Supporting Information

Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE

Bingjun Li1, Yibo Zhao1, Guoliang Liu1, Xiaomeng Li1, Yunjun Luo1

1School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China.

Contents

Fig. S1 The TG curves of PBAMO/GAP-10 with different heating rates

Fig. S2 The DTG curves of PBAMO/GAP-10 with different heating rates

Fig. S3 The TG curves of PBAMO/GAP-20 with different heating rates

Fig. S4 The DTG curves of PBAMO/GAP-20 with different heating rates

Fig. S5 The TG curves of PBAMO/GAP-30 with different heating rates

Fig. S6 The DTG curves of PBAMO/GAP-30 with different heating rates

Fig. S7 The TG curves of PBAMO/GAP-40 with different heating rates

Fig. S8 The DTG curves of PBAMO/GAP-40 with different heating rates

Table S1 Calculated values of the kinetic parameters of PBAMO/GAP-10

Table S2 Calculated values of the kinetic parameters of PBAMO/GAP-20

Table S3 Calculated values of the kinetic parameters of PBAMO/GAP-30

Table S4 Calculated values of the kinetic parameters of PBAMO/GAP-40

Fig. S1 The TG curves of PBAMO/GAP-10 with different heating rates

Fig. S2 The DTG curves of PBAMO/GAP-10 with different heating rates

Table S1 Calculated values of the kinetic parameters of PBAMO/GAP-10

β/℃ min-1 / Tp/℃ / Eo /kJ mol-1 / ro / Ek /kJ mol-1 / rk / lg(Ak/s-1)
First stage / 5 / 242.31 / 158.38 / 0.995 / 157.83 / 0.994 / 15.57
10 / 250.41
15 / 255.95
20 / 261.61
Second stage / 5 / 377.10 / 441.00 / 0.990 / 452.86 / 0.989 / 36.21
10 / 381.91
15 / 384.30
20 / 388.05

Fig. S3 The TG curves of PBAMO/GAP-20 with different heating rates

Fig. S4 The DTG curves of PBAMO/GAP-20 with different heating rates

Table S2 Calculated values of the kinetic parameters of PBAMO/GAP-20

β/℃ min-1 / Tp/℃ / Eo /kJ mol-1 / ro / Ek /kJ mol-1 / rk / lg(Ak/s-1)
First stage / 5 / 242.96 / 164.99 / 0.999 / 164.78 / 0.999 / 16.09
10 / 252.18
15 / 257.35
20 / 261.33
Second stage / 5 / 377.55 / 378.87 / 0.991 / 387.50 / 0.990 / 30.87
10 / 383.32
15 / 386.09
20 / 390.36

Fig. S5 The TG curves of PBAMO/GAP-30 with different heating rates

Fig. S6 The DTG curves of PBAMO/GAP-30 with different heating rates

Table S3 Calculated values of the kinetic parameters of PBAMO/GAP-30

β/℃ min-1 / Tp/℃ / Eo /kJ mol-1 / ro / Ek /kJ mol-1 / rk / lg(Ak/s-1)
First stage / 5 / 244.41 / 170.98 / 0.997 / 171.05 / 0.997 / 16.84
10 / 253.70
15 / 257.73
20 / 262.50
Second stage / 5 / 376.91 / 353.37 / 0.987 / 360.69 / 0.986 / 28.73
10 / 381.99
15 / 385.88
20 / 390.38

Fig. S7 The TG curves of PBAMO/GAP-40 with different heating rates

Fig. S8 The DTG curves of PBAMO/GAP-40 with different heating rates

Table S4 Calculated values of the kinetic parameters of PBAMO/GAP-40

β/℃ min-1 / Tp/℃ / Eo /kJ mol-1 / ro / Ek /kJ mol-1 / rk / lg(Ak/s-1)
First stage / 5 / 246.12 / 181.48 / 0.996 / 182.08 / 0.995 / 17.93
10 / 254.99
15 / 258.46
20 / 263.32
Second stage / 5 / 376.31 / 335.95 / 0.995 / 342.35 / 0.995 / 27.23
10 / 383.26
15 / 386.40
20 / 390.72

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