Hydrothermal Synthesis, Crystal Structure and Magnetic Property of Two Organic Amine Templated

Hydrothermal synthesis, crystal structure and magnetic property of two organic amine templated lanthanide sulfate

Lei Zheng,1Jie Fu,1Yan Yuan1,You Song2and Yan Xu[1],3

TableS1 HydrogenBonds of compound 1. (R=0.05)

D—H•••A / D—H(Å) / H•••A(Å) / D•••A(Å) / D—H•••A(°)
N1---H1C…O2 / 0.9100 / 2.4300 / 3.117(7) / 133.00
N1---H1C…O8 / 0.9100 / 2.2300 / 2.953(7) / 136.00
N1---H1C…O7 / 0.9100 / 2.3700 / 3.009(6) / 127.00
O1W---H1WB…O5W / 0.856(17) / 1.90(3) / 2.691(8) / 152(3)
N2---H2C…O10 / 0.9100 / 1.7900 / 2.658(7) / 159.00
O2W---H2WA…O9 / 0.855(13) / 1.87(2) / 2.674(9) / 156(4)
O2W---H2WB…O4W / 0.860(18) / 2.08(3) / 2.734(9) / 133(3)
O2W---H2WB…O4W / 0.860(18) / 1.94(2) / 2.744(8) / 155.7(16)
O3WA---H3WB…O3 / 0.867(15) / 2.33(2) / 2.732(11) / 108.5(14)
O3WA---H3WB…O5W / 0.867(15) / 2.328(17) / 2.660(11) / 102.9(15)
O3WA---H3WA…O4W / 0.920(18) / 1.966(16) / 2.762(14) / 143.6(16)
O4W---H4WA…O2W / 0.850(18) / 1.97(5) / 2.734(9) / 149(9)
O4W---H4WB…O5W / 0.852(14) / 2.13(2) / 2.868(9) / 145(4)
O5W---H5WA…O1W / 0.854(19) / 2.02(2) / 2.691(8) / 135(2)
O5W---H5WA…O4W / 0.854(19) / 2.53(3) / 2.868(9) / 104.9(19)
O5W---H5WB…O3WA / 0.85(2) / 1.82(3) / 2.660(11) / 166(3)
O5W---H5WB…O3W / 0.85(2) / 2.04(2) / 2.844(10) / 158(3)
C1---H1A…O6 / 0.9700 / 2.4800 / 3.419(7) / 161.00
C1---H1B…O7 / 0.9700 / 2.3800 / 3.176(7) / 139.00
C1---H1B…O4 / 0.9700 / 2.5200 / 3.233(7) / 130.00
C2---H2A…O5 / 0.9700 / 2.5400 / 3.305(7) / 136.00
C3---H3A…O1 / 0.9700 / 2.5900 / 3.512(6) / 159.00
C4---H4A…O1W / 0.9700 / 2.5200 / 3.481(7) / 171.00
C4---H4B…O8 / 0.9700 / 2.5900 / 3.078(7) / 111.00
C5---H5A…O5 / 0.9700 / 2.3400 / 3.279(8) / 162.00
C6---H6B…O3 / 0.9700 / 2.4400 / 3.376(7) / 161.00

TableS2 HydrogenBonds of compound 2. (R=0.06)

D—H•••A / D—H(Å) / H•••A(Å) / D•••A(Å) / D—H•••A(°)
N1---H1C…O2 / 0.9100 / 2.4200 / 3.108(7) / 132.00
N1---H1C…O8 / 0.9100 / 2.2400 / 2.960(7) / 135.00
N1---H1C…O7 / 0.9100 / 2.3700 / 3.009(6) / 128.00
N2---H2C…O10 / 0.9100 / 1.8000 / 2.677(7) / 160.00
C1---H1A…O6 / 0.9700 / 2.4900 / 3.418(7) / 161.00
C1---H1B…O7 / 0.9700 / 2.3700 / 3.163(7) / 139.00
C1---H1B…O4 / 0.9700 / 2.5000 / 3.208(7) / 130.00
C2---H2B…O5 / 0.9700 / 2.5300 / 3.299(7) / 137.00
C3---H3A…O1 / 0.9700 / 2.5700 / 3.502(6) / 160.00
C4---H4A…O8 / 0.9700 / 2.5900 / 3.054(7) / 109.00
C4---H4B…O1W / 0.9700 / 2.5300 / 3.491(7) / 173.00
C5---H5A…O5 / 0.9700 / 2.3600 / 3.295(7) / 162.00
C6---H6B…O3 / 0.9700 / 2.4600 / 3.385(7) / 160.00

Fig. S1 The IR of compounds 1 and 2.

1 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, PR China

2 Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China

3 To whom correspondence should be addressed. E-mail: . Tel: 86-25-83587857; Fax: 86-25-83211563