SM Table 2C and N litter pool partitioning parameters PC and PN, i.e. the fraction of total C and N in the rapidly decomposing pool estimated by: measured as neutral detergent soluble C or N (NDS), kinetically-defined or optimized against mineralization data (OPT),or simple-linear (SLSCD), multiple-linear (MLSCD) and PLS regression (PLSNIR) models predicting the kinetically-defined litter pool partitioning. The regression models were based upon stepwise chemical digestion (SCD) or near infrared reflectance spectroscopy (NIR) data. For validation ‘OPT’ see main Table 1.

Carbon litter pool partitioning (PC) / Nitrogen litter pool partitioning (PN)
No / Common name / NDS / OPT / SLSCD / MLSCD / PLSNIR / NDS / OPT / SLSCD / MLSCD / PLSNIR
1 / Alfalfa GL / 0.42 / 0.44 / 0.51 / 0.53 / 0.57 / 0.92 / 0.58 / 0.56 / 0.55 / 0.78
2 / Barley GL / 0.26 / 0.52 / 0.41 / 0.50 / 0.44 / 0.82 / 0.48 / 0.54 / 0.49 / 0.47
3 / Barley spikes / 0.72 / 0.47 / 0.72 / 0.71 / 0.72 / 0.91 / 0.00 / 0.50 / 0.65 / 0.92
4 / Barley straw / 0.16 / 0.34 / 0.33 / 0.35 / 0.43 / 0.71 / 0.07 / 0.23 / 0.31 / 0.22
5 / Broad bean WP / 0.35 / 0.40 / 0.46 / 0.46 / 0.38 / 0.74 / 0.38 / 0.51 / 0.15 / 0.46
6 / Cabbage GL / 0.83 / 1.00 / 0.81 / 0.84 / 1.00 / 0.98 / 1.00 / 0.51 / 0.71 / 0.77
7 / Carrot GL / 0.78 / 0.84 / 0.76 / 0.77 / 0.80 / 0.91 / 0.64 / 0.57 / 0.60 / 0.57
8 / Cock's foot stem / 0.34 / 0.50 / 0.46 / 0.48 / 0.47 / 0.81 / 0.33 / 0.39 / 0.57 / 0.77
9 / Cock's foot WP / 0.41 / 0.52 / 0.51 / 0.55 / 0.53 / 0.79 / 0.45 / 0.57 / 0.52 / 0.70
10 / Crimson clover flower / 0.56 / 0.62 / 0.59 / 0.58 / 0.53 / 0.89 / 0.59 / 0.60 / 0.57 / 0.36
11 / Crimson clover GL / 0.77 / 0.81 / 0.74 / 0.74 / 0.76 / 0.92 / 0.74 / 0.60 / 0.64 / 0.53
12 / Egyptian clover WP / 0.65 / 0.51 / 0.66 / 0.64 / 0.61 / 0.89 / 0.28 / 0.58 / 0.55 / 0.67
13 / Elephant grass WP / 0.25 / 0.24 / 0.38 / 0.37 / 0.27 / 0.80 / 0.00 / 0.00 / 0.43 / 0.00
14 / Flax fibers / 0.27 / 0.31 / 0.40 / 0.40 / 0.36 / 0.87 / 0.28 / 0.45 / 0.40 / 0.41
15 / Flax GL / 0.68 / 0.53 / 0.67 / 0.63 / 0.74 / 0.84 / 0.13 / 0.56 / 0.47 / 0.33
16 / Flax oil / 0.49 / 0.49 / 0.53 / 0.45 / 0.43 / 0.90 / 0.47 / 0.52 / 0.47 / 0.23
17 / Flax stem 1 / 0.32 / 0.31 / 0.40 / 0.31 / 0.31 / 0.85 / 0.07 / 0.49 / 0.28 / 0.38
18 / Flax stem 2 / 0.22 / 0.36 / 0.37 / 0.38 / 0.43 / 0.83 / 0.05 / 0.31 / 0.38 / 0.26
19 / Flax stem 3 / 0.21 / 0.33 / 0.36 / 0.36 / 0.32 / 0.73 / 0.07 / 0.05 / 0.16 / 0.00
20 / Flax WP / 0.38 / 0.47 / 0.46 / 0.41 / 0.40 / 0.77 / 0.41 / 0.43 / 0.34 / 0.00
21 / Hemp GL / 0.77 / 0.72 / 0.73 / 0.71 / 0.76 / 0.91 / 0.32 / 0.59 / 0.50 / 0.46
22 / Hemp stem / 0.19 / 0.32 / 0.33 / 0.31 / 0.31 / 0.70 / 0.27 / 0.19 / 0.00 / 0.62
23 / Hemp straw / 0.28 / 0.40 / 0.41 / 0.41 / 0.41 / 0.74 / 0.59 / 0.15 / 0.10 / 0.85
24 / Leek GL / 0.77 / 1.00 / 0.76 / 0.81 / 0.79 / 0.98 / 0.49 / 0.60 / 0.67 / 0.59
25 / Maize GL / 0.41 / 0.55 / 0.49 / 0.49 / 0.50 / 0.66 / 0.67 / 0.57 / 0.46 / 0.72
26 / Maize spikes / 0.82 / 0.62 / 0.76 / 0.66 / 0.63 / 0.93 / 0.61 / 0.53 / 0.67 / 0.59
27 / Maize stem 1 / 0.40 / 0.34 / 0.49 / 0.49 / 0.44 / 0.88 / 0.27 / 0.45 / 0.60 / 0.16
28 / Maize stem 2 / 0.37 / 0.32 / 0.48 / 0.50 / 0.48 / 0.87 / 0.41 / 0.50 / 0.61 / 0.37
29 / Maize stem 3 / 0.32 / 0.61 / 0.44 / 0.43 / 0.46 / 0.79 / 1.00 / 0.39 / 0.59 / 0.25
30 / Maize WP / 0.31 / 0.37 / 0.43 / 0.42 / 0.51 / 0.64 / 0.57 / 0.37 / 0.35 / 0.24
31 / Oil radish GL / 0.71 / 0.79 / 0.74 / 0.85 / 0.81 / 0.92 / 0.58 / 0.60 / 0.64 / 0.58
32 / Onion GL / 0.71 / 0.65 / 0.69 / 0.64 / 0.62 / 0.81 / 0.16 / 0.55 / 0.45 / 0.10
33 / Pea WP 1 / 0.25 / 0.31 / 0.39 / 0.39 / 0.27 / 0.77 / 0.37 / 0.40 / 0.17 / 0.00
34 / Pea WP 2 / 0.26 / 0.31 / 0.38 / 0.35 / 0.38 / 0.68 / 0.73 / 0.34 / 0.13 / 0.16
35 / Persian clover WP / 0.53 / 0.63 / 0.58 / 0.58 / 0.48 / 0.88 / 0.69 / 0.55 / 0.52 / 0.39
No / Common name / NDS / OPT / SLSCD / MLSCD / PLSNIR / NDS / OPT / SLSCD / MLSCD / PLSNIR
36 / Phacelia GL / 0.74 / 0.73 / 0.73 / 0.77 / 0.77 / 0.88 / 0.51 / 0.59 / 0.59 / 0.41
37 / Rape GL / 0.81 / 0.99 / 0.79 / 0.91 / 0.86 / 0.98 / 0.75 / 0.62 / 0.69 / 0.54
38 / Rape spikes / 0.51 / 0.39 / 0.53 / 0.41 / 0.50 / 0.81 / 0.20 / 0.34 / 0.29 / 0.44
39 / Rape stem 1 / 0.23 / 0.36 / 0.38 / 0.37 / 0.39 / 0.65 / 0.56 / 0.07 / 0.03 / 0.59
40 / Rape WP / 0.76 / 0.76 / 0.73 / 0.76 / 0.77 / 0.97 / 0.72 / 0.62 / 0.67 / 0.59
41 / Red clover GL / 0.72 / 0.55 / 0.71 / 0.72 / 0.62 / 0.81 / 0.22 / 0.61 / 0.49 / 0.61
42 / Red clover stem / 0.46 / 0.48 / 0.54 / 0.54 / 0.54 / 0.87 / 0.51 / 0.51 / 0.43 / 0.68
43 / Ribbed melilot WP / 0.55 / 0.66 / 0.59 / 0.58 / 0.66 / 0.93 / 0.93 / 0.53 / 0.54 / 0.74
44 / Sugar beet GL 1 / 0.74 / 0.70 / 0.75 / 0.80 / 0.90 / 0.83 / 0.52 / 0.57 / 0.56 / 0.84
45 / Sunflower straw / 0.22 / 0.43 / 0.37 / 0.39 / 0.39 / 0.65 / 1.00 / 0.30 / 0.02 / 0.41
46 / Turnip rape GL / 0.80 / 0.88 / 0.78 / 0.90 / 0.91 / 0.90 / 0.67 / 0.62 / 0.63 / 0.63
47 / Turnip rape straw / 0.20 / 0.44 / 0.35 / 0.37 / 0.34 / 0.79 / 0.36 / 0.46 / 0.23 / 0.58
48 / WW ryegrass WP 1 / 0.39 / 0.57 / 0.49 / 0.49 / 0.55 / 0.87 / 0.74 / 0.45 / 0.55 / 0.66
49 / Wheat GL 1 / 0.30 / 0.50 / 0.42 / 0.43 / 0.42 / 0.76 / 0.24 / 0.44 / 0.42 / 0.34
50 / Wheat GL 2 / 0.10 / 0.43 / 0.30 / 0.37 / 0.53 / 0.67 / 0.00 / 0.04 / 0.24 / 0.00
51 / Wheat spikes 1 / 0.59 / 0.71 / 0.62 / 0.60 / 0.57 / 0.89 / 0.83 / 0.51 / 0.60 / 0.67
52 / Wheat spikes 2 / 0.71 / 0.75 / 0.70 / 0.66 / 0.59 / 0.90 / 0.86 / 0.50 / 0.63 / 0.50
53 / Wheat stem 1 / 0.42 / 0.60 / 0.50 / 0.49 / 0.57 / 0.71 / 0.57 / 0.38 / 0.43 / 0.93
54 / Wheat stem 2 / 0.23 / 0.29 / 0.35 / 0.31 / 0.27 / 0.66 / 0.00 / 0.00 / 0.27 / 0.00
55 / Wheat stem 3 / 0.37 / 0.55 / 0.46 / 0.43 / 0.44 / 0.88 / 0.37 / 0.39 / 0.55 / 0.51
56 / Wheat stem 4 / 0.47 / 0.48 / 0.54 / 0.50 / 0.56 / 0.85 / 0.00 / 0.00 / 0.52 / 0.00
57 / Wheat stem 5 / 0.17 / 0.37 / 0.33 / 0.32 / 0.27 / 0.73 / 0.00 / 0.05 / 0.25 / 0.23
58 / White clover WP 1 / 0.74 / 0.82 / 0.72 / 0.73 / 0.73 / 0.77 / 0.70 / 0.61 / 0.51 / 0.60
59 / Winter rye GL / 0.55 / 0.66 / 0.60 / 0.70 / 0.70 / 0.86 / 0.53 / 0.62 / 0.56 / 0.53
60 / Yellow mustard straw / 0.47 / 0.42 / 0.38 / 0.37 / 0.38 / 0.82 / 0.16 / 0.28 / 0.17 / 0.54
Validation data / NDS / ‘OPT’ / SLSCD / MLSCD / PLSNIR / NDS / ‘OPT’ / SLSCD / MLSCD / PLSNIR
1 / Barley stem 1 / 0.29 / 0.38 / 0.43 / 0.46 / 0.38 / 0.78 / 0.02 / 0.30 / 0.15 / 0.40
2 / Barley stem 2 / 0.16 / 0.25 / 0.32 / 0.30 / 0.23 / 0.65 / 0.35 / 0.00 / 0.00 / 0.00
3 / Maize stem 4 / 0.41 / 0.30 / 0.50 / 0.48 / 0.43 / 0.83 / 1.00 / 0.05 / 0.00 / 0.00
4 / Meadow foxtail WP / 0.30 / 0.21 / 0.44 / 0.48 / 0.40 / 0.73 / 0.09 / 0.40 / 0.23 / 0.05
5 / Nootka lupine GL / 0.53 / 0.62 / 0.58 / 0.57 / 0.55 / 0.82 / 0.82 / 0.55 / 0.43 / 0.36
6 / Oats WP / 0.47 / 0.68 / 0.54 / 0.52 / 0.52 / 0.89 / 0.43 / 0.33 / 0.25 / 0.56
7 / Rape stem 2 / 0.26 / 0.33 / 0.39 / 0.39 / 0.31 / 0.84 / 0.00 / 0.44 / 0.33 / 0.48
8 / Red clover WP / 0.59 / 0.56 / 0.62 / 0.61 / 0.56 / 0.89 / 0.50 / 0.54 / 0.46 / 0.59
9 / Red fescue straw / 0.25 / 0.36 / 0.40 / 0.44 / 0.36 / 0.83 / 0.15 / 0.45 / 0.34 / 0.21
10 / S. meadow grass straw / 0.31 / 0.43 / 0.44 / 0.49 / 0.46 / 0.82 / 0.25 / 0.48 / 0.36 / 0.24
11 / Sugar beet GL 2 / 0.73 / 0.99 / 0.76 / 0.84 / 0.83 / 0.90 / 0.96 / 0.54 / 0.47 / 0.80
12 / Swede WP / 0.33 / 0.58 / 0.45 / 0.47 / 0.48 / 0.87 / 0.53 / 0.48 / 0.39 / 0.67
13 / WW ryegrass WP 2 / 0.46 / 0.55 / 0.55 / 0.58 / 0.56 / 0.87 / 0.24 / 0.50 / 0.42 / 0.60
14 / White clover WP 2 / 0.74 / 0.81 / 0.72 / 0.74 / 0.67 / 0.77 / 0.65 / 0.61 / 0.46 / 0.53
15 / Yellow lupine stem / 0.42 / 0.64 / 0.51 / 0.52 / 0.55 / 0.86 / 0.58 / 0.50 / 0.41 / 0.65