Zibo Honors Chemical Co., Ltd

Add: Wutai Industrial Zone, Linzi Dist.Zibo, Shandong,China P.C:255420

Tel: +86-533-7167159 Fax: +86-533-7167159

E-mail:

MATERIAL SAFETY DATA SHEET OF MMA

Section 1 、MANUFACTURE AND PRODUCTS

a) Product

Chemical name: Methyl methacrylate

Synonyms: Methacrylic acid, methyl ester

b) Manufacturer

Name: Zibo Honors Chemical Co., Ltd

Address: Wutai, Linzi district, Zibo, Shandong, China

Tel: +86-533-7167159

Fax: +86-533-7167159 +86-533-7661437

Contact in emergency: Sales dept. of Zibo Honors Chemical Co., Ltd.

Tel: +86-533-7167159 Fax: +86-533-7167159

Section 2、PRODUCT INFOMATION

Product Name------Methyl methacrylate

Purity------99% min

Chemical Formula ----- C5H8O2;CH2C(CH3)COOCH3

Structural Formula ------

Molecular Weight------100.12

DENSITY: 0.936

CAS NO------80-62-6

Melting Point------48℃

Boiling Point-----100℃

Flash Point---- 10 ℃

UN Hazard Class-----3.2

UN NO.---1247

Section 3、DANGEROUS GOODS CAUTION

EMERGENCY OVERVIEW

Flammable (USA) Highly Flammable (EU). Irritant.

Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact.

Lachrymator. Target organ(s): Liver. Kidneys.

FLAMMABILITY: 3

REACTIVITY: 2

NFPA RATING

HEALTH: 2

FLAMMABILITY: 3

REACTIVITY: 2

Section 4、FIRST AID MEASURES

If swallowed, wash out mouth with water provided person is conscious. Call a physician.

If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

In case of contact, immediately wash skin with soap and copious amounts of water.

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

Section 5、FIRE FIGHTING MEASURES

FLAMMABLE HAZARDS

Flammable Hazards: Yes

EXPLOSION HAZARDS

Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions.

FLASH POINT 48.2 °F 10°C

Method: closed cup

EXPLOSION LIMITS Lower: 2.12 % Upper: 12.5 %

AUTOIGNITION TEMP 435 °C

FLAMMABILITY N/A

EXTINGUISHING MEDIA : Suitable: Carbon dioxide, dry chemical powder, or appropriate

foam.

FIREFIGHTING

Protective Equipment: Wear self-contained breathing apparatus

and protective clothing to prevent contact with skin and eyes.

Specific Hazard(s): Flammable liquid. Emits toxic fumes under fire conditions.

Section 6、ACCIDENTAL RELEASE MEASURES

PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL

Evacuate area. Shut off all sources of ignition.

PROCEDURE(S) OF PERSONAL PRECAUTION(S)

Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves.

METHODS FOR CLEANING UP

Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors.

Ventilate area and wash spill site after material pickup is complete.

Section 7、HANDLING AND STORAGE

HANDLING

User Exposure: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.

STORAGE

Suitable: Keep container closed. Keep away from heat, sparks, and open flame.

Store at 2-8°C

Section 8、EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS

Safety shower and eye bath. Use nonsparking tools. Use only in a chemical fume hood.

PERSONAL PROTECTIVE EQUIPMENT

Respiratory: Government approved respirator.

Hand: Wear heavy rubber gloves.

Eye: Chemical safety goggles.

Other: Faceshield (8-inch minimum).

GENERAL HYGIENE MEASURES

Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Physical State: Liquid

Color: Colorless

Property Value At Temperature or Pressure

Molecular Weight 100.12

BP/BP Range 98 - 100 °C

MP/MP Range -48 °C

Flash Point 10 °C Method: closed cup

Explosion Limits Lower: 2.12 % Upper: 12.5 %

Autoignition Temp 435 °C

Optical Rotation N/A

Solubility Solubility in Water:15 mg/ml H2O

Section 10、STABILITY AND REACTIVITY

STABILITY

Stable: Stable.

Conditions to Avoid: Heat. May polymerize on exposure to light.

Materials to Avoid: Oxidizing agents, Peroxides, Amines, Bases, Acids, Reducing agents, Halogens.

HAZARDOUS DECOMPOSITION PRODUCTS

Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.

STABILIZERS PRESENT

Methyl methacrylate is inhibited with 10 ppm hydroquinone

monomethyl ether. Do not store under inert atmosphere. It is advisable to use material within 6 months.

HAZARDOUS POLYMERIZATION

Hazardous Polymerization: May undergo autopolymerization

Section 11、PACKINGTRANSPORT INFORMATION

PROPER SHIPPING NAME: Methyl methacrylate

PRIMARY HAZARD CLASS/DIVISION: 3.2

UN/NA NUMBER: UN1247

PACKING GROUP: II

Handled with care to avoid leakage . And stored in dry ,cool place .

To be packaged with 200L PE drum or Iron drum(PVF inside).Net weight to be 180 kgs/drum, also can be packed in ISO-TANK(20mt net weight)