Chemical Bonding Basics

By John T. Moore

Part of the Chemistry For Dummies Cheat Sheet

In bonding, atoms lose, gain, or share electrons in order to have the same number of electrons as the noble gas that's nearest on the periodic table. Ionic, covalent, and metallic bonds are formed by combinations of metals and nonmetals.

·  Metal + nonmetal = ionic bond

·  Nonmetal + nonmetal = covalent bond

·  Metal + metal = metallic bond

When two elements engage in ionic bonding, one or more electrons are transferred from the metal to the nonmetal, forming ions (charged atoms). The metal, having lost one or more electrons, forms a cation, an ion with a positive charge; the nonmetal, having gained one or more electrons, becomes an anion, an ion with a negative charge.

When two elements form a covalent bond, one or more electron pairs are shared between these two elements. In metallic bonding, which occurs in metals (either a pure metal or an alloy of two or more metals), the valence (outer shell) electrons are donated to a "sea of electrons."

Chemistry Glossary

Archimedes Principle

A principle discovered by the Greek mathematician Archimedes which states that the volume of a solid is equal to the volume of water it displaces.

Chemistry Glossary

atomic number

The number of protons in the nucleus of an atom.

Chemistry Glossary

Bohr model

A model of atomic structure developed by Niels Bohr, a Danish scientist. In this model, electrons occur in orbits of differing energy levels around the nucleus of an atom.

Chemistry Glossary

condensation

The change in the physical state of matter from a gaseous state to a liquid state.

Chemistry Glossary

deposition

The change in the physical state of matter from a gaseous state to a solid state without ever becoming a liquid. The reverse of sublimation.

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electrolytes

Substances that can conduct electricity either in the molten state or when dissolved in water.

Chemistry Glossary

electron configuration notation

A method used by chemists to represent electrons in bonding and chemical reactions.

Chemistry Glossary

electronegativity

A measure of an atom’s strength to attract a bonding pair of electrons to itself.

Chemistry Glossary

energy level diagram

A method used by chemists to diagram the electrons for an atom (including orbitals and subshells) in bonding and chemical reactions.

Chemistry Glossary

heterogeneous mixture

A mixture whose composition varies from position to position within a sample.

Chemistry Glossary

homogeneous mixture

A mixture whose composition is the same from position to position within a sample.

Chemistry Glossary

isotopes

Atoms of the same element that have varying numbers of neutrons.

Chemistry Glossary

mass number

The sum of the protons and neutrons in a particular isotope; also called atomic weight.

Chemistry Glossary

nonelectrolytes

Substances that do not conduct electricity in the molten state or when dissolved in water.

Chemistry Glossary

nuclear fission

A nuclear reaction in which an atom’s nucleus splits into smaller parts.

Chemistry Glossary

nuclear fusion

A process in which lighter nuclei of atoms join together into a heavier nucleus; essentially the opposite of nuclear fission.

Chemistry Glossary

nuclear reaction

Any reaction that involves a change in nuclear structure.

Chemistry Glossary

periodic table

A table that displays all known chemical elements in an arrangement that is based on the properties of the elements; changes over time as new elements are discovered.

Chemistry Glossary

quantum mechanical model

A model of atomic structure that is based on mathematics and can be used to explain observations made on complex atoms.

Chemistry Glossary

radioactivity

The spontaneous decay of an unstable nucleus in an atom.

Chemistry Glossary

SI system

A worldwide measurement system that is based on the older metric system. The SI comes from the French Systeme International.

Chemistry Glossary

sublimation

The change in the physical state of matter from a solid state to a gaseous state without ever becoming a liquid (such as dry ice).

Chemistry Glossary

valence electrons

The electrons in the outermost energy level of an atom, the farthest away from the nucleus.