Name: ______Period: ______Date: ______

Notes Chapter 4: The Structure of the Atom

4.1 Early Theories of Matter

A. The Philosophers - believed matter was made of earth, water, air, and fire.

1.Democritus (460-370 BC) was the first to propose that matter was made up of tiny ______he called atomos, which could not be further ______.

a. Without being able to experiment, he could not ______his ideas, and they were ______.

B. John Dalton (1766-1844) – began the development of the modern ______theory.

1. Dalton’s Atomic Theory- 1803

a. All matter is made up of ______.

b. Atoms of ______element are______and are different from those of other elements.

c. Atoms cannot be ______, divided, or ______.

d. Different atoms ______in certain ratios to form ______.

e. In chemical reactions atoms are ______, combined, or ______.

2. Dalton was able to perform ______, observe many ______reactions, and determine the mass ______of elements to verify his theories.

C. Defining the Atom

1. Atom- the smallest particle of an ______that retains the ______of the element.

2. How big is an atom? consider this:

world population in 2000: 6,000,000,000

# of atoms in a single copper penny:

29,000,000,000,000,000,000,000 or ______x ______

3. Nanotechnology – molecular manufacturing which is the atom-by-atom building of ______the size of ______.

4.2 Subatomic Particles and the Nuclear Atom subatomic particles make up ______.

  1. Discovering the Electron

1. Cathode Ray Tube - Glass ______tube from which ______was removed.a. metal electrodes at each end -______is the negative end, anode is the ______end

2.Cathode Ray- a ray of ______that originates from the cathode and travels to the ______of a cathode ray tube

a. led to the invention of ______and computer monitor images – formed as radiation from the cathode strikes ______-producing chemicals that coat the backside of the ______.

3. By end of the 1800s scientists concluded that

a. No matter what the ______was in the tube or what the electrodes were ______of, the cathode ray was ______which meant that these ______particles were in ______matter.

b. since the particles were attracted to the positive anode, theymust be ______.

c. The ray deflected toward a ______which means it was made of ______ and not just a stream of light.

4. Electrons – ______charged particles.

5. J.J. Thomson(1856-1940) – discovered the first subatomic particle, the ______by determining the mass-to-charge ratio of the particle.

a. Determined that the ______of the charged particle was ______than that of smallest element, ______.

b.Meant that atoms were made of ______particles, disproving part of Dalton’s theory.

c. ______Plum-pudding / Chocolate-chip cookie dough modelof the atom – proposed that negatively charged ______(chips) were distributed through a “dough” of ______charge.

7. Robert Millikan (1868-1953) – 1909 determined that an electron has a ______charge. - 1 (e-)

B. The Nuclear Atom

1. Ernest Rutherford (1871-1937) – discovered existence of ______.

a. used a gold foil experiment to see if positive alpha particles would be ______by the ______in the atom.

b. Since the ______charge was thought to be ______out, he thought it would not alter the path of the alpha particles.

c. Amazingly some were deflected at ______angles which meant there must be a concentrated ______area.

2. Nuclear Model – An atom was mostly ______space through which the electrons move with a tiny ______region called the ______in the center.

3.Nucleus- dense region in ______of atom which is positively charged and contains virtually all of its ______.

4. Neils Bohr (1885 – 1962 ) Electrons ______the nucleus.

a. orbits have a set ______and energy.

b. Lowest energy is the ______orbit.

c. n = ______number or energy level.

d. Radiation (energy) is ______or absorbed when an ______moves from one orbit to another.

e. We see the emitted ______as light or photons.

f. the photons travel at different ______which we see as different ______

5. BUT there was still more ______than could be explained by the protons.

C. Completing the Atom- The Discovery of Protons and Neutrons

1. Rutherford refined the concept of the nucleus to include ______and ______.

2.Proton-subatomic particle carrying a ______charge +1 (p+)

3.James Chadwick (1932) – showed that the nucleaus also contained another subatomic particle.

4. Neutron-has a mass nearly ______to a proton, but carries ______charge (neutral) (n0)

4. Atoms are electrically ______meaning
the number of______= the number of ______.

4.3 How Atoms Differ

~ EachElement is made of ______type of atom. There are 92 natural elements, so there are 92 different kinds of ______.

~ The atoms ______in the number of electrons, protons, and neutrons.

A.Atomic Number- thenumber of ______in an atom.

1. The periodic table is organized left to right and top to bottom by ______atomic number

2.Atoms are neutral and that the number of protons = the number of electrons. So the atomic number will give you the number of ______AND______!!

Atomic number = # protons = # electrons

B. Isotopes and Mass Number

1.While the number of protons must ______the number of electrons, the number of ______may differ.

2.Isotope- atoms with ______number of protons but different numbers of ______.

EX: Potassium (K) has 3 isotopes. All three have ______protons and electrons, but one has ______neutrons, one has _____ neutrons, and one has ______neutrons.

3.Mass Number– is the sum of the number of ______and ______in the nucleus.

Mass Number = # protons + # neutrons

Mass Number – # protons = #neutrons

4.Isotope Identification - the______number is added after an element’s ______to identify the isotope.

EX: Neon-22, Chlorine-35, Uranium-238

5.Symbolic Notation -Shortened type of notation for an element using the chemical ______, atomic number, and the ______number.

The 3 naturally occurring potassium isotopes

Isotopes  / Potassium-39 / Potassium-40 / Potassium-41
Protons / 19 / 19
Electrons / 19 / 19
Neutrons / 39-19 = 20 / 40-19 = 21 / 41-19 = ______
Symbolic notation / K-41

C. Mass of Individual Atoms

1.Atoms have extremely ______masses which are hard to work with, so scientists use a ______for comparison

2.Standard used is a ______atom

3.Carbon-12 atom has mass of ______atomic mass units

4.atomic mass unit– one (amu) is nearly ______to the mass of 1 proton or 1 neutron.

5.Atomic mass- is the ______average atomic mass of ALL the ______of that element.

D. Calculating Atomic Mass

1. Isotopes of elements exist in nature in ______amounts.

2. Atomic Mass = % ______x atomic mass for each isotope

Then ______all the atomic masses to get the weighted average atomic mass

Ex: Chlorine:

Isotopes

Chlorine-35 exists at 75% so 35 x.75 = ______amu

Chlorine-37 exists at 25% so 37 x .25= ______amu

Weighted Atomic mass is 26.4 + 8.9 = ______amu