Nuclear Chemistry Notes

Nuclear Chemistry Notes

Nuclear reactions involve changes inside the nucleus of an atom. When the nucleus of an atom is unstable, it tends to decay, or fall apart. When a nucleus decays, it gives off radiation in the form of particles and energy. Generally, the atoms with the largest nuclei are the most unstable. When an atom’s nucleus decays it often changes the number of protons in the nucleus. Therefore, it also changes the identity of the atom.

The half-life is the time it takes for half of a sample of radioactive material to decay.

Study the graph at the top of page 688. The red dots represent the original radioactive element. The grey dots represent the element it is changing into as it decays. Why does the graph have a curved shape?

When a nucleus decays it can give off many types of radiation:

Alpha particle—two protons and two neutrons (a helium nucleus). Mass of 4 amu. Charge of + 2. Low energy—cannot penetrate a piece of paper.

Beta particle—an electron ( Mass of zero. Charge of 1-. Can penetrate paper and skin, but not lead or glass.) Beta particles come from the decay of a neutron into a proton and an electron. The proton generally stays in the nucleus and the electron is emitted.

Gamma radiation—high energy radiation, very short wavelength, very high frequency. No mass, no charge. Can be blocked only by thick layers of lead, concrete, or both.

The force that holds protons to protons, protons to neutrons, and neutrons to neutrons inside a nucleus is called the strong nuclear force. This force of attraction is a very powerful force. (If it wasn’t so strong, the positively charged protons would all repel each other because like charges repel.) The strong nuclear force is what gives a nuclear reaction its energy. A nuclear reaction releases thousands of times more energy than a chemical reaction. A chemical reaction involves only electrons. Nuclear reactions involve the protons and neutrons in the nucleus. In a nuclear reaction, some of the matter inside the nucleus is changed into energy.

Fission and fusion are two different types of nuclear reactions. In a fusion reaction, small atoms such as hydrogen are fused together to make larger atoms. In a fission reaction, heavy atoms such as uranium break apart to form smaller atoms. Which one is happening in the sun? Which one happens in a nuclear power plant? (see pages 697—699) Which one has the potential to produce more energy?