Zibo Honors Chemical Co., Ltd
Add: Wutai Industrial Zone, Linzi Dist.Zibo, Shandong,China P.C:255420
Tel: +86-533-7167159 Fax: +86-533-7167159
E-mail:
MATERIAL SAFETY DATA SHEET OF MMA
Section 1 、MANUFACTURE AND PRODUCTS
a) Product
Chemical name: Methyl methacrylate
Synonyms: Methacrylic acid, methyl ester
b) Manufacturer
Name: Zibo Honors Chemical Co., Ltd
Address: Wutai, Linzi district, Zibo, Shandong, China
Tel: +86-533-7167159
Fax: +86-533-7167159 +86-533-7661437
Contact in emergency: Sales dept. of Zibo Honors Chemical Co., Ltd.
Tel: +86-533-7167159 Fax: +86-533-7167159
Section 2、PRODUCT INFOMATION
Product Name------Methyl methacrylate
Purity------99% min
Chemical Formula ----- C5H8O2;CH2C(CH3)COOCH3
Structural Formula ------
Molecular Weight------100.12
DENSITY: 0.936
CAS NO------80-62-6
Melting Point------48℃
Boiling Point-----100℃
Flash Point---- 10 ℃
UN Hazard Class-----3.2
UN NO.---1247
Section 3、DANGEROUS GOODS CAUTION
EMERGENCY OVERVIEW
Flammable (USA) Highly Flammable (EU). Irritant.
Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact.
Lachrymator. Target organ(s): Liver. Kidneys.
FLAMMABILITY: 3
REACTIVITY: 2
NFPA RATING
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 2
Section 4、FIRST AID MEASURES
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
In case of contact, immediately wash skin with soap and copious amounts of water.
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
Section 5、FIRE FIGHTING MEASURES
FLAMMABLE HAZARDS
Flammable Hazards: Yes
EXPLOSION HAZARDS
Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions.
FLASH POINT 48.2 °F 10°C
Method: closed cup
EXPLOSION LIMITS Lower: 2.12 % Upper: 12.5 %
AUTOIGNITION TEMP 435 °C
FLAMMABILITY N/A
EXTINGUISHING MEDIA : Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Flammable liquid. Emits toxic fumes under fire conditions.
Section 6、ACCIDENTAL RELEASE MEASURES
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is complete.
Section 7、HANDLING AND STORAGE
HANDLING
User Exposure: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep container closed. Keep away from heat, sparks, and open flame.
Store at 2-8°C
Section 8、EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Use only in a chemical fume hood.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Government approved respirator.
Hand: Wear heavy rubber gloves.
Eye: Chemical safety goggles.
Other: Faceshield (8-inch minimum).
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before reuse.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical State: Liquid
Color: Colorless
Property Value At Temperature or Pressure
Molecular Weight 100.12
BP/BP Range 98 - 100 °C
MP/MP Range -48 °C
Flash Point 10 °C Method: closed cup
Explosion Limits Lower: 2.12 % Upper: 12.5 %
Autoignition Temp 435 °C
Optical Rotation N/A
Solubility Solubility in Water:15 mg/ml H2O
Section 10、STABILITY AND REACTIVITY
STABILITY
Stable: Stable.
Conditions to Avoid: Heat. May polymerize on exposure to light.
Materials to Avoid: Oxidizing agents, Peroxides, Amines, Bases, Acids, Reducing agents, Halogens.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
STABILIZERS PRESENT
Methyl methacrylate is inhibited with 10 ppm hydroquinone
monomethyl ether. Do not store under inert atmosphere. It is advisable to use material within 6 months.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: May undergo autopolymerization
Section 11、PACKINGTRANSPORT INFORMATION
PROPER SHIPPING NAME: Methyl methacrylate
PRIMARY HAZARD CLASS/DIVISION: 3.2
UN/NA NUMBER: UN1247
PACKING GROUP: II
Handled with care to avoid leakage . And stored in dry ,cool place .
To be packaged with 200L PE drum or Iron drum(PVF inside).Net weight to be 180 kgs/drum, also can be packed in ISO-TANK(20mt net weight)