Physicochemical and Excess Properties of Binary Mixtures Of

Supplementary data

Physicochemical and excess properties of binary mixtures of (1-alkyl-3-methylimidazoliumchloride/bromide + ethylene glycol) at T = (288.15 to 333.15) K

aYun-Xia Zhang, a,bShu-Ni Li*, a,bQuan-Guo Zhai, a,bYu-Cheng Jiang, a,bMan-Cheng Hu[*]

aSchool of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi’an, Shaanxi, 710062, China

bKey Laboratory of Macromolecular Science of Shaanxi Province, Xi’an, Shaanxi, 710062, China

Received 22 May 2015; Revised 13 August 2015; Accepted 13 August 2015


Table S1 Parameters A, B, C, D of equation (1) and the root-mean-square deviations (σ) for the four binary mixtures {([C6mim]Br + EG), ([C8mim]Br + EG), ([C6mim]Cl + EG), ([C8mim]Cl + EG)}.

Function / T/K / A / B / C / D / 100σ
[C6mim]Br + EG
ρ / 288.15 / 1.1189 / 0.2817 / -0.2860 / 0.1165 / 0.1020
293.15 / 1.1154 / 0.2811 / -0.2843 / 0.1156 / 0.1030
298.15 / 1.1119 / 0.2807 / -0.2833 / 0.1151 / 0.1020
303.15 / 1.1083 / 0.2806 / -0.2827 / 0.1148 / 0.1020
308.15 / 1.1048 / 0.2807 / -0.2826 / 0.1148 / 0.1010
313.15 / 1.1012 / 0.2808 / -0.2823 / 0.1147 / 0.0997
318.15 / 1.0976 / 0.2811 / -0.2826 / 0.1148 / 0.0987
323.15 / 1.0940 / 0.2815 / -0.2824 / 0.1146 / 0.0972
328.15 / 1.0904 / 0.2820 / -0.2828 / 0.1147 / 0.0962
333.15 / 1.0868 / 0.2827 / -0.2832 / 0.1148 / 0.0959
nD / 288.15 / 1.4348 / 0.2479 / -0.2549 / 0.1072 / 0.1000
293.15 / 1.4334 / 0.2468 / -0.2526 / 0.1059 / 0.1010
298.15 / 1.4319 / 0.2462 / -0.2512 / 0.1049 / 0.0981
303.15 / 1.4304 / 0.2455 / -0.2497 / 0.1041 / 0.0987
308.15 / 1.4288 / 0.2466 / -0.2516 / 0.1050 / 0.0968
313.15 / 1.4273 / 0.2465 / -0.2509 / 0.1046 / 0.0971
318.15 / 1.4257 / 0.2467 / -0.2513 / 0.1049 / 0.0965
323.15 / 1.4242 / 0.2471 / -0.2515 / 0.1047 / 0.0963
328.15 / 1.4227 / 0.2474 / -0.2517 / 0.1047 / 0.1010
333.15 / 1.4213 / 0.2486 / -0.2542 / 0.1063 / 0.1100
lnη / 288.15 / 3.2962 / -0.2593 / 8.6491 / -3.0611 / 0.9360
293.15 / 3.0725 / -0.2031 / 8.4185 / -3.1799 / 0.8480
298.15 / 2.8510 / 0.1012 / 7.5718 / -2.8640 / 1.1700
303.15 / 2.6561 / 0.1730 / 7.2151 / -2.8131 / 1.0100
308.15 / 2.4652 / 0.3653 / 6.6328 / -2.6308 / 0.8960
313.15 / 2.2924 / 0.4718 / 6.2613 / -2.5661 / 0.8090
318.15 / 2.1278 / 0.6281 / 5.7485 / -2.3883 / 0.8270
323.15 / 1.9731 / 0.7577 / 5.3104 / -2.2438 / 0.8480
328.15 / 1.8262 / 0.8893 / 4.8858 / -2.1064 / 0.7190
333.15 / 1.6877 / 0.9808 / 4.5800 / -2.0410 / 0.7650
[C8mim]Br + EG
ρ / 288.15 / 1.1179 / 0.1374 / -0.1333 / 0.0524 / 0.0528
293.15 / 1.1144 / 0.1369 / -0.1316 / 0.0513 / 0.0525
298.15 / 1.1109 / 0.1364 / -0.1299 / 0.0503 / 0.0527
303.15 / 1.1074 / 0.1361 / -0.1287 / 0.0495 / 0.0521
308.15 / 1.1038 / 0.1361 / -0.1280 / 0.0491 / 0.0518
313.15 / 1.1003 / 0.1362 / -0.1276 / 0.0489 / 0.0508
318.15 / 1.0967 / 0.1365 / -0.1275 / 0.0488 / 0.0501
323.15 / 1.0931 / 0.1369 / -0.1275 / 0.0486 / 0.0491
328.15 / 1.0894 / 0.1375 / -0.1278 / 0.0486 / 0.0482
333.15 / 1.0858 / 0.1384 / -0.1286 / 0.0490 / 0.0474
nD / 288.15 / 1.4351 / 0.2453 / -0.2720 / 0.1183 / 0.1190
293.15 / 1.4337 / 0.2451 / -0.2728 / 0.1191 / 0.1170
298.15 / 1.4322 / 0.2444 / -0.2715 / 0.1183 / 0.1150
303.15 / 1.4308 / 0.2445 / -0.2717 / 0.1184 / 0.1150
308.15 / 1.4292 / 0.2445 / -0.2716 / 0.1182 / 0.1150
313.15 / 1.4276 / 0.2441 / -0.2707 / 0.1177 / 0.1140
318.15 / 1.4261 / 0.2443 / -0.2709 / 0.1178 / 0.1140
323.15 / 1.4245 / 0.2444 / -0.2705 / 0.1173 / 0.1120
328.15 / 1.4229 / 0.2453 / -0.2722 / 0.1184 / 0.1130
333.15 / 1.4213 / 0.2471 / -0.2757 / 0.1203 / 0.1140
lnη / 288.15 / 3.2887 / 1.0201 / 7.8227 / -2.4624 / 0.6763
293.15 / 3.0699 / 0.9615 / 7.7637 / -2.7035 / 0.7194
298.15 / 2.8596 / 0.9626 / 7.6044 / -2.8723 / 0.5716
303.15 / 2.6573 / 1.0966 / 7.1306 / -2.8051 / 0.6029
308.15 / 2.4748 / 1.1590 / 6.9038 / -2.9493 / 0.6580
313.15 / 2.3002 / 1.2704 / 6.4459 / -2.8437 / 0.4907
318.15 / 2.1381 / 1.3808 / 5.9149 / -2.6471 / 0.2971
323.15 / 1.9850 / 1.4572 / 5.4964 / -2.4563 / 0.4569
328.15 / 1.8367 / 1.5665 / 5.0856 / -2.3371 / 0.3700
333.15 / 1.6956 / 1.6668 / 4.6808 / -2.2001 / 0.3008
[C6mim]Cl + EG
ρ / 288.15 / 1.1142 / -0.2410 / 0.3223 / -0.1524 / 0.1210
293.15 / 1.1107 / -0.2401 / 0.3221 / -0.1526 / 0.1200
298.15 / 1.1072 / -0.2389 / 0.3212 / -0.1523 / 0.1190
303.15 / 1.1037 / -0.2378 / 0.3204 / -0.1521 / 0.1190
308.15 / 1.1002 / -0.2363 / 0.3191 / -0.1516 / 0.1180
313.15 / 1.0967 / -0.2348 / 0.3176 / -0.1510 / 0.1180
318.15 / 1.0931 / -0.2329 / 0.3155 / -0.1500 / 0.1180
323.15 / 1.0895 / -0.2311 / 0.3134 / -0.1491 / 0.1180
328.15 / 1.0859 / -0.2289 / 0.3107 / -0.1479 / 0.1180
333.15 / 1.0823 / -0.2267 / 0.3083 / -0.1468 / 0.1180
nD / 288.15 / 1.4329 / 0.2020 / -0.1965 / 0.0799 / 0.0563
293.15 / 1.4314 / 0.2015 / -0.1953 / 0.0791 / 0.0562
298.15 / 1.4300 / 0.2013 / -0.1948 / 0.0788 / 0.0561
303.15 / 1.4285 / 0.2012 / -0.1945 / 0.0786 / 0.0560
308.15 / 1.4270 / 0.2011 / -0.1943 / 0.0783 / 0.0555
313.15 / 1.4255 / 0.2010 / -0.1940 / 0.0782 / 0.0547
318.15 / 1.4240 / 0.2013 / -0.1943 / 0.0783 / 0.0543
323.15 / 1.4225 / 0.2012 / -0.1942 / 0.0781 / 0.0539
328.15 / 1.4211 / 0.2014 / -0.1942 / 0.0780 / 0.0522
333.15 / 1.4197 / 0.2010 / -0.1925 / 0.0768 / 0.0534
lnη / 288.15 / 3.3206 / -1.1029 / 12.7255 / -5.3653 / 4.7100
293.15 / 3.0964 / -0.9373 / 12.1026 / -5.2702 / 4.6700
298.15 / 2.8781 / -0.5477 / 10.5968 / -4.3946 / 3.5900
303.15 / 2.6764 / -0.3744 / 10.0115 / -4.2830 / 3.4700
308.15 / 2.4702 / 0.2581 / 7.7788 / -2.8296 / 1.1500
313.15 / 2.2943 / 0.4145 / 7.2469 / -2.7105 / 1.2500
318.15 / 2.1316 / 0.5767 / 6.7050 / -2.5693 / 1.2100
323.15 / 1.9778 / 0.7389 / 6.1712 / -2.4180 / 0.8710
328.15 / 1.8300 / 0.8788 / 5.6984 / -2.2838 / 0.8870
333.15 / 1.6866 / 0.9592 / 5.4121 / -2.2603 / 1.2500
[C8mim]Cl + EG
ρ / 288.15 / 1.1127 / -0.3461 / 0.4680 / -0.2212 / 0.1950
293.15 / 1.1092 / -0.3452 / 0.4677 / -0.2213 / 0.1940
298.15 / 1.1057 / -0.3441 / 0.4670 / -0.2211 / 0.1940
303.15 / 1.1022 / -0.3430 / 0.4664 / -0.2211 / 0.1930
308.15 / 1.0987 / -0.3417 / 0.4654 / -0.2208 / 0.1920
313.15 / 1.0951 / -0.3402 / 0.4640 / -0.2202 / 0.1910
318.15 / 1.0916 / -0.3385 / 0.4622 / -0.2194 / 0.1910
323.15 / 1.0880 / -0.3366 / 0.4601 / -0.2185 / 0.1900
328.15 / 1.0844 / -0.3345 / 0.4575 / -0.2173 / 0.1900
333.15 / 1.0808 / -0.3323 / 0.4549 / -0.2161 / 0.1900
nD / 288.15 / 1.4335 / 0.1993 / -0.2113 / 0.0893 / 0.0830
293.15 / 1.4320 / 0.1984 / -0.2095 / 0.0884 / 0.0811
298.15 / 1.4304 / 0.1984 / -0.2095 / 0.0884 / 0.0785
303.15 / 1.4289 / 0.1983 / -0.2095 / 0.0884 / 0.0781
308.15 / 1.4274 / 0.1982 / -0.2092 / 0.0883 / 0.0777
313.15 / 1.4260 / 0.1978 / -0.2086 / 0.0879 / 0.0770
318.15 / 1.4244 / 0.1979 / -0.2086 / 0.0878 / 0.0763
323.15 / 1.4230 / 0.1976 / -0.2082 / 0.0876 / 0.0763
328.15 / 1.4216 / 0.1976 / -0.2080 / 0.0873 / 0.0770
333.15 / 1.4202 / 0.1975 / -0.2077 / 0.0872 / 0.0789
lnη / 288.15 / 3.2894 / 1.4888 / 6.9275 / -1.8691 / 4.1864
293.15 / 3.0538 / 1.7917 / 5.5103 / -0.7943 / 3.2000
298.15 / 2.8604 / 1.3159 / 6.9946 / -2.4139 / 2.6251
303.15 / 2.6772 / 0.9057 / 7.8991 / -3.2664 / 1.6411
308.15 / 2.4901 / 1.0611 / 7.2385 / -3.0001 / 0.8445
313.15 / 2.3113 / 1.2108 / 6.6797 / -2.8344 / 1.0059
318.15 / 2.1445 / 1.4105 / 5.8514 / -2.4544 / 1.3019
323.15 / 1.9712 / 1.5666 / 5.4333 / -2.3552 / 1.1890
328.15 / 1.8205 / 1.7214 / 4.7727 / -2.0326 / 1.4283
333.15 / 1.6802 / 1.7954 / 4.4343 / -1.9443 / 1.4878

, where n is the number of experimental points.


Table S2 Parameters k0, 1000k1 of equation (2) and the corresponding root-mean-square deviations (σ) for the four binary mixtures {([C6mim]Br + EG), ([C8mim]Br + EG), ([C6mim]Cl + EG), ([C8mim]Cl + EG)}.

x1 / k0 / 1000k1 / 100σ
[C6mim]Br + EG
0.0000 / 1.3229 / -0.7146 / 0.0067
0.0490 / 1.3388 / -0.7149 / 0.0050
0.1010 / 1.3535 / -0.7198 / 0.0104
0.1487 / 1.3613 / -0.7123 / 0.0015
0.2006 / 1.3708 / -0.7126 / 0.0054
0.2984 / 1.3834 / -0.7057 / 0.0065
0.4023 / 1.3929 / -0.6962 / 0.0064
0.4869 / 1.3999 / -0.6918 / 0.0066
0.5888 / 1.4074 / -0.6888 / 0.0068
0.7039 / 1.4157 / -0.6903 / 0.0104
0.7631 / 1.4160 / -0.6805 / 0.0037
0.8755 / 1.4197 / -0.6745 / 0.0028
1.0000 / 1.4232 / -0.6695 / 0.0039
[C8mim]Br + EG
0.0000 / 1.3229 / -0.7146 / 0.0067
0.0508 / 1.3319 / -0.7171 / 0.0090
0.1021 / 1.3367 / -0.7125 / 0.0018
0.1501 / 1.3414 / -0.7119 / 0.0024
0.1998 / 1.3448 / -0.7084 / 0.0037
0.2917 / 1.3496 / -0.7013 / 0.0057
0.4001 / 1.3534 / -0.6913 / 0.0066
0.4982 / 1.3572 / -0.6870 / 0.0075
0.5947 / 1.3595 / -0.6805 / 0.0050
0.6934 / 1.3614 / -0.6754 / 0.0037
0.7884 / 1.3618 / -0.6677 / 0.0025
0.8960 / 1.3634 / -0.6643 / 0.0047
1.0000 / 1.3649 / -0.6630 / 0.0050
[C6mim]Cl + EG
0.0000 / 1.3229 / -0.7146 / 0.0067
0.0520 / 1.3017 / -0.6919 / 0.0026
0.0998 / 1.2890 / -0.6837 / 0.0056
0.1500 / 1.2777 / -0.6743 / 0.0082
0.2009 / 1.2680 / -0.6638 / 0.0097
0.2974 / 1.2522 / -0.6413 / 0.0052
0.3992 / 1.2439 / -0.6340 / 0.0156
0.4995 / 1.2341 / -0.6156 / 0.0067
0.5962 / 1.2284 / -0.6072 / 0.0049
0.6933 / 1.2268 / -0.6101 / 0.0169
0.7949 / 1.2208 / -0.5981 / 0.0113
0.8937 / 1.2174 / -0.5931 / 0.0127
1.0000 / 1.2150 / -0.5913 / 0.0165
[C8mim]Cl + EG
0.0000 / 1.3229 / -0.7146 / 0.0067
0.0491 / 1.3010 / -0.7102 / 0.0263
0.0989 / 1.2763 / -0.6798 / 0.0015
0.1499 / 1.2607 / -0.6680 / 0.0008
0.2013 / 1.2484 / -0.6582 / 0.0020
0.3021 / 1.2295 / -0.6387 / 0.0039
0.3855 / 1.2194 / -0.6287 / 0.0053
0.4961 / 1.2093 / -0.6174 / 0.0061
0.6141 / 1.2008 / -0.6064 / 0.0035
0.6935 / 1.1963 / -0.6004 / 0.0031
0.7872 / 1.1911 / -0.5924 / 0.0023
0.8731 / 1.1879 / -0.5892 / 0.0045
1.0000 / 1.1837 / -0.5846 / 0.0055

, where n is the number of experimental points.

Table S3. Isobaric expansivity αP for the four binary mixtures {([C6mim]Br + EG), ([C8mim]Br + EG), ([C6mim]Cl + EG), ([C8mim]Cl + EG)} at T = (288.15 to 333.15) K and atmospheric pressure (0.1 MPa).

x1 / 288.15 K / 293.15 K / 298.15 K / 303.15 K / 308.15 K / 313.15 K / 318.15 K / 323.15 K / 328.15 K / 333.15 K
104αP/K-1/{[C6mim]Br + EG}
0.0000 / 6.3975 / 6.4181 / 6.4387 / 6.4595 / 6.4804 / 6.5015 / 6.5227 / 6.5441 / 6.5655 / 6.5872
0.0490 / 6.3105 / 6.3305 / 6.3506 / 6.3708 / 6.3911 / 6.4116 / 6.4322 / 6.4530 / 6.4739 / 6.4949
0.1010 / 6.2808 / 6.3006 / 6.3205 / 6.3405 / 6.3607 / 6.3810 / 6.4014 / 6.4219 / 6.4426 / 6.4635
0.1487 / 6.1615 / 6.1805 / 6.1997 / 6.2190 / 6.2384 / 6.2579 / 6.2775 / 6.2973 / 6.3172 / 6.3372
0.2006 / 6.1148 / 6.1335 / 6.1524 / 6.1714 / 6.1905 / 6.2097 / 6.2291 / 6.2485 / 6.2681 / 6.2878
0.2984 / 5.9809 / 5.9989 / 6.0169 / 6.0351 / 6.0533 / 6.0717 / 6.0902 / 6.1088 / 6.1275 / 6.1463
0.4023 / 5.8395 / 5.8566 / 5.8738 / 5.8911 / 5.9085 / 5.9260 / 5.9436 / 5.9613 / 5.9792 / 5.9971
0.4869 / 5.7620 / 5.7786 / 5.7954 / 5.8122 / 5.8292 / 5.8462 / 5.8633 / 5.8806 / 5.8979 / 5.9154
0.5888 / 5.6972 / 5.7134 / 5.7298 / 5.7463 / 5.7628 / 5.7795 / 5.7962 / 5.8131 / 5.8300 / 5.8471
0.7039 / 5.6730 / 5.6891 / 5.7053 / 5.7217 / 5.7381 / 5.7546 / 5.7712 / 5.7879 / 5.8047 / 5.8216
0.7631 / 5.5783 / 5.5939 / 5.6095 / 5.6253 / 5.6412 / 5.6571 / 5.6732 / 5.6893 / 5.7056 / 5.7219
0.8755 / 5.5051 / 5.5203 / 5.5356 / 5.5510 / 5.5664 / 5.5820 / 5.5976 / 5.6133 / 5.6291 / 5.6450
1.0000 / 5.4422 / 5.4570 / 5.4720 / 5.4870 / 5.5021 / 5.5172 / 5.5325 / 5.5478 / 5.5633 / 5.5788
104αP/K-1/{[C8mim]Br + EG}
0.0000 / 6.3975 / 6.4181 / 6.4387 / 6.4595 / 6.4804 / 6.5015 / 6.5227 / 6.5441 / 6.5655 / 6.5872
0.0508 / 6.3732 / 6.3936 / 6.4141 / 6.4347 / 6.4555 / 6.4764 / 6.4974 / 6.5186 / 6.5399 / 6.5614
0.1021 / 6.2974 / 6.3172 / 6.3373 / 6.3574 / 6.3777 / 6.3981 / 6.4186 / 6.4393 / 6.4601 / 6.4810
0.1501 / 6.2648 / 6.2844 / 6.3043 / 6.3242 / 6.3442 / 6.3644 / 6.3848 / 6.4052 / 6.4258 / 6.4465
0.1998 / 6.2103 / 6.2297 / 6.2492 / 6.2687 / 6.2885 / 6.3083 / 6.3283 / 6.3483 / 6.3686 / 6.3889
0.2917 / 6.1112 / 6.1300 / 6.1488 / 6.1678 / 6.1869 / 6.2061 / 6.2254 / 6.2448 / 6.2644 / 6.2841
0.4001 / 5.9892 / 6.0072 / 6.0253 / 6.0435 / 6.0619 / 6.0803 / 6.0988 / 6.1175 / 6.1362 / 6.1551
0.4982 / 5.9257 / 5.9434 / 5.9611 / 5.9789 / 5.9968 / 6.0148 / 6.0330 / 6.0512 / 6.0696 / 6.0881
0.5947 / 5.8498 / 5.8670 / 5.8842 / 5.9016 / 5.9191 / 5.9366 / 5.9543 / 5.9721 / 5.9900 / 6.0080
0.6934 / 5.7888 / 5.8056 / 5.8225 / 5.8395 / 5.8566 / 5.8738 / 5.8911 / 5.9085 / 5.9260 / 5.9436
0.7884 / 5.7100 / 5.7264 / 5.7428 / 5.7594 / 5.7760 / 5.7927 / 5.8096 / 5.8265 / 5.8435 / 5.8606
0.8960 / 5.6682 / 5.6843 / 5.7005 / 5.7168 / 5.7332 / 5.7497 / 5.7663 / 5.7830 / 5.7997 / 5.8166
1.0000 / 5.6475 / 5.6635 / 5.6796 / 5.6958 / 5.7121 / 5.7284 / 5.7449 / 5.7614 / 5.7781 / 5.7948
104αP/K-1/{[C6mim]Cl + EG}
0.0000 / 6.3975 / 6.4181 / 6.4387 / 6.4595 / 6.4804 / 6.5015 / 6.5227 / 6.5441 / 6.5655 / 6.5872
0.0520 / 6.2773 / 6.2970 / 6.3169 / 6.3369 / 6.3571 / 6.3773 / 6.3977 / 6.4183 / 6.4389 / 6.4597
0.0998 / 6.2604 / 6.2801 / 6.2999 / 6.3198 / 6.3398 / 6.3600 / 6.3803 / 6.4007 / 6.4212 / 6.4419
0.1500 / 6.2242 / 6.2437 / 6.2632 / 6.2829 / 6.3027 / 6.3226 / 6.3427 / 6.3629 / 6.3832 / 6.4036
0.2009 / 6.1647 / 6.1837 / 6.2029 / 6.2222 / 6.2416 / 6.2612 / 6.2808 / 6.3006 / 6.3205 / 6.3406