 15775.3824(3)
28½ / 15775.2090(4)
29½ / 15775.0242(-10)
30½ / 15774.8316(-4)
31½ / 15774.6292(3)
32½ / 15774.4158(-2)
33½ / 15774.1924(-8)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
Table C.9: Measurements and assignments of individual lines in the (B) 23/2 – (000) 23/2 band of 65Cu35Cl2, bandhead: 15732.4410cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15732.0572(0)c / 15731.8065(12)
2 / 15732.0572(-2)c / 15731.7572(55)c
2½ / 4 / 15732.1394(3) / 15731.7728(-7) / 15731.5216(0)
3 / 15732.1316(-14) / 15731.7572(-2)c
2 / 15732.1182(-36) / 15731.7353(28)
1 / 15732.1060(-35)
3½ / 5 / 15732.2099(-13) / 15731.7353(-6) / 15731.3700(-3)
4 / 15732.2022(-26) / 15731.7230(-14) / 15731.3486(-2)
15731.3797(-28)d
3 / 15732.1944(-14) / 15731.3574(-17)d
2 / 15732.1848(-13)
4½ / 6 / 15732.2712(-26) / 15731.2160(9)
5 / 15731.2009(2)
4 / 15732.2607(4) / 15731.1843(10)
15731.2094(6)d
3 / 15732.2499(-24)
5½ / 7 / 15732.3227(-42)c / 15731.6330(-29)c / 15731.0530(5)
6 / 15732.3227(12)c / 15731.6330(47)c / 15731.0409(-7)
5 / 15732.3156(6) / 15731.6208(15) / 15731.0305(15)
4 / 15732.3068(-13) / 15731.6075(-28)
6½ / 8 / 15732.3718(13) / 15730.8797(-17)
7 / 15732.3661(5)
6 / 15732.3608(9) / 15730.8644(18)
5 / 15732.3523(-16) / 15730.8516(-13)
7½ / 9 / 15732.4042(-4) / 15731.4992(-3) / 15730.7043(30)
8 / 15732.4008(8) / 15731.4932(-5) / 15730.6970(31)
7 / 15732.3955(6) / 15731.4867(-5) / 15730.6871(14)
6 / 15732.3884(-12) / 15731.4796(-11) / 15730.6764(-11)
8½ / 10 / 15730.5144(24)
9 / 15730.5089(34)
8 / 15730.4996(11)
7 / 15730.4948(33)
9½ / 11 / 15730.3148(16)
9 / 15730.3040(26)
8 / 15730.2957(5)
10½ / 12 / 15730.1058(10)
10 / 15730.0972(29)
9 / 15730.0895(7)
11½ / 13 / 15729.8870(3)
10 / 15729.8720(-2)
12½ / 14 / 15729.6581(-6)
11 / 15729.6467(11)
13½ / 15 / 15732.3990(8) / 15729.4119(-35)
14½ / 16 / 15732.3611(-17) / 15729.1696(16)
15½ / 17 / 15732.3164(-8) / 15728.9113(9)
16½ / 18 / 15732.2597(-14) / 15728.6436(10)
17½ / 15732.1931(-13) / 15728.3628(-17)
18½ / 15732.1156(-15) / 15728.0724(-35)
19½ / 15732.0277(-12) / 15727.7773(5)
20½ / 15731.9312(13) / 15727.4684(15)
21½ / 15727.1470(7)
22½ / 15726.8169(21)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 0 this transition.
Table C.10: Measurements and assignments of individual lines in the (C) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 15956.6867cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15956.4339(2) / 15956.1792(-2)
2 / 15956.4515(-15)
2½ / 4 / 15956.5100(2) / 15956.1501(5)
3 / 15956.5171(-8) / 15956.1572(34)
2 / 15956.5239(-2) / 15956.1572(-2)
3½ / 5 / 15956.5713(1) / 15956.1073(9)c / 15955.7440(-22)c
4 / 15956.5754(-7) / 15956.1073(-20c / 15955.7440(-12)c
4½ / 15956.6238(8) / 15956.0527(-1) / 15955.5840(-23)
5½ / 15956.6589(16) / 15955.9827(-8) / 15955.4132(-2)
6½ / 15956.6810(20) / 15955.9009(-7) / 15955.2280(2)
7½ / 15955.8050(-21) / 15955.0303(7)
8½ / 15955.7002(3) / 15954.8197(9)
9½ / 15956.6705(19) / 15954.5957(3)
10½ / 15956.6411(12) / 15955.4489(11) / 15954.3604(10)
11½ / 15956.5991(5) / 15954.1107(-1)
12½ / 15956.5459(12) / 15953.8492(-4)
13½ / 15956.4787(6) / 15953.5755(-2)
14½ / 15956.3998(8) / 15953.2883(-10)
15½ / 15956.3061(-11) / 15952.9894(-9)
16½ / 15952.6764(-22)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
Table C.11: Measurements and assignments of individual lines in the (C) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 15952.3627cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15952.1090(-5) / 15951.8630(6)c
2 / 15952.1265(-2) / 15951.8630(-39c)
1 / 15952.1348(-8)
2½ / 4 / 15952.1836(-3) / 15951.8354(22)c / 15951.5865(4)
3 / 15952.1903(-3) / 15951.8354(-1)c / 15951.5752(-5)c
2 / 15952.1952(-4) / 15951.5752(36)c
3½ / 15951.7931(-1) / 15951.4380(-16)
4½ / 15952.2949(1) / 15951.7388(-2) / 15951.2838(-5)
5½ / 15952.3294(-2) / 15951.6734(6) / 15951.1166(-4)
6½ / 15952.3517(-7) / 15951.5947(2) / 15950.9377(0)
7½ / 15951.5047(6) / 15950.7467(4)
8½ / 15951.4025(8) / 15950.5434(6)
9½ / 15950.3270(-3)
10½ / 15952.3239(11) / 15951.1614(6) / 15950.0997(-1)
11½ / 15952.2863(10) / 15951.0227(4) / 15949.8605(3)
12½ / 15952.2375(18) / 15950.8718(1) / 15949.6090(4)
13½ / 15952.1731(-10) / 15950.7102(12) / 15949.3452(3)
14½ / 15952.0991(-13) / 15949.0705(13)
15½ / 15952.0140(-7) / 15950.3454(-21) / 15948.7796(-18)
16½ / 15951.9179(10) / 15948.4811(-4)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
Table C.12: Measurements and assignments of individual lines in the (C) 23/2 – (000) 23/2 band of 63Cu37Cl2 bandhead: 15949.8946cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15949.6372(6) / 15949.3953(-1)
2 / 15949.6572(3) / 15949.4056(1)
2½ / 4 / 15949.7113(11) / 15949.3688(1) / 15949.1248(-26)c
3 / 15949.7196(8) / 15949.3768(32)c / 15949.1248(26)c
2 / 15949.7257(2) / 15949.3768(-11)c
3½ / 5 / 15949.7719(17) / 15948.9882(-9)d
4 / 15949.7769(14)
3 / 15949.7808(9)c
4½ / 15949.8233(13)c / 15949.2781(-33) / 15948.8380(-10)
5½ / 15949.2179(-2) / 15948.6767(-7)
6½ / 15949.1423(-9) / 15948.5028(-15)
7½ / 15949.0590(21) / 15948.3173(-24)
8½ / 15948.9600(9)
9½
10½
11½ / 15949.8233(-18)c
12½ / 15949.7808(13)c
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition.
Table C.13: Measurements and assignments of individual lines in the 23/2 – (000) 23/2 band of Cu35Cl2 bandhead: 15963.2022cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15962.8337(6)c / 15962.5810(8)
2 / 15962.8337(-4)c / 15962.6112(-6)e
1 / 15962.8232(-4)
2½ / 4 / 15962.9169(24) / 15962.2961(1)
3 / 15962.3115(-10)d
2 / 15962.9021(0)
3½ / 5 / 15962.1448(-7)
4 / 15962.1270(8)
15962.1554(-15)d
3 / 15962.1362(3)d
2 / 15962.9660(-13)
4½ / 6 / 15961.9896(-5)
5 / 15961.9788(12)
4 / 15961.9647(5)
3 / 15961.9518(-10)
5½ / 7 / 15961.8254(-12)
6 / 15961.8186(13)
5 / 15961.8085(10)
4 / 15961.7980(-5)
6½ / 8 / 15963.1386(-16)c / 15961.6538(-5)
7 / 15963.1386(23)c / 15961.6482(14)
6 / 15963.1327(7) / 15961.6398(7)
5 / 15963.1265(-11) / 15961.6312(-5)
7½ / 9 / 15963.1709(-13)c / 15961.4714(-12)
8 / 15963.1709(23)c / 15961.4684(20)
7 / 15963.1657(9) / 15961.4609(9)
6 / 15963.1601(-8) / 15961.4531(-7)
8½ / 10 / 15963.1942(-3) / 15961.2800(-15)
8 / 15963.1879(2)c / 15961.2714(8)
7 / 15961.2647(-6)
9½ / 11 / 15961.0790(-17)
9 / 15961.0723(11)
8 / 15961.0662(-3)
10½ / 12 / 15960.8693(-9)
11 / 15960.8640(-20)c
10 / 15960.8640(22)c
9 / 15960.8577(1)
11½ / 13 / 15960.6498(-1)
11 / 15960.6402(-22)c
10 / 15960.6402(16)c
12½ / 14 / 15960.4205(6)
12 / 15960.4118(-13)c
11 / 15960.4118(22)c
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 0 for this transition. e F = 1 for this transition.
Table C.14: Measurements and assignments of individual lines in the 23/2 – (000) 23/2 band of Cu35Cl2 bandhead: 15963.0945cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 15962.7801(6) / 15962.5264(14)
2 / 15962.7896(-2)c / 15962.5116(-17)
1 / 15962.7896(-23)c / 15962.5034(-27)
2½ / 4 / 15962.8602(12)d / 15962.4953(-1) / 15962.2410(2)
3 / 15962.4913(8) / 15962.2151(11)
15962.2552(-21)e
2 / 15962.2026(29)
15962.2274(0)e
3½ / 5 / 15962.9261(2)d / 15962.4553(-6)c / 15962.0919(-1)
4 / 15962.4553(27)c / 15962.0826(6)
3 / 15962.0739(6)
4½ / 6 / 15962.9813(-6)d / 15962.4037(10) / 15961.9347(-2)
5 / 15961.9299(10)
4 / 15961.9240(5)
5½ / 15963.0256(-12) / 15962.3427(3) / 15961.7655(22)
6½ / 15963.0590(-18) / 15962.2699(-12) / 15961.5879(12)
7½ / 15963.0824(-15) / 15962.1873(-15) / 15961.3993(2)
8½ / 15961.1993(-13)
9½ / 15961.9894(-20) / 15960.9898(-13)
10½ / 15961.8750(-12) / 15960.7700(-6)
11½ / 15960.5399(7)
12½ / 15961.6139(9) / 15960.2983(15)
13½ / 15960.0458(24)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
Table C.15: Measurements and assignments of individual lines in the (D) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16137.1397cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16137.0463(-23) / 16136.7898(-24)
16137.0302(-2)e
2 / 16137.0591(-29)
2½ / 4 / 16136.5060(-20)
3 / 16136.4857(-31)
2 / 16136.4758(-33)c
1 / 16136.4758(-13)c
3½ / 5 / 16137.1991(-6)d / 16136.3589(-22)
4 / 16136.3522(-20)
3 / 16136.3462(-26)
4½ / 16137.2563(-4) / 16136.6754(-11) / 16136.2022(4)
5½ / 16137.3031(2) / 16136.6166(-6) / 16136.0371(1)
6½ / 16137.3396(13) / 16136.5472(1) / 16135.8621(6)
7½ / 16137.3647(18) / 16136.4672(9) / 16135.6765(14)
8½ / 16136.3758(12) / 16135.4799(19)
9½ / 16136.2746(24) / 16135.2722(21)
10½ / 16136.1611(21) / 16135.0532(18)
11½ / 16137.3562(27) / 16134.8245(26)
12½ / 16137.3261(20) / 16135.9027(25) / 16134.5846(29)
13½ / 16137.2847(7) / 16135.7567(21) / 16134.3328(22)
14½ / 16137.2319(-12) / 16135.5996(14) / 16134.0721(33)
15½ / 16137.1680(-34) / 16135.4300(-11) / 16133.7982(20)
16½ / 16137.0928(-61) / 16133.5137(9)
17½ / 16133.2166(-20)
18½ / 16132.9082(-54)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
Table C.16: Measurements and assignments of individual lines in the (D) 23/2 – (000) 23/2 band of 65Cu35Cl2, bandhead: 16129.9482cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16129.7731(24) / 16129.5244(5)
2 / 16129.7873(-8) / 16129.5551(-26)d
1 / 16129.5424(-50)d
2½ / 4 / 16129.8399(16) / 16129.2391(-11)
3 / 16129.8455(10) / 16129.2251(-5)
16129.2554(-24)e
3½ / 16129.8933(13)
4½ / 16129.9273(10) / 16129.3680(-8) / 16128.9120(-7)
5½ / 16129.2860(-9) / 16128.7294(0)
6½ / 16129.1894(-6) / 16128.5328(16)
7½ / 16128.3206(25)
8½ / 16129.9153(7) / 16128.9506(-10) / 16128.0923(23)
9½ / 16129.8745(1) / 16128.8100(-1) / 16127.8473(2)
10½ / 16129.8196(3) / 16128.6540(4) / 16127.5896(3)
11½ / 16129.7492(-1) / 16128.4836(13) / 16127.3174(8)
12½ / 16129.6646(2) / 16128.2971(11) / 16127.0294(4)
13½ / 16129.5637(-8) / 16126.7276(11)
14½ / 16129.4503(5) / 16127.8787(-1) / 16126.4078(-13)
15½ / 16129.3161(-41) / 16127.6491(13)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 1 for this transition. e F = 0 for this transition.
Table C.17: Measurements and assignments of individual lines in the (D) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 16126.0000cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16125.8002(-4) / 16125.5575(16)
2 / 16125.8218(4) / 16125.5711(33)
1 / 16125.8345(11)
2½ / 4 / 16125.8696(-7) / 16125.5247(4) / 16125.2810(14)
3 / 16125.8796(2) / 16125.5326(24)
2 / 16125.8873(7)
3½ / 5 / 16125.9232(-10) / 16125.4791(12) / 16125.1337(-4)c
4 / 16125.9302(3)
4½ / 6 / 16125.9629(-7) / 16125.4247(37) / 16124.9750(16)c
5 / 16125.9680(2)
5½ / 16125.3488(26) / 16124.8012(22)
6½ / 16125.2581(5) / 16124.6121(11)
7½ / 16125.1527(-28) / 16124.4094(0)
8½ / 16125.9863(15) / 16125.0379(-19) / 16124.1934(-8)
9½ / 16125.9533(-16) / 16124.9097(-7) / 16123.9639(-15)
10½ / 16125.9094(-20) / 16124.7662(-12) / 16123.7216(-13)
11½ / 16125.8523(-20) / 16123.4638(-31)
12½ / 16125.7817(-18) / 16124.4391(-15) / 16123.1947(-25)
13½ / 16125.6978(-13) / 16124.2551(-17) / 16122.9106(-33)
14½ / 16125.6011(0) / 16124.0584(-9) / 16122.6148(-21)
15½ / 16123.8476(-6) / 16122.3053(-11)
16½ / 16125.3673(31) / 16123.6232(-3) / 16121.9826(4)
17½ / 16125.2296(43)
18½ / 16125.0781(54)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Hyperfine structure was not resolved for this transition.
Table C.18: Measurements and assignments of individual lines in the (D) 23/2 – (000) 23/2 band of 65Cu35Cl37Cl, bandhead: 16123.1741cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16122.9650(3)
16122.9496(25)d
2 / 16122.9794(-14)
1 / 16122.9851(-28)
2½ / 4 / 16123.0341(-12) / 16122.4463(4)
3 / 16123.0420(14)c / 16122.4308(22)c
16122.4609(-24)d
2 / 16123.0420(-23)c
3½ / 16123.0927(-5) / 16122.6430(0) / 16122.2981(12)
4½ / 16122.5834(-10) / 16122.1355(13)
5½ / 16121.9627(3)
6½ / 16121.7796(19)
7½ / 16121.5803(4)
8½ / 16121.3687(-3)
9½ / 16121.1457(6)
10½ / 16123.1034(-55) / 16120.9114(32)
11½ / 16123.0571(-19)
12½ / 16120.3952(0)
13½ / 16120.1234(43)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 0 for this transition.
Table C.19: Measurements and assignments of individual lines in the (D) 23/2 – (000) 23/2 band of 63Cu37Cl2, bandhead: 16116.3120cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16116.0820(-37) / 16115.8449(22)
2 / 16115.8731(-14)f
1 / 16115.8577(-31)f
2½ / 4 / 16116.1561(29) / 16115.8115(-6)c / 16115.5701(-46)
16115.7978(31)g
3 / 16115.8115(3)c / 16115.5580(10)
16115.7978(10)g / 16115.5909(-4)e
2 / 16115.8115(13)c / 16115.5509(25)
1 / 16115.5434(-35)
3½ / 5 / 16116.2105(19)d / 16115.7698(9)d / 16115.4313(0)
4 / 16115.4253(0)
3 / 16115.4178(-27)c
2 / 16115.4178(-2)c
4½ / 6 / 16116.2530(11)d / 16115.7153(8)d / 16115.2766(-11)
4 / 16115.2719(2)
5½ / 16116.2862(31)c / 16115.6485(5) / 16115.1124(19)
6½ / 16115.5688(-6) / 16114.9349(6)
7½ / 16115.4789(1) / 16114.7453(-6)
8½ / 16115.3762(2) / 16114.5443(-12)
9½ / 16115.2607(-5)
10½ / 16116.2597(17) / 16115.1341(-2)
11½ / 16116.2190(23)
12½ / 16116.1648(15)
13½ / 16116.0955(-23)
14½ / 16116.0190(-13)
15½ / 16115.9309(3)
16½ / 16115.8282(-7)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 0 for this transition. e F = 1 for this transition. f F = -1for this transition.
Table C.20: Measurements and assignments of individual lines in the (E) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16122.8171cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16122.5335(4)c / 16122.2860(20)
2 / 16122.5335(6)c / 16122.2364(-18)
2½ / 4 / 16122.6097(0) / 16122.2500(11) / 16122.0020(22)
3 / 16122.6052(11) / 16122.2371(34) / 16121.9403(14)
2 / 16121.9070(28)
1 / 16122.1968(-10) / 16121.9156(21)e
3½ / 5 / 16122.6745(-4) / 16122.2079(16) / 16121.8461(6)
4 / 16122.6700(8) / 16122.1968(13) / 16121.8268(17)
16121.8557(-11)e
3 / 16122.6608(-7) / 16122.1835(10) / 16121.8014(7)
16121.8354(7)e
2 / 16122.1698(-9)
4½ / 6 / 16122.7276(-16)c / 16122.1542(3) / 16121.6851(-2)
5 / 16122.7276(38)c / 16122.1457(2) / 16121.6720(1)
16121.6922(-18)e
4 / 16122.7168(-6) / 16121.6573(5)
3 / 16122.7084(-22) / 16122.1259(-6) / 16121.6430(-7)
5½ / 7 / 16122.7708(-17) / 16122.0913(1) / 16121.5153(-7)
6 / 16122.7682(6) / 16122.0847(5) / 16121.5066(7)
5 / 16122.7617(-3) / 16122.0770(5) / 16121.4952(3)
4 / 16122.7550(-12) / 16122.0678(-10) / 16121.4832(-15)
6½ / 8 / 16122.8020(-28) / 16122.0207(28) / 16121.3358(-8)
7 / 16122.7955(-49)c / 16121.3296(11)
6 / 16122.7955(0)c / 16121.3198(0)
5 / 16122.7883(-20) / 16122.0020(31) / 16121.3097(-17)
7½ / 9 / 16121.1449(-18)
8 / 16121.9285(0)
7 / 16121.1327(0)
6 / 16121.1239(-18)
8½ / 10 / 16120.9454(-7)
9 / 16120.9416(13)
8 / 16120.9352(11)
7 / 16120.9274(-6)
9½ / 11 / 16120.7345(-1)
9 / 16120.7259(18)
8 / 16120.7193(5)
10½ / 12 / 16121.6071(-30)d / 16120.5109(-13)
10 / 16120.5039(10)
9 / 16120.4972(-9)
11½ / 13 / 16122.7955(-15)c,d / 16120.2758(-31)c
12 / 16120.2758(11)c
10 / 16120.2639(-22)
12½ / 16122.7617(-17)c / 16120.0310(19)
13½ / 16119.7747(6)
14½ / 16122.6608(-20) / 16119.5074(-6)
15½ / 16119.2298(-10)
16½ / 16122.5144(-34) / 16118.9397(-28)
17½ / 16122.4286(-1)
18½ / 16122.3296(12)
19½ / 16122.2202(32)
20½ / 16122.0983(38)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
Table C.21: Measurements and assignments of individual lines in the (E) 23/2 – (000) 23/2 band of 63Cu37Cl2, bandhead: 16118.6399cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16118.3252(38)c / 16118.0841(1)
2 / 16118.3252(1)c / 16118.0529(15)c
16118.1121(-37)e
1 / 16118.0251(-66)c
16118.0677(-43)e
0 / 16118.0415(-3)c,e
2½ / 4 / 16118.3967(6) / 16118.0529(-5)c / 16117.8160(0)
3 / 16118.3880(-53)c / 16118.0415(-3)c / 16117.7691(10)
16117.8324(-1)d
2 / 16118.3880(3)c / 16118.0251(-23)c / 16117.7436(23)
16117.7794(-22)d
1 / 16118.3803(-8) / 16117.7356(45)
16117.7516(10)d
3½ / 5 / 16118.4616(14) / 16118.0149(-5) / 16117.6720(-6)
4 / 16118.4530(-36)c / 16118.0066(-7) / 16117.6567(8)
16117.6822(-18)d
3 / 16118.4530(13)c / 16117.9980(0) / 16117.6377(0)
16117.6654(-2)d
2 / 16118.4458(-6) / 16117.9878(-19) / 16117.6248(-7)
16117.6438(-16)d
4½ / 6 / 16118.5162(21) / 16117.9688(5) / 16117.5232(-3)
5 / 16118.5092(-14) / 16117.9628(8) / 16117.5140(13)
4 / 16118.5031(-32) / 16117.9557(6) / 16117.5020(6)
3 / 16117.9475(-10) / 16117.4908(-10)
5½ / 7 / 16118.5614(34) / 16117.9122(5) / 16117.3664(5)
6 / 16118.5558(11) / 16117.3600(20)
5 / 16118.5498(-11) / 16117.3509(12)
4 / 16117.8953(-2) / 16117.3415(-7)
6½ / 8 / 16117.8455(1) / 16117.1999(8)
7 / 16117.1951(23)
6 / 16117.1881(18)
5 / 16117.8312(-4) / 16117.1803(2)
7½ / 9 / 16117.0235(8)
7 / 16117.0143(22)
6 / 16117.0073(4)
8½ / 16117.6822(39)
14½ / 16118.4967(-26)
16½ / 16118.3803(38)
17½ / 16118.2972(-28)
18½ / 16118.2116(-19)
19½ / 16118.1131(-38)
22½ / 16117.7685(19)
25½ / 16117.3271(15)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d F = 0 for this transition. d F = 1 for this transition.
Table C.22: Measurements and assignments of individual lines in the (F) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16257.5112cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
2½ / 16256.7519(-11)
3½ / 16256.9609(-15) / 16256.6024(-5)
4½ / 16256.4379(-13)
5½ / 16256.8266(-4) / 16256.2613(-7)
6½ / 16256.7405(15) / 16256.0707(-6)
7½ / 16255.8663(-7)
8½ / 16257.4997(15) / 16256.5224(1) / 16255.6487(-5)
9½ / 16257.4733(11) / 16256.3933(-4) / 16255.4177(-1)
10½ / 16257.4343(16) / 16255.1736(7)
11½ / 16257.3812(16) / 16254.9144(0)
12½ / 16257.3135(6) / 16255.9261(-2) / 16254.6421(-2)
13½ / 16257.2337(10) / 16254.3562(-5)
14½ / 16257.1382(-6) / 16254.0568(-8)
15½ / 16257.0320(6) / 16253.7437(-11)
16½ / 16256.9107(3) / 16253.4177(-8)
17½ / 16256.7774(16) / 16253.0777(-9)
18½ / 16256.6290(14) / 16252.7265(14)
19½ / 16256.4662(4) / 16252.3593(13)
20½ / 16256.2903(-1) / 16251.9782(9)
21½ / 16256.1006(-7) / 16251.5836(6)
22½ / 16255.8986(0) / 16251.1750(-1)
23½ / 16255.6826(3)
24½ / 16255.4525(2) / 16250.3176(-8)
25½ / 16255.2097(11) / 16249.8686(-11)
26½ / 16254.9524(11) / 16249.4057(-15)
27½ / 16254.6812(9) / 16248.9301(-10)
28½ / 16254.3958(2) / 16248.4410(-4)
29½ / 16254.0950(-22) / 16247.9370(-10)
30½ / 16253.7843(-8)
31½ / 16253.4588(-5)
32½ / 16253.1193(-4)
33½ / 16252.7675(11)
35½ / 16252.0175(-11)
36½ / 16251.6242(3)
37½ / 16251.2172(17)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place.
Table C.23: Measurements and assignments of individual lines in the (F) 23/2 – (000) 23/2 band of 65Cu35Cl2, bandhead: 16254.1584cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
5½ / 16253.4851(4) / 16252.9207(-4)
7½ / 16253.2899(-18) / 16252.5234(3)
8½ / 16253.1764(18) / 16252.3070(35)
9½ / 16254.1179(-17) / 16253.0444(8) / 16252.0712(11)
10½ / 16254.0755(-18) / 16251.8242(13)
11½ / 16254.0190(-23) / 16251.5620(1)
12½ / 16253.9495(-19) / 16252.5703(23) / 16251.2890(19)
13½ / 16253.8667(-11) / 16251.0004(19)
14½ / 16253.7690(-13) / 16250.6946(-16)
15½ / 16253.6580(-11)
16½ / 16253.5328(-12) / 16250.0482(-19)
17½ / 16253.3976(24) / 16249.7053(-11)
18½ / 16253.2409(-16) / 16249.3481(-7)
19½ / 16248.9785(10)
20½ / 16252.8988(30) / 16248.5898(-26)
21½ / 16252.7061(43) / 16248.1928(-7)
22½ / 16247.7793(-15)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place.
Table C.24: Measurements and assignments of individual lines in the (F) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 16252.4003cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / R(J) / Q(J) / P(J)
2½ / 16251.9119(6)
3½ / 16251.8665(4) / 16251.5161(6)
4½ / 16251.3586(15)
5½ / 16251.1867(9)
6½ / 16251.6539(12) / 16251.0004(-12)c
7½ / 16250.8038(-7)
8½ / 16250.5931(-13)
9½ / 16252.3753(6) / 16251.3223(-7) / 16250.3708(-6)
10½ / 16252.3397(7) / 16250.1345(-10)
11½ / 16252.2914(9) / 16251.0370(-15) / 16249.8857(-9)
12½ / 16252.2300(10) / 16250.8757(-11) / 16249.6229(-19)
13½ / 16252.1568(23) / 16249.3487(-14)
14½ / 16250.5156(9) / 16249.0623(-1)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. c Weight =0.5 for this transition.
Table C.25: Measurements and assignments of individual lines in the (G) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16339.8108cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16339.5279(13) / 16339.2774(37)
16339.5058(19)e
2 / 16339.5362(7)c / 16339.2608(21)
16339.5174(16)e
1 / 16339.5362(-1)c / 16339.2501(6)
16339.5174(-50)e
2½ / 4 / 16339.6049(18)d / 16338.9915(19)
3 / 16338.9616(21)
2 / 16338.9464(32)
16338.9724(-4)e
3½ / 5 / 16339.6684(4)d / 16339.2010(-1) / 16338.8399(9)
4 / 16338.8284(7)
16338.8507(3)e
3 / 16339.1919(-7) / 16338.8189(12)
4½ / 6 / 16339.7209(-6)d / 16339.1480(-8) / 16338.6807(6)
5 / 16338.6736(4)
4 / 16338.6667(-1)
3 / 16338.6618(-1)
5½ / 7 / 16339.7624(-11)d / 16339.0837(17) / 16338.5107(-2)
6 / 16338.5061(1)
6½ / 8 / 16339.7920(-22)d / 16339.0069(-9) / 16338.3293(-15)
7 / 16338.3260(-10)
6 / 16338.3217(-17)
7½ / 9 / 16338.1364(6)
8½ / 10 / 16337.9316(-23)
9½ / 11 / 16337.7179(-27)
10½ / 12 / 16338.5918(-50) / 16337.4932(-27)
11½ / 13 / 16338.4621(-33) / 16337.2576(-21)
12½ / 16339.7361(-20) / 16337.0098(-23)
13½ / 16339.6883(-5) / 16336.7511(-21)
14½ / 16336.4820(-7)
15½ / 16339.5566(8) / 16336.2026(17)
16½ / 16335.9124(48)
17½ / 16335.6087(58)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
Table C.26: Measurements and assignments of individual lines in the (G) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 16328.8180cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
2½ / 4 / 16328.0677(46)
3 / 16328.0442(29)
2 / 16328.0333(32)
3½ / 5 / 16328.7159(7)d / 16327.9190(39)
4 / 16327.9107(35)
3 / 16327.9025(19)
2 / 16327.8974(5)
4½ / 6 / 16328.7615(8)d / 16328.2062(-19) / 16327.7609(39)
3 / 16327.7453(-3)
5½ / 16328.7942(2) / 16328.1397(10) / 16327.5836(-7)
6½ / 16328.0593(5) / 16327.4051(15)
7½ / 16327.9668(1) / 16327.2111(5)
8½ / 16327.8601(-21) / 16327.0054(0)
9½ / 16328.8015(-24) / 16326.7873(-5)
10½ / 16328.7734(-23) / 16327.6133(-31) / 16326.5568(-12)
11½ / 16328.7324(-28) / 16327.4732(-19) / 16326.3143(-16)
12½ / 16328.6793(-30) / 16327.3181(-34) / 16326.0610(-5)
13½ / 16328.6146(-26) / 16325.7915(-33)
14½ / 16328.5386(-12) / 16325.5122(-36)
15½ / 16328.4479(-22) / 16325.2199(-46)
16½ / 16324.9184(-25)
17½ / 16324.6034(-16)
18½ / 16324.2764(-4)
19½ / 16323.9403(40)
20½ / 16323.5888(52)
21½ / 16323.2291(106)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
Table C.27: Measurements and assignments of individual lines in the 23/2 – (000) 23/2 band of Cu35Cl2 bandhead: 16325.4039cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16325.1901(-9) / 16324.9357(-10)
2 / 16324.9651(-4)
2½ / 4 / 16325.2642(0) / 16324.9077(4) / 16324.6515(-15)
3 / 16324.6652(-4)
2 / 16325.2906(-19) / 16324.6770(5)
3½ / 5 / 16325.3203(0) / 16324.8614(4) / 16324.5034(-7)
4 / 16325.3301(-7) / 16324.8710(-1) / 16324.5129(-5)
3 / 16325.3378(-21) / 16324.8793(-6) / 16324.5214(-1)
2 / 16325.3459(-11) / 16324.8864(-4) / 16324.5280(-2)
4½ / 6 / 16325.3607(-2) / 16324.8004(10) / 16324.3401(-1)
5 / 16325.3689(0) / 16324.8079(7) / 16324.3470(-4)
4 / 16324.8140(0)
3 / 16324.8197(-1) / 16324.3586(-10)
5½ / 7 / 16325.3879(11) / 16324.1621(5)
6 / 16324.1678(2)
5 / 16324.1729(-1)
6½ / 16323.9764(14)
7½ / 16323.7677(8)
8½ / 16325.3815(-16) / 16323.5480(33)
9½ / 16325.3502(-9)c / 16323.3130(46)
10½ / 16323.0617(38)
11½ / 16325.2444(-1) / 16322.7961(28)
12½ / 16325.1672(-28) / 16322.5173(27)
13½ / 16325.0772(-42) / 16322.2222(4)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
Table C.28: Measurements and assignments of individual lines in the 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 16389.1148cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16388.8103(-2) / 16388.5631(-5)
2 / 16388.8186(-8)c / 16388.5478(-11)
1 / 16388.8186(-16)c / 16388.5405(6)
2½ / 4 / 16388.8868(3)c,d / 16388.5334(-8) / 16388.2859(-14)
3 / 16388.5278(-4) / 16388.2569(-8)
2 / 16388.5200(-20)c / 16388.2412(-5)
1 / 16388.5200(26)c
3½ / 5 / 16388.9514(-1)c,d / 16388.4928(-26)c / 16388.1412(-6)
4 / 16388.4928(15)c / 16388.1310(2)
3 / 16388.4862(-9) / 16388.1211(2)
2 / 16388.4818(-17) / 16388.1151(4)
4½ / 6 / 16389.0053(-5)c,d / 16388.4436(10)c,,d / 16387.9894(7)
5 / 16387.9882(63)
4 / 16387.9770(13)
3 / 16387.9716(8)
5½ / 7 / 16389.0486(-9)c,d / 16388.3839(1)d / 16387.8267(7)
6 / 16387.8227(15)
5 / 16387.8175(8)
4 / 16387.8132(4)
6½ / 8 / 16389.0814(-10)c,d / 16387.6514(-17)c
7 / 16387.6514(20)c
6 / 16387.6469(10)
5 / 16387.6428(0)
7½ / 16389.1038(-9)c / 16388.2331(-11) / 16387.4669(8)
8½ / 16387.2720(-9)
9½ / 16387.0693(3)
10½ / 16386.8542(-1)
11½ / 16386.6293(3)
12½ / 16386.3944(14)
15½ / 16388.8956(-22)
17½ / 16388.7402(12)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition.
Table C.29: Measurements and assignments of individual lines in the (H) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16431.3619cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16431.0486(-1)c / 16430.8011(11)
16431.0195(42)e / 16430.7119(-3)g
2 / 16431.0486(16)c / 16430.8297(-19)f
16431.0088(13)e
1 / 16431.0256(-23) / 16430.7119(17)c
16430.7640(-3)f
2½ / 4 / 16431.1259(3) / 16430.7640(-6) / 16430.5159(0)
16430.7317(5)g
3 / 16431.1199(12) / 16430.7484(7) / 16430.4474(28)
16430.7799(-12)f / 16430.5317(-7)c,e
2 / 16431.1058(-6) / 16430.7218(2) / 16430.4577(-3)e
16431.0834(-7)e
1 / 16431.0935(2)
3½ / 5 / 16431.1915(-1) / 16430.7218(-4) / 16430.3605(-6)
4 / 16431.1864(18) / 16430.7117(16) / 16430.3402(11)
16430.3710(-15)e
3 / 16431.1757(8) / 16430.6947(6) / 16430.3098(5)
16430.6559(4)f / 16430.3494(6)e
2 / 16431.1648(2) / 16430.6786(-8) / 16430.2894(8)
16430.3159(-10)e
4½ / 6 / 16431.2469(0) / 16430.6704(-2) / 16430.2009(-3)
5 / 16431.2422(17) / 16430.6626(17) / 16430.1871(7)
4 / 16431.2336(11) / 16430.6501(9) / 16430.1688(4)
16430.1943(3)e
3 / 16431.2233(-6) / 16430.6371(-6) / 16430.1520(-4)
5½ / 7 / 16431.2917(0) / 16430.6086(-4) / 16430.0319(-8)
6 / 16430.6025(16) / 16430.0223(9)
5 / 16431.2804(15) / 16430.5925(9) / 16430.0089(6)
4 / 16431.2714(-3) / 16430.5814(-7) / 16429.9948(-10)
6½ / 8 / 16431.3243(-14)c / 16430.5366(-5) / 16429.8536(-8)
7 / 16431.3243(38)c / 16430.5317(16) / 16429.8463(11)
6 / 16431.3158(14) / 16430.5228(5) / 16429.8353(4)
5 / 16431.3069(-11) / 16429.8232(-16)
7½ / 9 / 16430.4540(-6) / 16429.6645(-14)
8 / 16429.6592(10)
7 / 16429.6501(4)
6 / 16430.4340(-9) / 16429.6401(-10)
8½ / 10 / 16429.4660(-10)
9 / 16429.4612(9)
8 / 16429.4534(4)
7 / 16429.4449(-8)
9½ / 11 / 16429.2556(-20)
9 / 16429.2455(2)
8 / 16429.2371(-17)
10½ / 12 / 16429.0349(-25)
10 / 16429.0264(-1)
9 / 16429.0180(-28)
11½ / 13 / 16428.8029(-37)
11 / 16428.7961(-6)
10 / 16428.7888(-28)
12½ / 14 / 16431.3069(25) / 16428.5626(-24)c
13 / 16431.3030(20) / 16428.5626(20)c
11 / 16428.5506(-7)
13½ / 15 / 16431.2613(29)d / 16428.3085(-42)c
14 / 16428.3085(-1)c
12 / 16428.2975(-26)
14½ / 16 / 16431.2090(25)d / 16428.0459(-36)c
15 / 16428.0459(1)c
13 / 16428.0363(-16)
15½ / 17 / 16431.1459(22)d / 16427.7720(-36)c
16 / 16427.7720(-1)c
14 / 16427.7627(-21)
16½ / 18 / 16431.0713(13)d / 16427.4881(-28)c
17 / 16427.4881(5)c
15 / 16427.4801(-7)
17½ / 16430.9816(-39)
18½ / 16430.8912(11) / 16426.8833(-14)
19½ / 16426.5689(12)
20½ / 16426.2421(23)
21½ / 16425.9017(6)
23½ / 16425.1927(17)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
d Hyperfine structure was not resolved for this transition. e F = 0 for this transition.
f F = 1 for this transition. g F = -1 for this transition.
Table C.30: Measurements and assignments of individual lines in the (H) 23/2 – (000) 23/2 band of 63Cu35Cl37Cl, bandhead: 16426.4493cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16426.1436(8)c / 16425.9017(14)
16426.1141(27)e / 16425.8259(35)c,g
2 / 16426.1436(10)c / 16425.8523(-13)
16426.1081(-1)e / 16425.9298(-16)f
1 / 16426.1254(-29) / 16425.8259(4)
0 / 16426.1081(-55)
2½ / 4 / 16426.2183(2) / 16425.8678(13) / 16425.6248(8)
16425.8365(14)g
3 / 16425.8523(9) / 16425.5616(-8)
16425.8817(-11)f / 16425.6397(-5)e
2 / 16426.2017(-11) / 16425.5294(21)
16426.1827(-5)e / 16425.5731(-24)e
1 / 16426.1908(-15) / 16425.5151(20)
3½ / 5 / 16426.2840(16) / 16425.8259(2) / 16425.4768(27)
4 / 16425.8164(14) / 16425.4573(34)
16425.4860(7)e
3 / 16426.2704(16) / 16425.8033(16) / 16425.4307(17)
16425.4659(25)e
2 / 16426.2613(8) / 16425.7883(-13) / 16425.4124(5)
16425.4365(0)e
4½ / 6 / 16426.3319(-45)c / 16425.7768(11) / 16425.3215(26)
5 / 16426.3319(9)c / 16425.7698(26) / 16425.3092(36)
4 / 16426.3218(-26) / 16425.7594(20) / 16425.2928(25)
3 / 16426.3130(-45) / 16425.7490(11) / 16425.2782(13)
5½ / 7 / 16426.3775(-24)c / 16425.7109(-50) / 16425.1570(18)
6 / 16426.3775(25)c / 16425.7059(-29) / 16425.1486(35)
5 / 16426.3684(-9) / 16425.6977(-32) / 16425.1376(37)
4 / 16426.3614(-19) / 16425.1258(23)
6½ / 8 / 16426.4114(-16) / 16424.9775(-43)
7 / 16426.4048(-37)c / 16425.6397(-2) / 16424.9725(-12)
6 / 16424.9630(-19)
5 / 16426.3977(-6) / 16424.9532(-32)
7½ / 9 / 16425.5637(-19)c / 16424.7958(-27)
8 / 16425.5637(33)c / 16424.7913(-4)
7 / 16425.5542(-4) / 16424.7833(-11)
6 / 16424.7745(-27)
8½ / 10 / 16425.4659(-25) / 16424.6034(-16)
8 / 16424.5934(5)
7 / 16424.5859(-8)
14½ / 16426.3003(45)
17½ / 16426.0810(14)
19½ / 16426.5689(12)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
e F = 0 for this transition. f F = 1 for this transition. g F = -1 for this transition.
Table C.31: Measurements and assignments of individual lines in the (I) 23/2 – (000) 23/2 band of 63Cu35Cl2, bandhead: 16504.1417cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16503.8726(21) / 16503.6246(21)
2 / 16503.5774(0)
16503.6526(-15)f
1 / 16503.8584(11) / 16503.5508(5)c
16503.5955(-24)f
0 / 16503.5606(3)f
2½ / 4 / 16503.9474(20) / 16503.5861(-2) / 16503.3396(12)
3 / 16503.9432(32) / 16503.5724(11) / 16503.2790(8)
16503.3537(-12)e
2 / 16503.9328(19) / 16503.5508(-1)c / 16503.2466(27)
16503.2910(-5)e
1 / 16503.9211(2) / 16503.5329(-31)c / 16503.2552(21)e
3½ / 5 / 16504.0098(13) / 16503.5424(4) / 16503.1823(-6)
4 / 16504.0067(39) / 16503.5329(15)c / 16503.1634(7)
3 / 16503.9972(19) / 16503.5190(4) / 16503.1386(-1)
16503.1723(-1)e
2 / 16503.9880(6) / 16503.5060(-10) / 16503.1219(-2)
4½ / 6 / 16504.0601(1) / 16503.4875(0) / 16503.0213(3)
5 / 16503.4804(12) / 16503.0090(12)
4 / 16504.0516(32) / 16503.4700(4) / 16502.9931(2)
3 / 16504.0426(8) / 16503.4589(-15) / 16502.9792(-8)
5½ / 7 / 16504.0996(-5) / 16503.4218(-3) / 16502.8490(-5)
6 / 16503.4160(8) / 16502.8404(8)
5 / 16504.0912(14) / 16503.4087(12) / 16502.8292(5)
4 / 16504.0839(-2) / 16503.3992(-8) / 16502.8174(-12)
6½ / 8 / 16502.6662(-13)
7 / 16502.6604(10)
6 / 16502.6512(3)
5 / 16502.6413(-13)c
7½ / 9 / 16502.4717(-27)
8 / 16502.4669(-7)
7 / 16502.4597(-8)
6 / 16502.4510(-26)
8½ / 10 / 16502.2662(-38)
9 / 16502.2604(-38)
9½ / 11 / 16502.0500(-43)
9 / 16502.0407(-32)
8 / 16502.0344(-43)
10½ / 16501.8202(-7)
11½ / 16501.5783(-46)
14½ / 16503.9432(41)c
16½ / 16503.7798(26)
17½ / 16503.6803(14)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
e F = 0 for this transition. e F = 1 for this transition.
Table C.32: Measurements and assignments of individual lines in the (I) 23/2 – (000) 23/2 band of 65Cu35Cl2, bandhead: 16496.1031cm-1.
Assignment / Vacuum Wavenumbera /cm-1J" / F"b / R(J) / Q(J) / P(J)
1½ / 3 / 16495.8330(5) / 16495.5837(10)
16495.8089(35)e
2 / 16495.8151(15)c,e / 16495.6138(-27)f
1 / 16495.8151(-24)c,e / 16495.5402(-12)c
16495.5766(-23)f
0 / 16495.8223(-60)
2½ / 4 / 16495.9085(0) / 16495.5490(2) / 16495.2978(-12)
3 / 16495.5402(10)c / 16495.2579(9)
16495.3135(-30)e
2 / 16495.5261(-20) / 16495.2356(17)
16495.2723(10)e
3½ / 5 / 16495.9716(-2) / 16495.5056(2) / 16495.1495(38)
4 / 16495.4991(3) / 16495.1303(-3)
16495.1550(-27)e
3 / 16495.4924(10) / 16495.1151(-3)
2 / 16495.9619(-5) / 16495.4855(5) / 16495.1059(5)
4½ / 6 / 16496.0230(-1) / 16495.4495(-15) / 16494.9849(4)
5 / 16494.9768(17)
4 / 16496.0152(-23) / 16495.4415(12) / 16494.9667(12)
3 / 16495.4350(-2) / 16494.9585(7)
5½ / 7 / 16496.0612(-13) / 16495.3847(-5) / 16494.8134(2)
6 / 16494.8082(19)
5 / 16495.3768(2) / 16494.8007(14)
4 / 16495.3713(-10) / 16494.7939(7)
6½ / 8 / 16496.0894(-8) / 16494.6306(-1)
6 / 16494.6222(23)
5 / 16494.6167(18)
7½ / 9 / 16496.1031(0) / 16495.2166(17) / 16494.4379(9)
7 / 16494.4307(27)
8½ / 16496.1031(-44)
10½ / 16494.8754(-40)
11½ / 16494.7408(-32)
12½ / 16496.0082(8)
13½ / 16495.9535(6)
14½ / 16495.8893(26)
15½ / 16495.8089(2)
16½ / 16495.7178(-10)
a The numbers in parentheses are the residuals from the least-squares fit, in units of the last quoted decimal place. b The hyperfine transitions obey the selection rule F = J. c Weight =0.5 for this transition.
e F = 0 for this transition. f F = 1 for this transition.