Supplemental Instruction
Iowa State University / Leader: / Kia
Course: / CHEM 177
Instructor: / Anand
Date: / April 20th, 2017
Concept Check
- Fill in the blanks from the Kinetic-molecular Theory
- Gases consist of ______numbers of molecules that are in continuous random motion.
- The volume of the gas molecules is ______relative to the total volume of the container.
- Intermolecular forces between gas molecules are ______.
- Energy can be transferred between molecules during ______, but the average kinetic energy of the molecules ______.
- The average connect energy of the molecules is ______to the absolute temperature.
- Give 3 different units of pressure
Practice Question
- Complete the following table for an ideal gas:
P / V / n / T
2.00 atm / 1.00 L / 0.500 mol / ? K
0.300 atm / 0.250 L / ? mol / 27 degree C
650 torr / ? L / 0.333 mol / 350 K
? atm / 585 mL / 0.250 mol / 295 K
- The Goodyear blimps, which frequently fly over sporting events, hold approximately 175,000 ft3 of helium. If the gas is at 23 degrees C and 1.0 atm, what mass of helium is in a blimp?
- A 35.1 g sample of solid CO2 (dry ice) is added to a container at a temperature of 100 K with a volume of 4.0 L. If the container is evacuated (all of the gas removed), sealed and then allowed to warm to room temperature (T=298 K) so that all of the solid CO2 is converted to a gas, what is the pressure inside the container?
- Many gases are shipped in high-pressure containers. Consider a steel tank whose volume is 55.0 gallons that contains O2 gas at a pressure of 16,500 kPa at 23 degrees C.
- What mass of O2 does the tank contain?
- What volume would the gas occupy at STP?
- At what temperature would the pressure in the tank equal 150.0 atm?
- What would be the pressure of the gas, in kPa, if it were transferred to a container at 24 degrees C whose volume is 55.0L?
- Both Jacques Charles and Joseph Louis Guy-Lussac were avid balloonists. In his original flight in 1783, Jacques Charles used a balloon that contained approximately 31,150 L of H2. He generated the H2 using the reaction between iron and hydrochloric acid:
Fe(s) + 2 HCl(aq) à FeCl2(aq) + H2(g)
How many kilograms of iron were needed to produce this volume of H2 if the temperature was 22 degrees C?
ACS Final Practice
- The edge of a body-centered-cubic unit cell (which contains two atoms per unit cell) of an element Y was found to be 3.16x10-8 cm. The density of the metal is 19.35 g/cm3. What is the approximate molar mass of Y?
- Ammonia, NH3, reacts with the hypochlorite ion, OCl-, to produce hydrazine, N2H4. How many moles of hydrazine are produced from 5.85 mol of ammonia if the reaction has a 78.2% yield? 2NH3 + OCl- à N2H4 + Cl- + H2O
Challenge Question
- According to molecular orbital theory is Be2 or Be2+ expected to exist? Explain.