Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
SAFETY DATA SHEET
3-IN-ONE with added PTFE
1. Identification of the substance/preparation and of the company/undertaking
Product name: 3-IN-ONE with added PTFE Manufacturer : CCL Industries Ltd
South Humberside
Industrial Estate
Grimsby
DN31 2TF
Tel: 01472 265200
Fax: 01472 265290
Supplier : WD-40 Company Ltd.
PO Box 440
Kiln Farm
Milton Keynes
MK11 3LF
Tel: 01908 555400
Fax: 01908 266900
Emergency telephone number :
Material Uses : Not available.
2. Composition / information on ingredients
Substance/Preparation : Preparation
Chemical name* CAS No. % EC Number Classification
Solvent D40 64742-48-9 60-70 265-150-3 R10
Xn; R65
R66
Catenex Oil S323 64742-65-0 20-30 265-169-7
Butyl Diglycol 112-34-5 0-10 203-961-6 Xi; R36
Alox 575 0-10 Xi; R41
See Section 16 for the full text of the R Phrases declared above
* Occupational Exposure Limit(s), if available, are listed in section 8
3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC
and its amendments.
Classification : R10
Aggravating conditions: Repeated or prolonged exposure is not known to aggravate
medical condition.
4. First-aid measures
First Aid Measures.
Inhalation : If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical
Personnel. Never give anything by mouth to an unconscious
Person. Loosen tight fitting clothing such as a collar, tie
belt or waistband. Get medical attention if symptoms appear
Skin Contact : Wash with soap and water. Get medical attention if
irritation develops.
Eye Contact : Check for and remove any contact lenses. In case of
contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical attention.
5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog. Cool
containing vessels with water jet in order to prevent
pressure build-up, auto ignition or explosion.
Special fire-fighting procedures
: Fire fighters should wear positive pressure
self-contained breathing apparatus (SCBA) and full
turnout gear.
Protection of fire-fighters
: Be sure to use an approved/certified respirator or
equivalent.
6. Accidental release measures
Personal precautions:
Environmental : Keep away from heat. Keep away from sources of ignition.
Precautions and Stop leak if without risk. Absorb with DRY earth, sand
Clean-up Methods or other non-combustible material. Do not touch spilled
material. Prevent entry into sewers, basements or
confined areas; dike if needed.
Note: See section 8 for personal protective equipment and section 13 for
waste disposal.
7. Handling and storage
Handling : Keep away from heat. Keep away from sources of ignition.
Do not ingest. Do not breathe gas/fumes/ vapor/spray.
If ingested, seek medical advice immediately and show the
container or the label.
Storage : Store in a segregated and approved area. Keep container in a
cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Avoid all possible sources
of ignition (spark or flame).
Packing materials
Recommended use : Use original container.
8. Exposure controls/personal protection
Engineering : Provide exhaust ventilation or other engineering controls
measures to keep the airborne concentrations of vapours below their
respective occupational exposure limits. Ensure that
eyewash stations and safety showers are proximal to the
work-station location.
Hygiene measures : Wash hands after handling compounds and before eating,
smoking, using lavatory, and at the end of day.
Ingredient Name Occupational Exposure Limits
Solvent D40 Not available.
Catenex Oil S323 EH40 (United Kingdom(UK)
TWA 5 mg/m3 Form: mist
TWA 10 mg/m3 Form: mist
Butyl Diglycol Not available.
Alox 575 Not available.
Recommended monitoring procedures
Personal protective equipment
Respiratory : Wear appropriate respirator when ventilation is
system inadequate.
Skin and body : Gloves & Overalls
Eyes : Safety Glasses
9. Physical and chemical properties
Physical state : Aerosol.
Colour : Not available.
Odour : Not available.
pH : Not available.
Boiling Point :
Flash point :
Fire Hazards in : Flammable in the presence of open flames, sparks and
Presence of static discharge,
Various Substances
Auto ignition :
Temperature.
Explosive : Risks of explosion of the product in presence of
properties mechanical impact: Not available.
Risks of explosion of the product in presence of static
discharge: Not available.
Lower explosion :
Limit
Oxidizing : Not available.
Properties
Density :
Solubility : Not available.
10.Stability and reactivity
Stability : The product is stable.
11.Toxicological information
Acute toxicity
Ingredient Name Test Result Route Species
Butyl Diglycol LD50 6560 mg/kg Oral Rat
LD50 4120 mg/kg Dermal Rabbit
Alox 575 LD50 >5000 mg/kg Oral Rat
Local effects
Chronic toxicity : Repeated or prolonged exposure is not known to aggravate
medical condition.
Developmental :
and Teratogenic
Effects
12.Ecological information
Pale spindle oil is a mixture of non-volatile components which are not expected to be released to air in any significant quantities.
If released to water the oil will form a floating layer and its components will not evaporate or dissolve to any great extent. Dissolved components will be absorbed in sediments. In aerobic water any sediments will biodegrade slowly, but in anaerobic conditions they will persist. Pale spindle oil is practically non-toxic to aquatic organisms but contains components which have a high potential to bioaccumulate. Small volumes released on land will be absorbed in the upper soil layers and biodegrade slowly. Larger volumes may penetrate into anaerobic soil layers in which the product will persist and may reach the water table on which it will form a floating layer. The more soluble components may dissolve but their high soil absorption co-efficiency and the low solubility will prevent significant contamination of ground water.
Volatile organic compounds (weight): 60.5% of product contains VOC’s
Tins: Contain 7% recycled steel and in turn are recyclable
Caps: High Density polypropylene which is recyclable
Corrugated: Recyclable
13.Disposal considerations
Methods of : Waste must be disposed of in accordance with federal,
disposal; Waste state and local environmental control regulations.
of residues;
Contaminated
packaging
Waste : Not applicable.
Classification
European Waste
Catalogue (EWC) : Not available.
Hazardous Waste : The classification of the product may meet the criteria
for a hazardous waste
14.Transport information
International transport regulations
Proper Shipping Name: Aerosols
UN Number 1950
UN Class 2
Packing Group N/A
ADR/RID IMO
Proper Shipping Name: Aerosols Proper Shipping Name: Aerosols
UN Number 1950 UN Number 1950
UN Class 2 UN Class 2
Classification code 5F Packaging Group N/A
Packing Group N/A Marine Pollutant - No
Hazard Identification number – none. EmS 2-13
15.Regulatory information
EU Regulations
Risk Phrases : R10- Flammable.
Safety Phrases : S2 Keep out of reach of children.
Product Use : Classification and labelling have been performed according
to EU directives 67/548/EEC, 88/379/EEC including
amendments and the intended use.
- Consumer applications.
-
Additional : Pressurized container: protect from sunlight and do not
Warning Phrases expose to temperature exceeding 50°C. Do not pierce or
burn, even after use. Do not spray on a naked flame or
incandescent material. Keep away from sources of
ignition. - Do not smoke.
National
regulations
VOC Content : Not applicable.
(Retail Use)
VOC Content :
(Industrial Use)
Hazard symbol(s):
Risk Phrases : R10- Flammable.
16.Other information
Full text of : R10-Flammable.
R-Phrases with no. R36-Irritaing to eyes.
appearing in R41-Risk of serious damage to eyes.
section 2 R65-Harmful may cause lung damage if swallowed.
United Kingdom R66-Repeated exposure may cause skin dryness or
(UK) cracking.
Text of : Xn - Harmful.
classifications Xi – Irritant.
appearing in
Section 2 -
United Kingdom
(UK)
HISTORY.
Date of printing : 24/05/2002.
Date of issue : 24/05/2002.
Date of Previous : 15/05/2002.
Issue
Prepared by :
Notice to Reader
To the best of our knowledge, the information contained herein is accurate.
However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
Version 1
7