1

Supplementary material

1)  Hench bioglass 45S5 MM (constant P) unit cell, fractional XYZ coordinates

O 0.80136 0.98229 0.54226

O 0.01164 0.88534 0.42708

O 0.25613 0.85108 0.52185

O 0.35827 0.56787 0.60173

O 0.93509 0.78985 0.14069

O 0.90445 0.42504 0.50484

O 0.12856 0.60156 0.10685

O 0.56705 0.47473 0.50772

O 0.65185 0.26359 0.26508

O 0.02097 0.41831 0.73940

O 0.23397 0.22916 0.85702

O 0.92257 0.89356 0.84411

O 0.80828 0.96563 0.28601

O 0.20841 0.35627 0.48581

O 0.51873 0.33079 0.06837

O 0.78066 0.75324 0.41147

O 0.64284 0.35617 0.86338

O 0.39640 0.94666 0.70807

O 0.47839 0.98068 0.47239

O 0.63776 0.79752 0.87494

O 0.60327 0.57593 0.00591

O 0.16739 0.04868 0.02402

O 0.93574 0.64238 0.93951

O 0.88316 0.53178 0.16664

O 0.43845 0.65143 0.38568

O 0.13385 0.66255 0.38271

O 0.94206 0.70783 0.67994

O 0.40115 0.29251 0.26470

O 0.53277 0.22213 0.68118

O 0.07798 0.30497 0.03440

O 0.82773 0.00918 0.04150

O 0.50230 0.09425 0.16015

O 0.55039 0.70431 0.59960

O 0.22651 0.88202 0.27821

O 0.08225 0.18417 0.34373

O 0.25829 0.10593 0.53202

O 0.67402 0.81210 0.12020

O 0.97412 0.14068 0.87776

O 0.79453 0.29411 0.68092

O 0.72386 0.09736 0.82109

O 0.43435 0.78059 0.01968

O 0.02649 0.21101 0.58498

O 0.14425 0.73294 0.84371

O 0.40513 0.48513 0.87693

Na 0.79205 0.19677 0.43675

Na 0.26134 0.10789 0.22342

Na 0.02758 0.98128 0.64597

Na 0.71505 0.49714 0.33030

Na 0.50432 0.24395 0.47066

Na 0.11393 0.57149 0.58096

Na 0.41003 0.04622 0.90609

Na 0.03339 0.03245 0.20471

Na 0.93150 0.58831 0.37432

Na 0.77195 0.60512 0.58565

Na 0.93167 0.30936 0.21489

Na 0.87269 0.41036 0.92892

Si 0.98206 0.73921 0.81753

Si 0.11930 0.18265 0.94556

Si 0.58918 0.74138 0.00373

Si 0.14275 0.21510 0.47790

Si 0.35641 0.97401 0.56397

Si 0.80363 0.89792 0.15131

Si 0.85770 0.03320 0.89257

Si 0.96995 0.63204 0.09700

Si 0.66772 0.24236 0.75289

Si 0.54067 0.43995 0.95197

Si 0.93794 0.34293 0.63278

Si 0.84585 0.89279 0.43017

Si 0.16073 0.81409 0.39965

P 0.47748 0.60104 0.52034

P 0.52174 0.24144 0.19099

Ca 0.48220 0.86763 0.27497

Ca 0.17179 0.48190 0.91216

Ca 0.21226 0.81878 0.05981

Ca 0.63666 0.90787 0.67527

Ca 0.32769 0.34506 0.68862

Ca 0.25234 0.48489 0.29630

Ca 0.37298 0.72268 0.78140

2)  Hench bioglass 45S5 MM (constant V) unit cell, fractional XYZ coordinates

O 0.80136 0.98229 0.54226

O 0.00568 0.88040 0.41646

O 0.24345 0.86003 0.51093

O 0.34585 0.57627 0.58672

O 0.92172 0.78618 0.13119

O 0.90673 0.41580 0.47632

O 0.11159 0.60596 0.08315

O 0.55354 0.48408 0.50060

O 0.63371 0.25703 0.25289

O 0.00341 0.42084 0.72640

O 0.22205 0.24385 0.82819

O 0.91584 0.89258 0.81763

O 0.80826 0.96971 0.28056

O 0.20384 0.35776 0.47338

O 0.50853 0.34517 0.05966

O 0.77173 0.75818 0.40426

O 0.63977 0.36159 0.85073

O 0.38137 0.95357 0.70236

O 0.46819 0.98614 0.45894

O 0.63070 0.80987 0.85968

O 0.59651 0.58755 0.98999

O 0.16644 0.05290 0.99194

O 0.92027 0.64884 0.91949

O 0.87391 0.52972 0.15208

O 0.43670 0.65045 0.36507

O 0.13043 0.66360 0.36940

O 0.93833 0.69949 0.65212

O 0.38970 0.29090 0.25993

O 0.53372 0.21323 0.67321

O 0.07169 0.29854 0.02436

O 0.82758 0.00247 0.02757

O 0.48151 0.10549 0.12860

O 0.53603 0.71488 0.58781

O 0.22547 0.87782 0.26081

O 0.08673 0.17965 0.32754

O 0.25396 0.11174 0.52363

O 0.66506 0.81852 0.11295

O 0.97065 0.13660 0.85719

O 0.78706 0.29124 0.65835

O 0.72175 0.10279 0.81402

O 0.42751 0.78053 0.01133

O 0.02098 0.21263 0.57066

O 0.13215 0.73833 0.82079

O 0.40566 0.48691 0.86063

Na 0.78487 0.18381 0.41471

Na 0.24342 0.09511 0.19819

Na 0.03298 0.99076 0.63431

Na 0.71516 0.48098 0.31623

Na 0.51100 0.23786 0.45814

Na 0.11443 0.56714 0.57129

Na 0.39821 0.05884 0.90064

Na 0.94424 0.15021 0.16779

Na 0.92265 0.60748 0.38521

Na 0.75398 0.60319 0.58440

Na 0.00102 0.37730 0.24993

Na 0.86904 0.40670 0.92945

Si 0.97348 0.74039 0.79340

Si 0.11363 0.18375 0.92207

Si 0.58157 0.74902 0.99140

Si 0.14419 0.21422 0.46577

Si 0.34394 0.98118 0.55414

Si 0.80223 0.89491 0.14284

Si 0.85241 0.02899 0.87120

Si 0.95655 0.63583 0.07992

Si 0.66634 0.24019 0.74419

Si 0.53687 0.44981 0.93794

Si 0.93210 0.34140 0.61253

Si 0.84461 0.89277 0.42508

Si 0.15114 0.81587 0.38503

P 0.46945 0.60870 0.50580

P 0.50585 0.24551 0.17602

Ca 0.46599 0.87109 0.25353

Ca 0.16679 0.47954 0.88973

Ca 0.20096 0.82787 0.03681

Ca 0.61522 0.92246 0.65910

Ca 0.34425 0.34901 0.66504

Ca 0.26213 0.49605 0.28598

Ca 0.36242 0.73105 0.77191

3)  Hench bioglass 45S5 B3LYP unit cell, fractional XYZ coordinates

O -2.133001817649E-01 -3.911949560437E-03 -4.954387672615E-01

O 3.295962332208E-03 -1.001257311501E-01 3.727158257756E-01

O 2.264680552039E-01 -1.229208107347E-01 -4.731791040597E-01

O 3.315272205461E-01 -4.204519029180E-01 -4.041539647358E-01

O -5.476966929017E-02 -2.155213219414E-01 1.115516377134E-01

O -1.351237417162E-01 4.577006947605E-01 4.912700296506E-01

O 1.424268289616E-01 -4.172383387737E-01 8.656188762479E-02

O -4.133967921112E-01 4.992712328032E-01 -3.592590704952E-01

O -3.050434231710E-01 3.125462868174E-01 1.434217574589E-01

O 6.738820301156E-02 4.119870587310E-01 -3.088234784393E-01

O 2.351485405704E-01 2.232074664667E-01 -1.487189589444E-01

O -1.659712260449E-01 -1.328502636361E-01 -1.945793679019E-01

O -2.309611040114E-01 -4.251988877468E-02 2.468928716132E-01

O 2.104321783365E-01 3.820984876763E-01 4.427316731586E-01

O 4.406595234307E-01 3.887583441613E-01 6.885721541240E-02

O -2.426193998924E-01 -2.442043612884E-01 3.975416821455E-01

O -4.114309295805E-01 3.297346916266E-01 -1.404014313700E-01

O 3.932815294535E-01 -2.789598464134E-02 -2.975754643658E-01

O 4.741773431967E-01 -1.867645938915E-02 4.578704982116E-01

O 4.188574141764E-01 -1.952019356429E-01 -6.429950545653E-02

O -4.137582650326E-01 -4.276507068357E-01 -4.167248808179E-02

O 1.756113922184E-01 3.601650900185E-02 2.970372308004E-02

O -7.032196239699E-02 -3.807628462673E-01 -8.999246562798E-02

O -1.257464845460E-01 -4.660618063392E-01 1.526772376171E-01

O -4.952076554903E-01 -4.239551995360E-01 4.123468151133E-01

O 1.559763119094E-01 -3.291147862911E-01 3.656509471808E-01

O -3.274838931127E-02 -2.967162189782E-01 -3.444897941728E-01

O 4.939256690404E-01 3.172445359668E-01 2.944222075004E-01

O -4.477261968726E-01 2.328296440304E-01 -3.857465420044E-01

O 9.799866776504E-03 2.700644816052E-01 -3.104494765491E-03

O -1.764596182902E-01 4.359086345552E-03 1.772765312037E-02

O 4.996393676817E-01 1.441584950703E-01 1.188059721938E-01

O -4.742452671169E-01 -2.635462834712E-01 -4.067476900913E-01

O 2.690798635305E-01 -1.191459372704E-01 2.707390060500E-01

O 1.105483107956E-01 1.978152601069E-01 2.894579323666E-01

O 2.508467875570E-01 1.402186279386E-01 -4.716270698307E-01

O -3.395863361509E-01 -2.077411102211E-01 7.892721101119E-02

O -4.087472524001E-03 7.734166297700E-02 -1.758203611865E-01

O -1.869538666146E-01 3.130638808475E-01 -2.927031860556E-01

O -2.952022136659E-01 9.742773552374E-02 -2.052771147727E-01

O 4.462394304884E-01 -3.308084438963E-01 1.615785880096E-01

O -4.626796737372E-03 2.286813306172E-01 -4.776418518337E-01

O 1.196001517561E-01 -2.121851660479E-01 -1.416841325821E-01

O 3.437130935565E-01 4.939881445925E-01 -1.596705679702E-01

NA -3.949880124069E-01 1.354784991843E-01 4.100918516752E-01

NA 3.018522744553E-01 9.162948067712E-02 2.151014256444E-01

NA 1.316151031897E-02 1.932027803997E-02 -4.037545270813E-01

NA -3.423967217730E-01 -4.716710029976E-01 2.236315637856E-01

NA -3.538286840702E-01 3.818196792733E-01 4.689152522655E-01

NA 1.070681842501E-01 -4.326735621146E-01 -4.529700633050E-01

NA 4.024211835088E-01 5.556209950050E-02 -8.453237979090E-02

NA 6.403019238665E-03 5.323938013718E-02 1.835537132289E-01

NA -6.872969454902E-02 -3.935169072662E-01 3.504455528728E-01

NA -2.292738507430E-01 -3.717874414844E-01 -4.104208372777E-01

NA -6.750448084404E-02 3.211560629194E-01 1.957120608648E-01

NA -2.000463575343E-01 4.004801553835E-01 -4.138013160842E-02

SI -2.863465009751E-02 -2.570564483389E-01 -1.976738491748E-01

SI 1.120369202698E-01 1.542147650079E-01 -6.930613301039E-02

SI -4.793571826368E-01 -2.896052727296E-01 2.832207534338E-02

SI 1.410714713339E-01 2.431261827648E-01 4.334875887822E-01

SI 3.412680072353E-01 -2.012050845926E-03 -4.470549051484E-01

SI -2.069770634883E-01 -1.213999104376E-01 1.121297886486E-01

SI -1.517242804668E-01 1.682286833276E-02 -1.381733928032E-01

SI -2.723303981149E-02 -3.763138458999E-01 7.117599372643E-02

SI -3.398130299412E-01 2.523216823718E-01 -2.667612661999E-01

SI 4.845473584983E-01 4.494704126935E-01 -7.826425536626E-02

SI -6.221849585549E-02 3.603437021889E-01 -3.953923230887E-01

SI -1.708143150051E-01 -1.053852537872E-01 3.941928207156E-01

SI 1.669296910827E-01 -1.743504213190E-01 3.797239656787E-01

P 4.865706675719E-01 -4.056918527500E-01 -4.386729896877E-01

P -4.596926734501E-01 2.789490979938E-01 1.567260768535E-01

CA -4.914158864363E-01 -2.026425755662E-01 3.405137234380E-01

CA 1.291953205612E-01 4.372885698634E-01 -9.520597857741E-02

CA 2.128523379533E-01 -1.905968380770E-01 6.411100696068E-02

CA -3.707794653968E-01 -6.847148942173E-02 -3.499394090316E-01

CA 3.173974680817E-01 3.366710142738E-01 -3.396210812218E-01

CA 3.091345695580E-01 -4.936760069855E-01 2.755655380869E-01

CA 3.155163483905E-01 -2.417043046435E-01 -2.643492262152E-01

4)  GULP input of the MM (constant V) Hench bioglass 45S5, in case of the constant P calculation, substitute the keyword conv with the keyword conp

opti conv prop distance

title

bioglass

end

cell

10.1000000000 10.1000000000 10.1000000000 90.000000 90.000000 90.000000

frac

O core 0.801364500000 0.982289150000 0.542257700000

O core 0.008023700000 0.875241250000 0.408132350000

O core 0.234937850000 0.861346550000 0.517697350000

O core 0.313511400000 0.580027800000 0.592552600000

O core 0.922698500000 0.783066550000 0.130825450000

O core 0.895887600000 0.406762450000 0.455393900000

O core 0.099219900000 0.604783850000 0.067516500000

O core 0.538735100000 0.483085450000 0.533353350000

O core 0.655861550000 0.256562700000 0.235524950000

O core 0.979255800000 0.418015200000 0.726704950000

O core 0.207931250000 0.240221750000 0.808507550000

O core 0.933070600000 0.906259700000 0.829936700000

O core 0.818390400000 0.978179450000 0.274860650000

O core 0.182588100000 0.343453500000 0.433573350000

O core 0.524644700000 0.311652250000 0.036400200000

O core 0.762909450000 0.782088050000 0.366154700000

O core 0.656350800000 0.367231050000 0.843831400000

O core 0.348052450000 0.954499750000 0.704395150000

O core 0.448153000000 0.007045200000 0.458622950000

O core 0.620439850000 0.792460150000 0.863694950000

O core 0.597836500000 0.576994450000 0.998336550000

O core 0.185425750000 0.060079900000 0.994716100000

O core 0.909390900000 0.654883050000 0.909978000000

O core 0.863890650000 0.519556500000 0.130238350000

O core 0.419972200000 0.637661450000 0.357837450000

O core 0.128085650000 0.659286300000 0.354412700000

O core 0.912424250000 0.716626400000 0.648620650000

O core 0.402359200000 0.283471450000 0.241004550000

O core 0.540105000000 0.191786000000 0.695392950000

O core 0.126226500000 0.299812400000 0.041781950000

O core 0.814574250000 0.990802100000 0.027006600000

O core 0.510162900000 0.078280000000 0.142371750000

O core 0.513391950000 0.729444750000 0.583452550000

O core 0.231708800000 0.866434750000 0.260672400000

O core 0.053621800000 0.158517000000 0.329950200000

O core 0.238460450000 0.114484500000 0.532766250000

O core 0.666625050000 0.804397850000 0.116637200000

O core 0.973286950000 0.148536300000 0.900290850000

O core 0.772694450000 0.286211250000 0.644217400000

O core 0.741186750000 0.112136100000 0.813204350000

O core 0.411067850000 0.761441700000 0.030431350000

O core 0.005675300000 0.210475350000 0.575037450000

O core 0.122410350000 0.726117850000 0.810855950000

O core 0.406566750000 0.472126250000 0.852735750000

Na core 0.814965650000 0.198146250000 0.399521550000

Na core 0.247169100000 0.103036050000 0.206072100000

Na core 0.049903500000 0.984441850000 0.638444250000

Na core 0.688739150000 0.509869350000 0.286700500000

Na core 0.559381450000 0.229751800000 0.446196000000

Na core 0.085031650000 0.571906250000 0.564567500000

Na core 0.412339900000 0.092663950000 0.868783150000

Na core 0.895496200000 0.191883850000 0.167812750000

Na core 0.908901650000 0.630714100000 0.391497850000

Na core 0.710266150000 0.616917250000 0.674942300000

Na core 0.026321650000 0.393944100000 0.252453000000

Na core 0.864379900000 0.399619400000 0.921720000000

Si core 0.967220250000 0.745002900000 0.788644000000

Si core 0.130238350000 0.188948350000 0.933266300000

Si core 0.584528900000 0.735120050000 0.002348400000

Si core 0.122312500000 0.205876400000 0.455491750000

Si core 0.324862000000 0.984833250000 0.557620150000

Si core 0.796178450000 0.886298300000 0.149319100000

Si core 0.865260550000 0.036302350000 0.886396150000

Si core 0.950977150000 0.637955000000 0.070060600000

Si core 0.673865950000 0.238754000000 0.755668550000

Si core 0.539909300000 0.432203450000 0.938941600000

Si core 0.915555450000 0.338561000000 0.608600000000

Si core 0.852148650000 0.904400550000 0.413122700000

Si core 0.152352450000 0.810268850000 0.378092400000

P core 0.436998100000 0.609774200000 0.516718850000

P core 0.527775900000 0.227403400000 0.165072950000

Ca core 0.467723000000 0.857823950000 0.266249850000

Ca core 0.157440650000 0.474768200000 0.869076700000

Ca core 0.183370900000 0.827784000000 0.036693750000

Ca core 0.605664500000 0.941290000000 0.665255150000

Ca core 0.338267450000 0.331124400000 0.637563600000

Ca core 0.259008950000 0.490815600000 0.239536800000

Ca core 0.367622450000 0.726607100000 0.784436450000

space

1

species 5

Si core 2.400000

P core 3.000000

O core -1.200000

Ca core 1.200000

Na core 0.600000

morse

O core Na core .23363000E-01 1.7639 3.00631 0.0000 0.000 5.500

morse

O core Ca core .30211000E-01 2.2413 2.92324 0.0000 0.000 5.500

morse

O core Si core .34055400 2.0067 2.10000 0.0000 0.000 5.500

morse

O core P core .83132600 2.5858 1.80079 0.0000 0.000 5.500

morse

O core O core .42395000E-01 1.3793 3.61870 0.0000 0.000 5.500

lennard 12 6

O core O core 100.00000 0.0000000 0.000 5.000

lennard 12 6

O core Si core 1.0000000 0.0000000 0.000 5.000

lennard 12 6

O core Ca core 5.0000000 0.0000000 0.000 5.000

lennard 12 6

O core Na core 5.0000000 0.0000000 0.000 5.000

lennard 12 6

O core P core 1.0000000 0.0000000 0.000 5.000

cutd 3.0

dump hench5_opti_conv5.5.res

output xtl hench5_opti_conv5.5_.xtl

5)  CRYSTAL input of the Hench bioglass 45S5

Henh Si13Ca7Na12P2O44 dens=2.7 g/cm3

CRYSTAL

0 0 0

1

9.41693623 10.23748789 10.34220117 88.715102 91.747106 86.015359

78

8 -2.133067085917E-01 -3.944059490382E-03 -4.954441893540E-01

8 3.291019871621E-03 -1.001291088537E-01 3.727317580487E-01

8 2.264825631147E-01 -1.228925393722E-01 -4.731933622500E-01

8 3.315393431085E-01 -4.204608035563E-01 -4.041399410440E-01

8 -5.477701677617E-02 -2.155124322651E-01 1.115695093236E-01

8 -1.351270179914E-01 4.576879298130E-01 4.912666618157E-01

8 1.424397861851E-01 -4.172318006899E-01 8.656212574543E-02

8 -4.134100003628E-01 4.992738725847E-01 -3.592685711268E-01

8 -3.050359308236E-01 3.125343460397E-01 1.433967902126E-01

8 6.738329337804E-02 4.119778076115E-01 -3.088383228109E-01

8 2.351531944587E-01 2.232141168403E-01 -1.487082166001E-01

8 -1.659666863229E-01 -1.328466112752E-01 -1.945790688431E-01

8 -2.309847409940E-01 -4.253510000786E-02 2.468923504366E-01

8 2.104306710304E-01 3.820954298446E-01 4.427461843184E-01

8 4.406583977100E-01 3.887683264236E-01 6.886078159481E-02

8 -2.426213094950E-01 -2.441653011419E-01 3.975415901112E-01

8 -4.114600071784E-01 3.297617955598E-01 -1.404089590562E-01

8 3.932865922849E-01 -2.788487395401E-02 -2.975772750354E-01

8 4.741559625777E-01 -1.868780371819E-02 4.578811123090E-01

8 4.188789367371E-01 -1.952217728945E-01 -6.430198047783E-02

8 -4.137752960589E-01 -4.276379703895E-01 -4.165631562164E-02

8 1.756081253529E-01 3.601759760341E-02 2.970668664853E-02

8 -7.033227898072E-02 -3.807546781094E-01 -8.999298973855E-02

8 -1.257537404929E-01 -4.660696996532E-01 1.526483261183E-01

8 -4.951996671388E-01 -4.239507871966E-01 4.123550006477E-01

8 1.559752092424E-01 -3.291221601752E-01 3.656412673959E-01

8 -3.274094079772E-02 -2.967183627266E-01 -3.444774414370E-01

8 4.939125299212E-01 3.172163055494E-01 2.944191631814E-01

8 -4.477307144889E-01 2.328218591427E-01 -3.857404016723E-01

8 9.801072332170E-03 2.700535214743E-01 -3.099643527176E-03

8 -1.764422862886E-01 4.365192263731E-03 1.769761650751E-02

8 4.996639400614E-01 1.441807124431E-01 1.187754423586E-01

8 -4.742623255048E-01 -2.635478475172E-01 -4.067462548472E-01

8 2.691082874695E-01 -1.191042348465E-01 2.707564180849E-01

8 1.105417828104E-01 1.978181019403E-01 2.894583647325E-01

8 2.508831255424E-01 1.402108161907E-01 -4.716350337628E-01

8 -3.395860472204E-01 -2.077346604882E-01 7.891109031747E-02

8 -4.125398157589E-03 7.733820759479E-02 -1.758057436249E-01

8 -1.869612957960E-01 3.130668781753E-01 -2.926972560759E-01

8 -2.951835724720E-01 9.740393621532E-02 -2.052639814927E-01

8 4.462171253807E-01 -3.308199190368E-01 1.615766706049E-01

8 -4.622112314234E-03 2.287213686864E-01 -4.776551715288E-01

8 1.195811267162E-01 -2.121896252754E-01 -1.417030444534E-01

8 3.437404875736E-01 4.939846912988E-01 -1.596714018583E-01

11 -3.949789314856E-01 1.354649798801E-01 4.101014739487E-01

11 3.018472928686E-01 9.159775326633E-02 2.151009492728E-01

11 1.317222056917E-02 1.929336581174E-02 -4.037295910655E-01

11 -3.423967632224E-01 -4.716724046693E-01 2.236388166534E-01

11 -3.538218034201E-01 3.818215597879E-01 4.689102051156E-01

11 1.070673898693E-01 -4.326655337095E-01 -4.529577728616E-01

11 4.024273945641E-01 5.555437374608E-02 -8.452766585720E-02

11 6.413665358810E-03 5.323905093999E-02 1.835543658308E-01

11 -6.874683138311E-02 -3.935210991651E-01 3.504448188121E-01

11 -2.292793193296E-01 -3.717828262601E-01 -4.104268870990E-01

11 -6.750433050941E-02 3.211550455363E-01 1.957094496367E-01

11 -2.000545802769E-01 4.004901857459E-01 -4.137819786054E-02

14 -2.864861175347E-02 -2.570535720017E-01 -1.976747268853E-01

14 1.120304408998E-01 1.541955057013E-01 -6.932241703623E-02

14 -4.793519671757E-01 -2.895989648197E-01 2.834782964872E-02

14 1.410940191293E-01 2.431282997096E-01 4.334790780132E-01

14 3.412804989216E-01 -2.028975271118E-03 -4.470608336666E-01

14 -2.069626365129E-01 -1.213822549236E-01 1.121231287065E-01

14 -1.517291758895E-01 1.682947848094E-02 -1.381649734105E-01

14 -2.724841098037E-02 -3.763214435892E-01 7.118353875073E-02

14 -3.398168554239E-01 2.523368385319E-01 -2.667578861289E-01

14 4.845769048117E-01 4.494717069696E-01 -7.828091770717E-02

14 -6.220331889592E-02 3.603414377606E-01 -3.953893869468E-01

14 -1.708046797060E-01 -1.053694881321E-01 3.941879892514E-01

14 1.669502712333E-01 -1.743626772495E-01 3.797277028613E-01

15 4.865767150080E-01 -4.056950763517E-01 -4.386743514455E-01

15 -4.597200812272E-01 2.789542101120E-01 1.567722513733E-01

220 -4.914122732528E-01 -2.026365330642E-01 3.405104887798E-01

220 1.291825730676E-01 4.372872366540E-01 -9.520973289721E-02

220 2.128502867353E-01 -1.905997078436E-01 6.411616894255E-02

220 -3.707842710856E-01 -6.846289444810E-02 -3.499491479942E-01

220 3.173889985346E-01 3.366695817369E-01 -3.396225261856E-01

220 3.091252811392E-01 -4.936693915292E-01 2.755617744839E-01

220 3.155079102082E-01 -2.417134780025E-01 -2.643606093234E-01

OPTGCOOR

BFGS

FRACTIOO

RENOSAED

FULLOPTG

MAXOPTC

1000

ENDOPT

ENDG

14 5

2 0 6 2.0 1.0

2 1 6 8.0 1.0

2 1 2 0.0 1.0

0 1 1 0.0 1.0

0.13 1. 1.

0 3 1 0. 1.

0.5 1.

11 4

0 0 8 2. 1.

56700. 0.000225

8060. 0.00191

1704. 0.01105

443.6 0.05006

133.1 0.1691

45.8 0.3658

17.75 0.3998

7.38 0.1494

0 1 5 8. 1.

119.0 -0.00673 0.00803

25.33 -0.0798 0.0639

7.80 -0.0793 0.2074

3.00 0.3056 0.3398

1.289 0.5639 0.3726

0 1 1 0. 1.

0.578 1. 1.

0 1 1 0. 1.

0.323 1. 1.

220 2

HAYWSC

0 1 3 8. 1.

5.3568 -1.4687 -0.0794

1.71 -1.8752 0.2902

1.0 3.4301 0.1427

0 1 1 0. 1.

0.500 1.0 1.0

8 4

0 0 6 2. 1.

5484.6717 0.0018

825.2349 0.0140

188.0470 0.0684

52.9645 0.2327

16.8976 0.4702

5.7996 0.3585

0 1 3 6. 1.

15.5396 -0.1108 0.0709

3.5999 -0.1480 0.3398

1.0138 1.1308 0.7272

0 1 1 2. 1.

0.2742 1. 1.

0 3 1 0. 1.

0.538 1.

15 5

0 0 8 2. 1.

202703. 0.0001

22413.1 0.0013

4625.08 0.0068

1312.41 0.0275

425.149 0.0951

146.409 0.2667

51.8363 0.4781

18.5913 0.2971

0 1 5 8. 1.

339.375 0.00089 0.00287

94.9248 -0.03549 0.02778

23.125 -0.153 0.172

6.9753 0.355 0.4215

2.275 0.9102 0.4109

0 1 2 0. 1.

1.219 -0.3715 0.09158

0.48105 1.271 0.9349

0 1 1 0. 1.

0.135 1. 1.

0 3 1 0. 1.

0.74583 1.

1 3

0 0 3 1. 1.00

0.1873113696D+02 0.3349460434D-01

0.2825394365D+01 0.2347269535D+00

0.6401216923D+00 0.8137573262D+00

0 0 1 0. 1.00

0.1612777588D+00 0.1000000000D+01

0 2 1 0. 1.

1.1 1.

99 0

ENDBS

DFT

LGRID

B3LYP

ENDDFT

SCFDIR

TOLINTEG

6 6 6 6 14

ENDM

2 0 2

LEVSHIFT

6 1

FMIXING

30

MAXCYCLE

100

END

1