Supplementary Materials

Contribution of Inorganic Constituents to Sorption of Neutral and Ionized Pharmaceuticals and Pyrene Derivatives by Sediment/Soil

Hiroshi Yamamoto, Kohei Takemoto, Ikumi Tamura, Norihiro Shin-oka, Takahiro Nakano, Masayo Nishida, Yuta Honda, Shigemi Moriguchi, and Yudai Nakamura

(a) Montmorillonite (b) Kaolin

Fig. S1 Atenolol sorption isotherms.

Fig. S2 Ifenprodil sorption isotherms (silica sand).

(a) Montmorillonite (b) Kaolin

(c)Silica Sand

Fig. S3 Propranolol sorption isotherm

(a) Montmorillonite (b) Kaolin

(c) Silica sand

Fig. S4 Acetaminophen sorption isotherms

(a) Montmorillonite (b) Kaolin

Fig. S5 Carbamazepine sorption isotherms

(a) Montmorillonite (b) Kaolin

Fig. S6 Ibuprofen sorption isotherms

(a) Montmorillonite (b) Kaolin

(c) Silica sand

Fig. S7 Indomethacin sorption isotherm

Fig. S8 Mefenamic acid sorption isotherm (silica sand)

(a) Montrillonite (b) Kaolin

(c) Silica sand (d) Dando humic acid (Stern-Volmer Plot)

Fig. S9 1-Aminopyrene Sorption Isotherms (and Stern-Volmer Plot)

(a) Montmorillonite (b) Kaolin

(c) Silica sand (d) Aldrich humic acid (Stern-Volmer Plot)

(e) Dando humic acid (Stern-Volmer Plot) (f) Akui River Sediment

Fig. S10 1-pyrene methylamine sorption isotherms (and Stern-Volmer Plot).

(g) Tamiya Creek Sediment (h) Tatara Creek Sediment

(i) Elliot Silt Loam Soil

Fig. S10 (Continued)

(a) Montmorillonite (b) Kaolin

(c) Silica sand (d) Dando humic acid (Stern-Volmer Plot)

Fig. S11 Pyrene sorption isotherms (and Stern-Volmer Plot).

(a) Montmorillonite (b) Kaolin

(c) Silica sand (d) Aldrich humic acid (and Stern-Volmer Plot)

(e) Dando humic acid (and Stern-Volmer Plot) (f) Akui River sediment

Fig. S12 1-methylpyrene sorption isotherms (and Stern-Volmer Plot).

(g) Tamiya Creek Sediment (h) Tatara Creek Sediment

(i) Elliot Silt Loam Soil

Fig. S12 (Continued)

(a) Montmorillonite (b) Kaolin

(c) Silica sand (d) Aldrich humic acid (Stern-Volmer Plot)

(e) Dando humic acid (and Stern-Volmer Plot) (f) Tamiya Creek Sediment

Fig. S13 1-pyrenemethanol sorption isotherms (and Stern-Volmer Plot).

(g) Tatara Creek Sediment (h)Elliot Silt Loam Soil

Fig. S13 (Continued)

(a)  Montmorillonite (b) Kaolin

(c) Silica sand (d) Dando humic acid (and Stern-Volmer Plot)

Fig. S14 1-pyrenecarboxylic acid sorption isotherms.

(a) Montmorillonite (b) Kaolin

(c) Silica sand (d) Aldrich humic acid (and Stern-Volmer Plot)

(e) Dando humic acid (and Stern-Volmer Plot) (f) Akui River Sediment

Fig. S15 1-pyreneacetic acid sorption isotherms (and Stern-Volmer Plot).

(g) Tamiya Creek Sediment (h)Tatara Creek Sediment

(i) Elliot Silt Loam Soil

Fig. S15 (Continued)

(a) Akui River Sediment (b) Tamiya Creek Sediment

(c) Tatara Creek Sediment (d) Elliot Silt Loam Soil

Fig. S16 Sorption kinetics for pyrene.