Publication ListDr. Nathan Patmore

1.“Transition metal complexes of the weakly coordinating carborane anion [CB11H12]-: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction.” N. J. Patmore, J. W. Steed, A. S. Weller,Chem. Commun., 2000, 1055.

2.“Synthesis and characterisation of {Mo(-L)(CO)3}+ (-L = C5H5 or C5Me5) fragments ligated with [CB11H12]- and derivatives. Isolation and structural characterisation of an intermediate in a silver salt metathesis reaction.” N. J. Patmore, M. F. Mahon, J. W. Steed, A. S. Weller,J. Chem. Soc., Dalton Trans., 2001, 277.

3.“Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(2-BH3)Ph2PCH2PPh2}][PF6] (COD = 1,2-cyclooctadiene).” M. J. Ingleson, N. J. Patmore, C. G. Frost, M. F. Mahon, M. C. Willis, A. S. Weller, Organometallics, 2001,20, 4434.

4.“[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.” C. Hague, N. J. Patmore, C. G.Frost, M. F. Mahon, A. S. Weller,Chem. Commun., 2001, 2286.

5.“Silver phosphines partnered with carborane mono anions: Synthesis, structures and use as a highly active Lewis-acid catalysts in hetero Diels-Alder reactions.” N. J. Patmore, C. Hague, J. H. Cotgreave, M. F. Mahon, C. G. Frost, A. S. Weller,Chem. Eur. J., 2002, 9, 2088.

6. “Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H,Br). Synthesis and evaluation as alkene hydrogenation catalysts.” A. Rifat, N. J. Patmore, M. F. Mahon, A. S. Weller, Organometallics, 2002, 21, 2856.

7. “Solution and Solid-State Structure of the Anion [Ag2{closo-CB11H12}4]2-.” M. A. Fox, M. F.Mahon, N. J. Patmore, A. S. Weller, Inorg. Chem., 2002, 41, 4567.

  1. “(PPh3)Ag(HCB11Me11): A complex with intermolecular Ag···H3C interactions.” M. J. Ingleson, M. F. Mahon, N. J. Patmore, G. D. Ruggiero, A. S. Weller, Angew. Chem. Int. Ed.,2002, 41, 3694.

9.“Bi- and Tri-metallic {Cp*RhCl} frgaments partnered with carborane monoanions [CB11H6Y6]- (Y = H, Br): Control of nuclearity by choice of anion.” N. J. Patmore, M. F. Mahon, A. S. Weller, App. Organomet. Chem., 2003, 17, 388 (Thomas Fehlner honour issue).

10.“Investigation of the synthesis of {Mo(5-C5H5)(CO)3}+ fragments partnered with the mono-anionic carboranes [closo-CB11H11Br]-, [closo-CB11H6Br6] and [closo-HCB11Me11]- by silver salt metathesis and hydride abstraction.” N. J. Patmore, M. J. Ingleson, M. F. Mahon, A. S.Weller,Dalton Trans.,2003, 2894.

11. “Silver phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.” M. J. Ingleson, N. J. Patmore, G. Kociok-Köhn, M. F. Mahon, G. D. Ruggiero, A. S. Weller, M. J.Clarke, J. P. Rourke, J. Am. Chem. Soc., 2004,126, 1503.

12.“3,6-Dioxypyridazine bridged tungsten tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds.”M. H. Chisholm, R. J. H. Clark, C. M. Hadad, N. J. Patmore, Chem. Commun.,2004, 80.

13.“Electronically-coupled tungsten-tungsten quadruple bonds. Comparisons of electron delocalization in 3,6-dioxypyridazine and oxalate-bridged compounds.”M. H. Chisholm, R. J. H. Clark, J. C. Gallucci, C. M. Hadad, N. J. Patmore, J. Am. Chem. Soc., 2004, 126, 8303.

14. “Thienyl carboxylate ligands bound to and bridging MM quadruple bonds, M = Mo or W: models for polythiophenes incorporating MM quadruple bonds.” M. J. Byrnes, M. H. Chisholm,R. J. H. Clark, J. C. Gallucci, C. M. Hadad,N. J. Patmore, Inorg. Chem.,2004,43, 6334.

15.“On the solvatochromic properties of the oxalate-bridged complexes [(tBuCO2)3M2]2(µ-O2C2O2) where M = Mo or W.” M. H. Chisholm, N. J. Patmore, Inorg. Chim. Acta, 2004, 357, 3877 (Tobin Marks honour issue).

16.“Concerning the relative importance of enantiomorphic site versus chain end control in the stereoselective polymerization of lactides: reactions of (R,R-salen)- and (S,S-salen)-aluminum alkoxides LAlOCH2R complexes (R = CH3 and S-CHMeCl)” M. H. Chisholm, N. J. Patmore, Z. Zhou,Chem. Commun., 2005, 127.

17. “The cations M2(O2CBut)4+, where M = Mo and W, and MoW(O2CBut)4+. Theoretical and spectroscopic investigations.” J. S. D’Acchioli, M. H. Chisholm, N. J. Patmore, B. D. Pate, N. S. Dalal, D. J. Zipse, Inorg. Chem., 2005, 44, 1061.

18. “Linkage isomerisation in oxalate bridged metal-metal quadruple bonds.” J. S. D’Acchioli, M. H. Chisholm, N. J. Patmore, Dalton Trans., 2005, 1852.

19.“Electronically-Coupled MM Quadruply-Bonded Complexes of Molybdenum and Tungsten.” M. H. Chisholm, N. J. Patmore, Chemical Record, 2005, 5, 308 (review article).

20.“Long Range Electronic Coupling of MM Quadruple Bonds (M = Mo or W) via a 2,6-Azulenedicarboxylate Bridge.” M. V. Barybin, M. H. Chisholm, N. S. Dalal, T. H. Holovics, N. J. Patmore, R. E. Robinson, D. J. Zipse, J. Am. Chem. Soc., 2005, 127, 15182.

21.“A New Metal-Organic Polygon Involving MM Quadruple Bonds: M8(O2CtBu)4(μ-SC4H2-3,4-{CO2}2)6 (M = Mo, W).” M. J. Byrnes, M. H. Chisholm, N. J. Patmore, Inorg. Chem., 2005, 44, 9347.

22.“Electronically Coupled MM Quadruply-Bonded Complexes (M = Mo or W) Employing Functionalized Terephthlalate Bridges: Towards Molecular Rheostats and Switches.” M. H. Chisholm, F. Feil, C. M. Hadad, N. J. Patmore, J. Am. Chem. Soc., 2005, 127, 18150.

23.“Electronic coupling in 1,4-(COS)2C6H4 linked MM quadruple bonds (M = Mo, W): the influence of S for O substitution.” M. H. Chisholm, N. J. Patmore, Dalton Trans., 2006, 3164.

24.“Concerning the Electronic Coupling of MoMo Quadruple Bonds Linked by 4,4' Azodibenzoate and Comparison With t2g6-Ru(II) Centers by 4,4' Azodiphenylamido Ligands.” M. H. Chisholm, J. S. D’Acchioli, C. M. Hadad, N. J. Patmore,Inorg. Chem., 2006, 45, 11035.

25.“2,5-Dianilinoterephthalate Bridged MM Quadruply Bonded Complexes of Molybdenum and Tungsten” M. H. Chisholm, N. J. Patmore, Dalton Trans., 2007, 91.

26. “Studies of Electronic Coupling and Mixed Valency in MM Quadruply Bonded Complexes Linked by Dicarboxylate and Closely Related Ligands.” M. H. Chisholm, N. J. Patmore, Acc. Chem. Res., 2007, 40, 19.

27.“Photophysical Properties of Metal Complexes.” N. J. Patmore*, Annu. Rep. Prog. Chem., Sect. A, 2007, 103, 518.

28.“Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands.” M. V. Barybin, M. H. Chisholm, N. J. Patmore, R. E. Robinson, N. Singh, Chem. Commun., 2007, 3652.

29.“Photophysical Properties of Metal Complexes.” N. J. Patmore*, Annu. Rep. Prog. Chem., Sect. A, 2008, 104, 498.

30.“Dimolybdenum Bis-2,4,6-triisopropylbenzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4'-Bipyridine with Ambivalent Properties.” M. H. Chisholm, A. S. Dann, F. Dielmann, J. C. Gallucci, N. J. Patmore*, R. Ramnauth, M. Scheer, Inorg. Chem., 2008, 47, 9248.

31.“Oxalate bridged heteronuclear compounds containing MM quadruple bonds (M = Mo and W) and their radical cations.” M. H. Chisholm, N. J. Patmore, Can. J. Chem., 2009, 87, 88.

32.“Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes.” R. Gracia, H. Adams, N. J. Patmore*, Dalton Trans., 2009, 259.