/ SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email :
Visit us : /
1. / IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1.1 / Identification of the substance
  • EC#
/ 228-250-8
  • CAS#
/ 6197-30-4
  • NIOSH, Registry of Toxic Effects (RTECS) Identification Number
/ Not Available
  • Substance Name
/ Octocrylene
  • Synonym:
/ 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate
2-ethylhexyl 2-cyano-3,3-diphenyl-2-propenoate
2-Ethylhexyl D19202-cyano-3,3-diphenylacrylate
2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester
  • Chemical Formula
/ C24H27NO2
  • Structural Formula
/
  • SMILES
/ CCCCC(CC)COC(=O)C(=C(c1ccccc1)c2ccccc2)C#N
1.2 / Use of the substance/mixture
  • It is used as ultraviolet absorber inplastics, paints anddyes.
  • It can penetrate into the skin where it acts as a photosensitizer.
  • Used as an ingredient in sunscreens and cosmetics that is protecting the skin from direct DNA damage

1.3 / Company/undertaking identification
  • The person responsible for placing the substance on the market within the Community.
/

  • Full address
/ Salicylates and chemical Pvt ltd
A-25 road no.18 I.D.A Nacharam
Hyderabad -500076
  • Telephone No.
/ 0091 40271715550,27174691
1.4 / Emergency telephone
  • Emergency telephone number of the company and/or relevant official advisory body
/ 0091 40271715550,27174691
2. / HAZARDS IDENTIFICATION
Classification according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
  • Hazard Class and Category Code(s)
/ Skin Irrit. 2
Eye Irrit. 2
  • Hazard statement Code(s)
/ H316
H320
Most important adverse physicochemical, human health and environmental effects and symptoms relating to the uses and possible misuses of the mixture that can reasonably be forseen
None Found
3. / COMPOSITION/INFORMATION ON INGREDIENTS
Substance Name / CAS# / EC# / Percentage by weight / Risk phrases / Hazard Class and Category Code(s) / Hazard statement Code(s) / Pictogram, Signal Word Code(s)
Octocrilene / 6197-30-4 / 228-250-8 / 100% / R38
R36 / Eye Irrit. 2
Skin Irrit.2 / H316
H320 /
Wng
4. / FIRST AID MEASURES
Subdivision of information according to route of exposure
  • Eye contact
/ In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
  • Skin Contact
/ In case of contact, immediately wash skin with soap and copious amounts of water.
  • Inhalation
/ If inhaled, remove to fresh air. If breathing is difficult,
give oxygen. If not breathing, give artificial respiration. Get medical
attention.
  • Ingestion
/ Do not ingest. If this material is swallowed, call a physician
Immediately. Drink plenty of water; induce vomiting if conscious
and as directed by a physician. Loosen tight clothing such as collar,
tie, belt or waistband. Never give anything by mouth to an unconscious
person.
5. / FIRE-FIGHTING MEASURES
Suitable extinguishing media
  • Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Extinguishing media which shall not be used for safety reasons
  • Carbon oxides (CO, CO2), nitrogen oxides(NO, NO2, etc.)

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
As in any fire, wear a self-contained breathing apparatus in pressure demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Other information
  • Flammability of the Product
/ This product may be combustible at high temperature. This product
is slightly flammable in the presence of open flames, sparks and
Static discharge.
  • Auto-Ignition Temperature
/ Not Applicable
  • Flash Points
/ >1190C closed cup method
  • Flammable Limits
/ Not Available
  • Products of Combustion
/ Carbon oxides (CO, CO2), nitrogen oxides
(NO, NO2, etc.)
  • Fire Hazards in Presence of Various Substances
/ NA
  • Special Remarks on Fire Hazards
/ NA
6. / ACCIDENTAL RELEASE MEASURES
Personal Precautions:
  • Isolate spill area immediately.

  • Keep unauthorized personnel away.

  • Ventilate closed spaces before entering.

Methods for cleaning up:
Small Spill and Leak: Use a tool to scoop up solid or absorbed material and place into appropriate labeled waste container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional regulatory requirements.
Large Spill and Leak: Use appropriate tools to put the spilled material into a labeled waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional regulatory requirements.
7. / HANDLING AND STORAGE
7.1 / Handling
  • Avoid breathing vapors, spray or mists

  • Keepcontainer closed.

  • Use with adequate ventilation

  • Wear suitable protective clothing.

  • Avoid contact with eyes. Wash thoroughly after handling.

7.2 / Storage
  • Keep container tightly closed.

  • Keep container in a cool, well-ventilated area.

  • Do not store at high temperatures

8. / EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. / Exposure controls
8.2.1. / Occupational Exposure controls
  • Engineering Controls
/ Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure toairborne contaminants below the exposure limit.
(a) / Respiratory protection
  • Be sure to use NIOSH/ OSHA-approved respirator

  • government-approved respirator.

(b) / Hand protection
  • Be sure to use an approved/certified or equivalent Gloves

(c) / Eye protection
  • Safety glasses, goggles, or face shield recommended.

  • Splash goggles in case of large spill

(d) / Skin protection
  • Wear Lab coat

  • Full suit in case of large spill

  • Boots in case of large spills

9. / PHYSICAL AND CHEMICAL PROPERTIES
9.1 / General Information
  • Physical state
/ liquid
  • Color
/ Yellow
  • Odor
/ Mild, characteristic
9.2 / Important health, safety and environmental information
  • pH(1% soln/water)
/ NA
  • Molecular Weight
/ 361.4767
  • Boiling point/boiling range
/ 2000 C
  • Melting point
/ NA
  • Specific Gravity
/ Between 1.045 to 1.055
  • Flash point

  • Flammability (solid, gas)
/ Non Flammable
  • Auto ignition point
/ Not Applicable
  • Vapour pressure
/ NA
  • Dispersionproperty
/ NA
  • Solubility
/ NA
  • Water solubility:
/ Insoluble
  • Refractive index
/ 1.561 to 1.571
10. / STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and Handling
10.1. / Conditions to avoid:
  • Strong heating.

10.2. / Materials to avoid:
  • None hazardous decomposition products

10.3. / Hazardous decomposition products:
  • Hazardous Decomposition Products: Nitrogen oxides, (NO, NO2)

  • Polymerisation will not occur.

11. / TOXICOLOGICAL INFORMATION
Acute effects (acute toxicity, irritation and corrosivity)
  • May cause mild eye irritation

  • May cause mild skin irritation

Sensitization
  • No sensitizing effects on human.

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
  • Mutagenic Effects
/ Not Mutagenic
Test System::MOUSE LYMPHOMA
Strain Indicator: L5178Y (TK+/TK-)
Metabolic Activation:NONE
Method: SUSPENSION/PLATE
Dose: 0.028-0.38 UG/ML (TEST MATERIAL SOLVENT: DMSO)
Results: NEGATIVE
  • Reproductive toxicity Effects
/ No Repro-toxic
Component NameValue
Dose Range0.0067-0.089 UG/ML (TEST MATERIAL SOLVENT: DMSO)
Metabolic ActivationRAT, LIVER, S-9, AROCLOR 1254
MethodSUSPENSION/PLATE
Reference[ODIO,MR, AZRI-MEEHAN,S, ROBISON,SH AND KRAUS,AL; EVALUATION OF SUBCHRONIC (13 WEEK), REPRODUCTIVE, AND IN VITRO GENETIC TOXICITY POTENTIAL OF 2-ETHYLHEXYL-2-CYANO-3,3-DIPHENYL ACRYLATE (OCTOCRYLENE); FUNDAM. APPL. TOXICOL. 22(3):355-368, 1994]
ResultsNEGATIVE
Strain/IndicatorL5178Y (TK+/TK-)
Test SystemMOUSE LYMPHOMA
Other Toxic Effects on Humans:
  • Eyes:
/ May cause irritation
  • NIOSH Immediately Dangerous To Life or Health Concentration (IDLH):500 mg/m3

  • Acute Oral Toxicity, rat: LD50 = >67000mg/kg

12. / ECOLOGICAL INFORMATION
12.1 / Ecotoxicity
  • Inherently Toxic to Aquatic OrganismsNo
  • Meets CEPA Categorization CriteriaNo
  • Meets Environmental Criteria for CategorizationNo
  • Meets Human Health CriteriaNo
  • PersistentNo
  • Fish toxicity: LC50 :>10000mg/1/0.5h
  • Bacterial toxicity: EC50: >100mg/1/48h

12.2 / Persistence and degradability
Biodegradation:<20% MITI test Slightly biodegradable
12.3 / Bioaccumulative potential
  • Bioaccumulative: Yes

  • Bioaccumulation potential is to be (log p(o/w)>3

13. / DISPOSAL CONSIDERATIONS
Waste Disposal
Appropriate method of disposal of substance or preparation dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations
14. / TRANSPORT INFORMATION
Not Regulated
15. / REGULATORY INFORMATION
Classification and Labelling according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
  • U.S. Federal Regulations:
  • TSCA 8(a) Pair octocrylene (2-ethylhexyl-2-cyano-3, 3-diphenyl-2-propenoate
  • TSCA 8(b) inventory: Octocrylene (2-ethylhexyl-2-cyana-3, 3-diphenyl-2-propenoate

Label elements / Acute / Chronic
GHS Pictogram /
Signal Word / Warning
Hazard Statement / H316
H320
Precautionary Statement prevention / P262: Do not get in eyes, on skin, or on clothing
P270: Do not eat, drink or smoke when using this product
Precautionary Statement Response / P350: Gently wash with soap and water
Precautionary Statement Storage / P403: Store in a well ventilated place
P404: Store in a closed container
Other regulatory information
  • HMIS(Hazardous Materials Identification System) Classification

1 = Temporary or minor injury may occur
0= Minimal Hazard = Materials that will not burn
0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water, polymerise, decompose, condense or self react
E =
  • NFPA (National Fire Protection Association)

1 = Health Hazard = Exposure could causeirritationbut only minor residual injury even if no treatment is given.
0 = Flammability = Materials that will not burn.
0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.
16. / OTHER INFORMATION
Technical Advice
  • Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the factory

  • Create a Register for Workplace Chemicals;

  • Set priorities concerning the safety in the organization

  • Create emergency plans for the assessed hazards;

  • Organize occupational health care and regular surveys as necessary;

  • Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards, and to reliably measure and/or estimate occupational exposures to chemicals when needed;

  • Start collecting case studies of accidents and sickness records in the enterprise to create a basis for priority measures in the control of hazards;

  • Involve workers in safety organizations, such as the system of Safety Representatives and Committees.

  • Do regular inspection using checklists made for the particular chemicals and chemical processes in use;

  • Mark and label all chemicals;

  • Keep at hand an inventory list of all chemicals handled in the place of work together with a collection of Chemical Safety Data Sheets for these chemicals;

  • Train workers to read and understand the Chemical Safety Information, including the health hazards and routes of exposure; train them to handle dangerous chemicals and processes with respect;

  • Plan, develop and choose the safe working procedures;

  • Reduce the number of people coming into contact with dangerous chemicals;

  • Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals;

  • Train workers to know and understand the emergency procedures;

  • Equip and train workers to use personal protective equipment properly after everything possible has been done to eliminate hazards by means of other methods;

List of relevant R phrases
  • R 38/36

Created by

ELC Group

Momaja s.r.o

Krakovska9, Prague1, 11000, CzechRepublic

Tel.+420224910000

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall SALICYLATES & CHEMICALS PVT. LTD be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages.