Atomic Theory and the Periodic Table Review

What are the contributions of the following people to the atomic model? For those that resulted in a revision to the model. Draw the model they proposed.

Democritus- originally named atom; atom model is solid homogenous sphere

Dalton- proposed the atomic theory, atom model is solid homogeneous sphere

Thomson- proved the existence of negative particles through work with cathode ray tubes; atom model had negative particles embedded in positive matrix (also called plum pudding model)

Rutherford- proved the existence of the nucleus with gold foil experiment; atom model had positive particles in a nucleus surrounded by electron

Chadwick- discovered the neutron

Bohr- atom model had a nucleus of protons and neutrons surrounded by electron in fixed orbits like planets orbiting the sun

Give the charge and location of each of the subatomic particles.

Particle Charge Location

Proton __+______nucleus______

Neutron __0______nucleus______

Electron __-______orbiting nucleus______

Define the following:

Atomic Number- number of protons in an atom

Mass Number- number of particles in the nucleus (protons + neutrons) in a particular atom

Atomic Mass- average mass of all the naturally occurring isotopes of an element according to their abundance

Isotope- atoms of the same element that differ in their number of protons (and so also differ in their mass number)

Ion- atom with a charge because of the number of protons and electrons are unequal

Cation- a positively charged ion; occurs when a neutral atom loses electrons

Anion- a negatively charged ion; occurs when a neutral atom gains electrons

Calculate the number of protons, neutrons, and electrons of the following isotopes.

Isotope # of Protons # of Neutrons # of Electrons

Hydrogen-3 1 2 1

Hydrogen-2 1 1 1

Calcium-40 20 20 20

Copper-63 29 34 29

Iodine-127 53 74 53

Barium-137 56 81 56

Write the nuclear symbol for each of the isotopes in the previous problem

_3H__ __2H __ ___40Ca __ ___63Cu __ ___127I __ ___137Ba ___

Calculate the number of protons, neutrons, and electrons of the following ions.

Ion # of Protons # of Neutrons # of Electrons

37Cl- 17 20 18

22Na+ 11 11 10

28Mg+2 12 16 10

14N-3 7 7 10

Name each of the following ions. Multivalent ion are in bold.

Fe+3 __iron (III) ion______

S-2 __sulfide ion______

Li+ __lithium ion______

I- __iodide ion______

Calculate the average atomic mass of the following problems.

Silver (Ag) is found as two isotopes (silver-107 and silver-109). What is the average atomic mass if the abundance of silver 107 is 51.86%?

107 x 0.5186 = 55.4902

109 x 0.4814 = 52.4726

55.4902 + 52.4726 = 107.96 amu

Iron has four isotopes (listed with their abundances below). Calculate the average atomic mass.

Iron-54 5.90%

Iron-56 91.72%

Iron-57 2.10%

Iron-58 0.280%

54 x 0.0590 = 3.186

56 x 0.9172 = 51.3632

57 x 0.0210 = 1.197

58 x 0.00280 = 0.1624

3.68 + 3.666 + 35.232 + 2.695 = 55.91 amu

Who is the “father” of the period table? Mendeleev

The modern periodic table has the elements arranged by their _atomic number___ forming columns called _groups or families___ and rows called _periods______.

What group numbers are each of the following?

Alkali metals- 1

Alkaline earth metals- 2

Halogens- 17 (7A)

Nobel gases- 18 (8A)

Transition elements- 3-12

Name at least three characteristics of metals and nonmetals.

Various (see notes)

For each of the following elements, determine if it is a metal, metalloid, or non-metal.

Na __metal______

Si __metalloid______

N __non-metal______

Ar __non-metal______

U __metal______

Pb __metal______

List the seven diatomic elements. N, O, F, Cl, Br, I