Supplementary Material

Figure S1: Alignment of the pfam family PF02458 proteins from rice, Brachpodium and Arabidopsis. Highlighted in color is the HXXXD motif, which is proposed to be the active site for transferase activity. The different colors for this motif are relative to the grouping of proteins into clades (I–V) by Piston et al. (2010).

* 20 * 40 * 60 * 80 * 100

Bradi2g04990.1 M------AAAKK-----SVSRLAQRLVLPAE--PTPSGP------LRLSWLDRYPTQMALIESLHVFKPAPARHAD---AC-- 59

Bradi2g04980.1 M------AAANK-----SVSRLPQRLVLPAE--PTPAGP------LRLSWLDRYPTQMALIESLHVFKPAPAHDG------56

Os01g08380.1 M------AAAK-----SVERLGQRRVVPAE--PTPAGP------LRLSWLDRYPTQMALIESLHVFKPALDRAIGGDDVA-- 61

Os05g08640.1 M------AAAAPDK-----AVERLSQKLVHPSS--PTPSAP------LRLSWLDRYPTQMALIESLHVFKPDPARDAAG--QG-- 62

Bradi2g33980.1 M------AAAAAAKP---VPVERLAQRLVAPAG--PTPEGP------LRLSWLDRYPTQMALIESLHVFKPDMAREGD------61

Os06g39470.1 M------RGSAAAAA---ATVTRVAQRVVAPSA--ATPGGA------LPLSWLDRYPTQRALIESLHVFKGRADAAVA------61

Bradi1g36980.1 M------RSAGAVAA---ATVTRVAQRVVAPSA--PTPGGE------LPLSWLDRYPTQRALIESLHVFKGRAGATEG------61

Os06g39390.1 M------GV---FAVTKVSEGPVRPSA--ATPSET------LPLAWVDRYPTHRGLVESVHIYLRRDDAAVEAPCADGG 62

Os01g09010.1 M------AGTGS---FKVTRISEGAVKPAA--ATPEET------LPLAWVDRYPTHRGLVESMHIFRSGADAAPG------58

Bradi2g05480.1 M------ASPSS---FKVTRISEGPVKPASP-DTPGHT------LPLAWVDRYPTHRGLVESMHIFRSGADAAPG------59

Os05g19910.1 M------VA---VTVMRKSRNFVGPSPPTPPAEIT---T----TLELSSIDRVPGLRHNVRSLHVFRRHKNSGPVVDGDS-- 64

Os01g18744.1 M------G---FAVVRTNREFVRPSAATPPSSGE------LLELSIIDRVVGLRHLVRSLHIFSAAAPSGGDAKPS--- 61

Os05g04584.1 M------G---FTVTRTSRSLVAPSS--PTPAET------LPLSVIDRVAGLRHLVRSLHVFEAGGRNGGGE------55

Bradi2g36910.1 M------EKK---FTVTRTSKSLVPPSSSSPTPAATEDDAPVPVIMRLSTIDRVPGLRHLVLSLHAFDGHGVVAGEDDEERI- 73

Os01g42880.1 M------AA---AAVTKSPPALVPPAG--PTPGGS------LPLSSIDKTAAVRVSVDFIQVFPSSAEAAKDQA----- 57

Bradi2g43520.1 M------A---PTVTKSPPALIPPAG--PTPGGS------LPLSSIDKTAAVRVSVDFIQVFPSSADAPRDQG----- 56

Os01g42870.1 M------AAAAAVAAVAAAAAAAE---PTVSKSAPELVPPAG--PTPRGA------LPLSSIDKTAAVRVSVDFIQVFPPATGGPAADGQE--- 74

Bradi2g43510.1 M------ADAA---PTVSKSPPALVPPVG--PTPRGA------LPLSSIDKTAAVRVSVDFIQVFPPSTDGASAG------58

Os04g09590.1 M------KN---VVITKSSPELVG-LSTKPAPPPPGD------ISLSSFDEALAF-AAFTSFHIFTNGIVEPAM------57

Os04g11810.1 M------S---YIVNKSSPELVGPPTTKPVAPTVADV------INLSSFDKAIGS-YLFTSFHVFDNGIVEPAM------58

AT5G41040.1 MVAENNKNKDVTLSASMDNNNNNIKGTNIHLEVHQKEPALVKPES--ETRKG------LYFLSNLDQNIAV--IVRTIYCFKS--EERGNEE----- 80

Bradi5g01240.1 MVAAEQENG---SSVAMAAGNMNSKAQ--LVSVKRGEPSLVAPAE--PTPTGE------HYYLSNLDQNIAV--IVQTVYCFKCPPSGRGHEAG---- 79

* 120 * 140 * 160 * 180 * 200

Bradi2g04990.1 ------PGPAR-TIERALAQALVRYYPLAGRLAFTD---DGG-Q------SHVDCGGP---RSGVWFTEAEAACGLEDVD 119

Bradi2g04980.1 ------ADPAR-TIERALAQALVRYYPLAGRLAFTD---DGG-Q------SHVDCGGP---GSGVWFTEAAAACGLEDVD 116

Os01g08380.1 ------VGPAR-TIERALARALVHYYPLAGRLAFSD---SG--E------VCVDCG-----DAGVWFTEAEASCSLEDVD 118

Os05g08640.1 ------LAPAR-AIETALARALVEYYPLAGRLAVSR---DSG-E------LQVDCCGGAGGHGGVWFIEAAVPCRLEDVD 125

Bradi2g33980.1 ------SPAR-AVERALARALVDYYPLAGRLAVS----DAG-E------LQVDCR-----DGGVWFIEAAVRCRLEDVD 117

Os06g39470.1 ------PAA-AIERALAAALVSYYPIAGRLAERG---DGG-E------LVVDCTG-----EGVWFIEATASCSLEDVD 117

Bradi1g36980.1 ------PVK-AIERALAAALVSYYPLAGRLAVPA---DGG-E------LVVDCTG-----EG------DVD 104

Os06g39390.1 VIVEGKKKNNKPAAAVVRGALADALVHYYPFAGRIVEDE---RSPGRP------AVLCSG-----EGVYFVEAAANCTLADVN 131

Os01g09010.1 ------VIRDALARALVFFYPLAGRIVEPE---AGSPA------IRCTA-----DGVYFAEAAADCSLEDVR 110

Bradi2g05480.1 ------VIRDALAKALVFFYPLAGRIVEPE---KEAAAAAAAAAAGENGDGEKKAPAASFPLGVRCAG-----DGVYFAEAEAECSLEDVR 136

Os05g19910.1 ------RRPAA-VIRAALARALADYPAFAGRFVGSL---LAG-D------ACVACTG-----EGAWFVEAAADCSLDDVN 122

Os01g18744.1 ------PAR-VIKEALGKALVDYYPFAGRFVDGG---GGPGS------ARVECTG-----EGAWFVEAAAGCSLDDVN 118

Os05g04584.1 ------PARVVIREALGKALVEYHPFAGRFVEGD---GGG-E------VAVACTG-----EGAWFVEATAACSLEEVK 112

Bradi2g36910.1 ------RWPAR-VVREALGKALVDYYPFAGRFVVDE---EG--E------VGVKCSG-----EGAWFVEAKAECSLEEAR 130

Os01g42880.1 ------ASVAAMREGFARALVHYYPVAGRIAEPV---PGE------PEIDCTG-----EGVWFIEAEASCSLEEAR 113

Bradi2g43520.1 ------ASVATMREGFAKALVHYYPVAGRIAEPV---QGE------PEVECTG-----EGVWFVEAEASCTLEDAR 112

Os01g42870.1 ------DAVARMRDGFARALVPYYPVAGRIAEPA---PGD------VVVDCTG-----EGVWFVEATASCTLADVN 130

Bradi2g43510.1 ------DQVAAMRDGFARALVPYYPVAGRIAEPT---PGD------LVVDCTG-----EGVWFVEAAASCSLADVN 114

Os04g09590.1 ------A--IKRALSQALVYYYPIAGRANFA----AGERR------LRISCTG-----EGVGFVAATASCALDDVK 110

Os04g11810.1 ------T--IKGALSQALVYYYPIAGRLVITGAADGGGDQ------LCVSCTG-----EGVAFVSATASCALDDVK 115

AT5G41040.1 ------AVQVIKKALSQVLVHYYPLAGRLTISP---EGK------LTVDCTE-----EGVVFVEAEANCKMDEIG 135

Bradi5g01240.1 ------AADALRDALSRVLVHYHPLAGRLAISP---EMK------LAVDCTG-----EGVVFVEADAACDLADMG 134

* 220 * 240 * 260 * 280 * 300

Bradi2g04990.1 YLEHP---MMISKDELLP-PTP---AAEEGDERRLVLLVQVTSFACGGFVVGFRFSHAVADGPGAAQFMAAVGDLARGAESLSMEPQWGRD-AVP--DPA 209 Clade III

Bradi2g04980.1 YLEHP---MMIPKDALLP-PTPH--AAEEGDERRLVLLVQVTSFACGGFVVGFRFSHAVADGPGAAQFMAAVGDLARGAESLSMEPQWGRD-AVP--DPA 207 Clade III

Os01g08380.1 YLEYP---MMVPKDELLP-PTP---AGEE--ERELVLLVQVTAFACGGFVVGFRFSHAVADGPGAAQFMAAVGELARGAGGVSVDPVWGRD-AIP--DPA 206 Clade III

Os05g08640.1 YLEYP---LAISKDELLPHPRPR--PTRD-EEDKLILLVQVTTFACGGFVVGFRFSHAVADGPGAAQFMGAVGELARGGERITVAPSWGRD-AVP--DPA 216 Clade III

Bradi2g33980.1 YLEYP---LAVDKDELLPHPRPK--PTHE-EESKLILLVQVTTFDCGGFVVGFRFSHAVADGPGAAQFMGAVGELARGAGRISVPPAWGRD-AIP--DPA 208 Clade III

Os06g39470.1 YLEYP---LMVDKDELLPHPTYP--ASESHPEDSLILLVQVTQFACGGFVVGFRFSHAVADGPGAAQFMTAVGEIARGRAAPALAPAWGRD-AIPC-PPS 210 Clade III

Bradi1g36980.1 YLEYP---LMMPKDELLPHPTYP--AADPLPEDSFILLVQVTQFACGGFVVGFRFSHAVADGPGAAQFMTAVGEIARGRAGPSVKPAWGRE-AIPS-PPA 197 Clade III

Os06g39390.1 HLERP---LLLSKEDLVPCPTPEQWPVEP---HNSLAMIQVTTFTCGGFVIGLRTNHAVADGTGAAQFMNAVGDLARGLPEPRVKPIWARD-RFP--DPD 222 Clade IV

Os01g09010.1 FLERP---LLLPKEDLVPYPGDDRWGVEP---HNTIMMMQITKFTCGGFVMGLRFNHASADGMGAAQFINAVGDMARGLPEPRVKPVWDRE-KFP--NPS 201 Clade IV

Bradi2g05480.1 FLERP---LLLPKEDLVPYPGPDKWSVEP---HNTIMMMQITKFTCGGFVMGLRFNHASADGMGAAQFIKAVGDMARGLPEPAVKPVWDRE-KFP--NPS 227 Clade IV

Os05g19910.1 GLEYP---LMISEEELLPAPED---GVDP---TSIPVMMQVTEFTCGGFILGLVAVHTLADGLGAAQFITAVAELARGMDKLRVAPVWDRS-LIP--NPP 210 Clade V

Os01g18744.1 GLDHP---LMIPEDDLLPDAAP---GVHP---LDLPLMMQVTEFSCGGFVVGLISVHTMADGLGAGQFINAVGDYARGLDRPRVSPVWARE-AIP--SPP 206 Clade V

Os05g04584.1 LLDHP---MVIPKEELLPEPAP---DVQP---LDIPLMMQVTEFTCGGFVVGLISVHTIADGLGAGQFINAVADYARGLAKPRVSPVWARD-AIP--DPP 200 Clade V

Bradi2g36910.1 HLDGNPMEMVIPKEDLLPEPIP---GVDP---LDIPLIMQVTEFTCGGFVVGLISVHTIADGLGAGQFINAVADYARGLPKPRVSPVWARD-LVP--DPP 221 Clade V

Os01g42880.1 NLERP---LCIPKEELLPRPPP---EVRV---EDTVLLAQITKFTCGGFAVGICFSHLVFDGQGAAQFLKAVGEMARGLPEPSLKPIWARD-AIP--NPP 201 Clade I

Bradi2g43520.1 NLERP---LCIPKEELLPRPPP---EVRL---EDTVLLAQITKFTCGGFSVGICFSHLVFDGQGAAQFLKAVGEMARGLPEPSLKPIWSRD-AIP--NPP 200 Clade I

Os01g42870.1 NLERP---LLIAKEHLLPRPPP---EEKL---EDLILMAQVTKFTCGGFAVGICFSHLVFDGQGAAQFLKAAGEMARGLPAPSVPPVWDRD-AIP--DPP 218 Clade I

Bradi2g43510.1 GLERP---LLIPKGELIPRPPP---EEKL---EDLILMAQVTKFTCGGFAVGICFSHLVFDGQGAAQFLKAAGELARGLPAPSVAPVWDRD-AIP--DPP 202 Clade I

Os04g09590.1 LFDPP--FAAVLKELAVDYPAEG--CGED----DPLLLMQVTEFACGGFVVGVTWNHVVADGLGIAQFLQAVGDLARGLPRPSVFPVSCGDGSLPA-LPP 201 Clade II

Os04g11810.1 LFDPP--FAALLKELAVAHPAAG--EAEA----DPLLLMQVTEFACGGFVVGMTWNHVVADGKGIAQFLRAVGELARGLPRPSVLPVSCGDDSLPE-LPP 206 Clade II

AT5G41040.1 DITK------PDPETLGKLVYDVVDAKN-ILEIPPVTAQVTKFKCGGFVLGLCMNHCMFDGIGAMEFVNSWGQVARG-LPLTTPPFSDR-TILNARNPP 225

Bradi5g01240.1 DLSTT------PDPAALGQLVYSIPGAKN-ILQMPPITAQVTRFKCGGFSLGLAMNHCMFDGLGAMEFVNSWAEMARGATELTVPPYLDRAAVLRARDPP 227

* 20 * 40 * 60 * 80 * 400

Bradi2g04990.1 GAV------VGALPDPAGAKRLEYLAMDISADYIDHFKAQYNSTNNG---G-ARCSAFEVLVAKAWQSRTRAA-GFDPSTT------VHLCF 284

Bradi2g04980.1 GAV------VGALPDPAGAKRLEYLAMDISADYIDHFKSQYNSSNNG---GGARCSAFEVLVAKAWQSRTRAA-GFDPSAT------VHLCF 283

Os01g08380.1 AAV------IGSLPDPAGAKRLEYLAVDISADYINHFKNQYNAEAHAAAAGVARCSAFEVLIAKAWRSRTRAA-GFEPDTT------VNLCF 285

Os05g08640.1 GAM------VGALPEPAGASRLEYLAIDISADYINHFKSQFAAATGG-----ARCSAFEVLIAKAWQSRTRAA-AFDPSTP------INLSF 290

Bradi2g33980.1 GAL------VGRLPEPAGAKRLEYLAIDISADYINHFKAQFAAATGG-----ARCSAFEVLIAKAWQSRTRAA-GFDEESP------VHLSF 282

Os06g39470.1 AA------VGPLPVPT-ELRLQYLAMDISTDYIDHFKARFLEQTGH------RCSAFEVLIAKAWQSRTRAA-GFAPGSP------VHVCF 281

Bradi1g36980.1 AAP------VGPLPVPT-ELRLQYLAMDISTDYIEHFKARFLEQAGH------RCSAFEVLIAKAWQARTRAA-RFAPGTP------VHVCF 269

Os06g39390.1 IKP------GPLPELP-VLPLQYIAFDFPAAYLGKLKAQYAATAGA----SKICSAFDIVIAKLWQCRTRAI-AADPAAA------VKLCF 295

Os01g09010.1 IKP------GPLPGLP-VLALDYIVLDFPTGYIDGLKAQYKAHSG------KFCSGFDVLTAKLWQCRTRAL-NLEPGAT------VKLCF 272

Bradi2g05480.1 IKP------GPLPELP-VLALDYIVLDFPTGYIDGLKAQYKAHSG------KFCSGFDVLTAKLWQCRTRAL-NLEPGAT------VKLCF 298

Os05g19910.1 KLP------PGPPPSFQ-SFGFQHFSTDVTSDRIAHVKAEYFQTFGQ------YCSTFDVATAKVWQARTRAV-GYKPEIQ------VHVCF 282

Os01g18744.1 KLP------PGPPPELK-MFQLRHVTADLSLDSINKAKSAYFAATGH------RCSTFDVAIAKTWQARTRAL-RLPEPTSR------VNLCF 279

Os05g04584.1 RMP------APPPRLE-LLDLRYFTVDLSPDHIAKVKSAFFESTGH------RCSAFDVCVAKTWQARTRAL-VAAAAAAGDDDQERRTVRVCF 280

Bradi2g36910.1 KMP------APPPKLE-LLDLRHFTVDLSPDHIAKVKSQYFASTGH------RCSAFDVVVAVTWQSRTRAL-RLAGAGY---DD----VHVCF 294

Os01g42880.1 KPP------LGPPPSFT-AFNFEKSVIEISLDSIKRVKDQVASET------NQKCSTFDVVTAMMFKSRTLAI-DFAPDAD------VRLGF 273

Bradi2g43520.1 KPP------LGPPPSFT-AFNFEKSVVEISLDSIKRVKDQVASET------SQKCSTFDVVTAIIFKCRALAI-GFAPEAD------VRLGF 272

Os01g42870.1 KPPP------RGPPPSFT-AFNFVTQVVDVSPESIARIKEDFSASPTG---GGQACSTFDAVTAVVFRCRALAASSLPDDAE------VRLGF 295

Bradi2g43510.1 KLP------RGPPPSFT-AFNFVTQVVEISPENIARIKEDFKAAT-----GGETCSTFDAVTAVVFKCRALAV-ELPDTAE------VRLGF 275

Os04g09590.1 LVAA------IEKTMLSLETKRFAYLDITIPSTMIERVKAEYAAAAGNVDSG-EPCTVFEAVTAALWRSRTRAVISS--DDPD------APAPLVF 282

Os04g11810.1 LVAA------MEKAMLTQESKQFAYLDVTIPSSVIGRVKAAFDDVGDVARSGGEPCTVFEAVAAVLWRSRTRAVLISGDSDAD------TPAPLVF 290

AT5G41040.1 KIENLHQEFEEIEDKSNINSLYTKEPTLYRSFCFDPEKIKKLKLQATENSESL--LGNSCTSFEALSAFVWRARTKSLKMLSDQKT------KLLF 313

Bradi5g01240.1 LISFPHREFEEIPDVSGMAALYGDQDLTYRSFCFGPDRLERVRGLAQSQAQ----A--SFTTFEALSGLVWRARTAALGLAPEQQT------KLLF 311

* 20 * 40 * 60 * 80 * 500

Bradi2g04990.1 AMNARPLLHAS--LPSAGAG------FYGNCYYIMRVSAPAGKVSGSSVPEVVKIIKDGKRRMPAEFARWASGEAGAGG----EDPYRITSDYRTLLVSD 372

Bradi2g04980.1 AMNARPLLHAS--LPSAGAG------FYGNCYYIMRVSAPAGKVSGSSVPEVVKIIKDGKRRMPAEFARWASGEAGAGG----EDPYRITSDYRTLLVSD 371

Os01g08380.1 AMNARPLLHAS--LPRGGAG------FYGNCYYIMRVSAPAGKVAGSSVTEVVKIIKDGKRRMPSEFSRWAAGDMAGG------DPYQITSDYRTLLVSD 371

Os05g08640.1 AMNARPLL-----LPRGGAG------FYGNCYYIMRVASTAGRVATASVTDVVRMIREGKKRLPSEFARWAAGEMAG------VDPYQITSDYRTLLVSD 373

Bradi2g33980.1 AMNARPLLHAR--LPSGGAG------FYGNCYYIMRVSSTAGKVASSSMADVVKIIKEGKKRLPSEFARWAAGEMAG------VDPYQITSDYRTLLVSD 368

Os06g39470.1 AMNARPVLR-----RALPDG------FYGNCYYIMRVTAAAGAVADASVNDVVRLIREGKKRLPGEFARWSGGGGGGE-----DDPYRITSDYRTLLVSD 365

Bradi1g36980.1 AMNARSALPQ---PRAVPDG------FYGNCYYIMRVSAPAEAVSDAPLHEVVRLIREGKKRLPSEFARWSRGEMNG------DPYRITSDCRTLLVSD 353

Os06g39390.1 FASARQVLG------LETG------YWGNAIFPVKVSAAAGEVAASSVIELVGVVREAKRRMAGECLRWAEGRTGG------ADPFQMTFDYESVYVSD 376

Os01g09010.1 FASVRHLLK------LDRG------YYGNSIFPVKMSAPSETVLSSSVMEVVDMIRQAKERMAVEFFQFAKEETE------QDPFQMTFNYESIYVSD 352

Bradi2g05480.1 FASVRHLLK------LDPG------YYGNSIFPVKMSAPSEKVLGSSVMEVIDMIREAKQRMAVEFFQFAKEETK------QDPFQMSFDYESIYVSD 378

Os05g19910.1 FANTRHLLTQV---LPKDGG------YYGNCFYPVTVTAIAEDVATKELLDVIKIIRDGKARLPMEFAKWASGDVKV------DPYALTFEHNVLFVSD 366

Os01g18744.1 FANTRHLMAGAAAWPAPAAGGNGGNGFYGNCFYPVSVVAESGAVEAADVAGVVGMIREAKARLPADFARWAVADFRE------DPYELSFTYDSLFVSD 372

Os05g04584.1 FANTRHLMLKGDGAAAAATG------FYGNCFYPVAAVASGGEVAGADIVDVVRIVRDAKARLAADVARWAVGGFEE------DPYELTFTYDSLFVSD 367

Bradi2g36910.1 FANTRHLMLHG---GAGAAG------FYGNCFYPVRATCGSAEVASADVAGVVKVVRDAKARLAGDVARWAVGGFEQ------DPYELTFTYDSLFVSD 378

Os01g42880.1 AASTRHLLNN---VLPSVDG------YYGNCVYPGGLAKTSQEVKDASLVEIVTAIREAKDVLSTRFLDWMSGGAKE------NHYNVSLDYGTLVVTD 357

Bradi2g43520.1 AAGTRHLLNN---VLPSVEG------YYGNCVYPGGLAKTSQDVKEASLVEIVTAIREAKDALSTRFLDWMSGGAKE------NHYNVSLDYGTLIVTD 356

Os01g42870.1 AASTRHLLAG---VLPAVDG------YYGNCVYPVGIARHRGAVRGAALAEVVGVVREAKEALAARFTDWLGGGGGG------DHYDVPLDYGTVTVSD 379

Bradi2g43510.1 AASTRHLLQG---VLPSVDG------YYGNCVYPVGITRSSKTIREAALTEVVGVMREAKEALTVRFTDWMRGGAKD------DHYNVPLDYGTVTVSD 359

Os04g09590.1 AANARKHVG------AKEG------YYGNCVTSQVAVPTSDEVANGDLKHVVRLIRRAKEEIPLQFKNAGGGGMNG---KRVKQLAGVLFGYSAFYVAS 366

Os04g11810.1 AANVHKHVG------AKHG------YYGNCVTSQVVAATSGEVANGDANDVVKLIRRAKELIPAQFEN-GGVAMNGAAARVERQLMSALFGYNAFYVAS 376

AT5G41040.1 AVDGRAKFEP-----QLPKG------YFGNGIVLTNSICEAGELIEKPLSFAVGLVREAIKMVTDGYMRSAIDYFEV------TRARPSLSSTLLITT 394

Bradi5g01240.1 AVDARRRLSP-----PLPRG------YFGNGIVLTNALATAGDLLASPVSSAAAMVQDAVRMVTDEYVRSAVDYFEA------TRARPSLASTLLITT 392

* 20 * 40 * 60 *

Bradi2g04990.1 WTRLGFAEVDYGWGPPAHVVPLTN-LDYIATCILVKPWAHKPGARLITQCVTPDRVAAFHQGMLDMN*----- 438

Bradi2g04980.1 WTRLGFAEVDYGWGPPAHVVPLTN-LDYIATCILVKPWAHKPGARLITQCVTPDRVAAFHQGMLDMN*----- 437

Os01g08380.1 WTRLGFAEVDYGWGPPAHVVPLTN-LDYIATCILVRPWAHKPGARLITQCVTPDRVAAFHEGLLDLN*----- 437

Os05g08640.1 WTRLGFAEVDYGWGPPGHVVPLTN-LDYIATCILVKPWAHKPGARLITQCVTPDRVTAFHDAMVDIN*----- 439

Bradi2g33980.1 WTRLGFAEVDYGWGPPAHVVPLTN-LDYIATCILVKPWAHKPGARLITQCVTPDRVAAFHDAMVDTN*----- 434

Os06g39470.1 WSRLGFAEVDYGWGAPVHVVPLTN-LDYIATCILVRPSAHKPGARLITQCVAADAVDAFHNDMMRLD*----- 431

Bradi1g36980.1 WSRLGFAEVDYGWGAPVHVVPLTN-LDYIATCILVRPSAHKPGARLITQCVAADGVDEFHRDMMRLD*----- 419

Os06g39390.1 WSKLGFNDVDYGYGAPSAAGPLVN-CDLISSVIVMRAPAPLAGTRLLASCVTKEHADDFAARMREDLV*---- 443

Os01g09010.1 WSKLGFAEVDYGFGPPKFAGPLVN-NDFIASVVILKAPLPLDGTRMLASCVTKEHSEEFVRGMKEDLP*---- 419

Bradi2g05480.1 WSKLGFSDVDYGFGPPMFAGPLVN-NDFIASVVILKAPLPLDGTRMLASCVTKEHSDEFVRGMKEDMP*---- 445

Os05g19910.1 WTRLGFFEVDYGWGTPNHIIPFTY-ADYMAVAVLGAPPMPKKGTRIMTQCVENKCIKEFQDEMKAFI*----- 432

Os01g18744.1 WTRLGFLEADYGWGPPSHVIPFAY-YPFMAVAIIGAPPVPKTGARIMTQCVEDDHLPAFKEEIKAFDK*---- 439

Os05g04584.1 WTRLGFLDADYGWGTPSHVVPFSY-HPFMAVAVIGAPPAPKLGARVMTMCVEEAHLPEFRDQMNAFAAAN*-- 436

Bradi2g36910.1 WTRLGFLEADYGWGPPAHVVPFSY-HPFMAVAVIGAPPKPKLGSRVMTMCVEEDHLPEFRDQMNAFAFTAGK* 449

Os01g42880.1 WSHVGFNEVDYGFGEPSYVFTLNDDVNIVPSVVYLKPPKPKQGIRLVLQCVEAQHSKVFGEELQKLA*----- 424

Bradi2g43520.1 WSHVGFNEVDYGFGEPSYVFTMNDDVNIVPSVVYLKPPKPKQGIRLVLQCVEEQHSAVFREELQKLA*----- 423

Os01g42870.1 WSRVGFNEVDYGFGEPGYVFTLNDDVNIVASVIYLRPPAPKRGIRLMLRCVEEPHAAAFADELAKFA*----- 446

Bradi2g43510.1 WSRVGFNEVDYGFGEPGYVFTLNDDVNIVASVIYLKPPTPKRGIRLMLRCVEEPHAAVFADEIAKYA*----- 426

Os04g09590.1 WRNIGFEAPDFGGGRAARVMCHFE--PTGVPSCVACLPRDGGGASVLSLCVRDEHVDAFLAELATLG*----- 431

Os04g11810.1 WRNIGFEAVDFGGGRPARVMCHVG--PTAVPSCVACLPRDSGGASVLLLCVKEEHVDAFLAELESFK*----- 441

AT5G41040.1 WSRLGFHTTDFGWGEPILSGPVALP---EKEVTLFLSHGEQRRSINVLLGLPATAMDVFQEQFLQI*------457

Bradi5g01240.1 WSRLAFDGADFGWGQPAMSGPVTLP---EKEVILFLAHGQERKSINVLLGLPASAMDAFQELMDEI*------455

Figure S2: Content of p-coumaric acid in isolated cell walls (AIR) of leaves + stems of RNAi::BdAT1 transformants derived from (a) nine T2 plants generated from T0 transformation event 3-4, (b) five T2 plants generated from T0 transformation event 4-11, (c) five T2 plants generated from T0 transformation event 2-3, and corresponding control plants. CONT = control. Mean ± SEM of duplicate determinations from from 3-month-old plants. Asterisks indicate significant differences from the control (Tukey’s, α = 0.05).

Figure S3: Content of p-coumaric acid in isolated cell walls (AIR) of leaves + stems of RNAi::BdAT7 transformants derived from (a) six T2 plants generated from T0 transformation event 2_6, (b) five T 2 plants generated from T0 transformation event 4_11, and corresponding control plants. Mean ± SEM of duplicate determinations from from 3-month-old plants. Asterisks indicate significant differences from the control (Tukey’s, α = 0.05).

Figure S4: Content of p-coumaric acid in isolated cell walls (AIR) of leaves (a, c, e) and stems (b, d, f) of 35S::BdAT1 transformants derived from (a, b) eight T1 plants generated from T0 transformation event 18-19, (c, d) six T1 plants generated from T0 transformation event 18-8, (e, f) eight T1 plants generated from T0 transformation event 18-9, and corresponding control plants. Mean ± SEM of duplicate determinations from 3-month-old plants. Asterisks indicate significant differences from the control (Tukey’s, α = 0.05).

Table S1: Primer and probe sequences designed for cloning for vector construction and qRT-PCR experiments

Gene specific primers

BdAT1-1F AAGTTCACCTGCGGTGGATTCTCT 60.1°C

BdAT1-R AAAGTTGAAAGCGGTGAACGACGG 59.9°C

BdAT7-5F ACGTCGACTATCTGGAGTACCCTCT 59.8°C

BdAT7-1R AGATCTCGATGGCGAGGTACT 60.1°C

Cloning for RNAi vector

BdAT1-2F CACCAAGTTCACCTGCGGTGGATTCTCT 62.8°C

BdAT1-1R CGAAAGTGGAACATTTCTGGCTGGTC 59.8°C

BdAT7-F1 CACCAAACTGGTAGTGAAGAAAGGCATC 62.0°C

BdAT7-R TCTTACATGGACAGAACAACACCT 59.9°C

Cloning for Over-expression vector

BdAT1-5F ACACATCCTCCTCCGGAGCTC 60.8°C

BdAT1-5R1 ACAGTCTAGAGACACGGCCAA 60.5°C

qRT-PCR

BdAT1-F CAACCCTCCTAAGCCACCTCTT

BdAT7-F AAGGCGCCACCGACTAGTCT

SamDC-F GAGGAGGATGGCGTGCTGTA

UBC18-F CCTCCAAAGGTGGGTGATTG

BdAT1-R GCTGGTCTCACTCGCAACCT

BdAT7-R AAAAGTCTATACACCTTGCGGGTTT

SamDC-R GGCTGGCTGCTTCACAGAATA

UBC18-R GGGATAATGCTCGGGGAAGT

Probes for qRT-PCR

BdAT1 ACCGTCGTTCACTGCT

BdAT7 CCTTCCGTCAGCGTAT

SamDC CCCGTGCAATTTG

UBC18 CCTCTACGCTGGTGAGAC

Primers for RT-PCR Notes

BdAT9-F TCGTGGAGCCGGAGAAAGAGG Product size is 2274 bp

BdAT9-R GGAAGTCCAGCACGATGTAGTCCA

BdAT1-F TCCGTCGACTTCATCCAGGTCTT Product size is 1493 bp

BdAT1-R AAAGTTGAAAGCGGTGAACGACGG

BdAT8-F ATCGAGTCCCTCCACGTCTTCAA Product size is 575 bp

BdAT8-R ATCGAGTCCCTCCACGTCTTCAA

BdAT21-F TGCAGACGGTCTACTGCTTCAAGT Primers designed across

intron. Product size is 379 bp

BdAT21-R AACATGCAGTGGTTCATCGCCA

BdAT2-F CACTACAATGTGCCTTTGGACTAC Product size is 313 bp

BdAT2-R TAGATACTGCAAGAGCGGTTACAC

BdAT6a-F TTCTACGGCAACTGCTACTACATC Product size is 387 bp

BdAT6a-R GTGGAACGCAGCTACTCTGTC

BdAT6b-F GAGTCGCTCCACGTCTTCA Product size is 460 bp

BdAT6b-R GCTCCATTGACAGGGACTCT

BdAT7-F AAACTGGTAGTGAAGAAAGGCATC Product size is 341 bp

BdAT7-R TCTTACATGGACAGAACAACACCT

BdAT3-F CATCTTCGTCTTCCCCAACA Product size is 383 bp

BdAT3-R CTCCTTGGGGATCACCATCT

GAPDH-F AGAAGGTTGTCATCTCTGCACCCA Product size is 391 bp

GAPDH-R ACAGTGAGATCACCAACCGACACA

Table S2: Sequences of theRNAi fragments

BdAT1 RNAi sequence (301 bp)

1AAGTTCACCTGCGGTGGATTCTCTGTGGGTATTTGCTTCAGCCACCTGGTGTTTGATGGG
61CAGGGCGCAGCCCAGTTTCTGAAAGCAGTCGGCGAGATGGCACGAGGGCTCCCTGAGCCA
121TCACTTAAGCCCATCTGGTCCCGTGACGCCATTCCCAACCCTCCTAAGCCACCTCTTGGA
181CCACCACCGTCGTTCACCGCTTTCAACTTTGAGAAGTCAGTGGTTGAGATCTCTCTTGAC
241AGCATCAAGCGTGTCAAAGACCAGGTTGCGAGTGAGACCAGCCAGAAATGTTCCACTTTC
301G

BdAT7 RNAi sequence (341 bp)

1AAACTGGTAGTGAAGAAAGGCATCAAAGAAGGACGGAAGAAAGAAGAAGAAGACTAGAAC
61AGAACATAACGATATGGGGGACAGGTAGACACAGCTAAATGGCGGTTGGCAATAGTGGAA
121TTGGTATTGGATTCCTTTGGACGTTCTCGGTGGTGTTTGGTGAAGACTGTGTACGACAAG
181GGGGTTCTAGTTGAAGGATCAAGGCGCCACCGACTAGTCTCCCCTTCCGTCAGCGTATTG
241TACTATTCAATTTTATTTTTTATTTTTTAAAATATAAACCCGCAAGGTGTATAGACTTTT
301CTGTAGTTGATATCTTCAGGTGTTGTTCTGTCCATGTAAGA

Table S3: Summary of plant transformations

Construct / Transformations / Calli on regeneration medium / Plants regenerated / Plants that survived / Regeneration percentage
RNAi::BdAT1 / 2 / 340 / 38 / 19 / 5.6
RNAi::BdAT7 / 2 / 120 / 19 / 11 / 9.2
35S::BdAT1 / 4 / 696 / 45 / 16 / 2.3

Table S4: Results for Blastn of the primer, probe and RNAi trigger sequences for BdAT1 and BdAT7 against the Brachypodium genome assembly v2.1 and Brachypodium sequences in the GenBank Nucleotide Collection.