Online resource OR1.Enzyme mapping of cell wall polysaccharides in developing and mature caryopses of wheat cv. Hereward, determined by HPAEC. Peak areas are given for arabinoxylan oligosaccharides (AXOS) (X, XX, XA3X, XA2+3XX, XA3XA3XX, XA3A2+3XX, XA3XA2+3XX), β-glucan oligosaccharides (G3, G4) that were used for principal component analysis (Fig. 3).

Sample / X1 / X2 / G3 / G4 / XA3X / XA3XX / XA2+3XX / XA3A3XX / XA3XA3XX / XA3A2+3XX / XA2+3A2+3XX
10.1.1 / 50709.5 / 90538.3 / 202240.8 / 87016.1 / 13048.3 / 43669.3 / 12369.7 / 21147.6 / 18632.8 / 24233.3 / 7022.5
10.1.2 / 48402.1 / 73748.7 / 181482.1 / 74248.7 / 10879.8 / 36669.7 / 10376.3 / 16958 / 12506.5 / 19673.3 / 5824.5
10.2.1 / 29310.5 / 33604.6 / 102163.8 / 37744.5 / 3701 / 14617.4 / 5831.1 / 8595.9 / 7150.6 / 13129.2 / 2927.3
10.2.2 / 58313.9 / 76544.3 / 194687.1 / 78677.5 / 9665.7 / 33158.2 / 11092.4 / 20490.3 / 16758.4 / 31558.5 / 9026.4
12.1.1 / 42442.9 / 102503.8 / 183171 / 75735.6 / 13736.6 / 54475.7 / 15912.8 / 21746.4 / 18310.4 / 24739.5 / 6804.9
12.1.2 / 59566.8 / 115169 / 190030.1 / 81652.2 / 13143.8 / 55744 / 14366.2 / 20479.6 / 19719.2 / 22761.4 / 7197.8
12.2.1 / 34847.9 / 73933.4 / 102434.6 / 40325.7 / 5850.3 / 29983.2 / 8707.3 / 11036.5 / 8089.2 / 15995.4 / 1352.1
12.2.2 / 89242.7 / 174147.2 / 196256.7 / 83981.3 / 13485.9 / 67084.1 / 19870.4 / 26725 / 23970.7 / 35741.5 / 9126.1
14.1.1 / 120987.6 / 298046.1 / 182865.3 / 81674.3 / 14945.5 / 102243.3 / 31423.5 / 30347.1 / 21313 / 29566.3 / 10495.7
14.1.2 / 110980.3 / 278284.8 / 175912.1 / 76432.1 / 13722.2 / 96143.4 / 30217.3 / 27488.3 / 18635.1 / 26503.1 / 10431.6
14.2.1 / 104031.3 / 254611.4 / 166472.7 / 72008.5 / 13794.5 / 87756.9 / 26374.3 / 24289.3 / 19205.3 / 24362.8 / 8619
14.2.2 / 94376.8 / 239977.4 / 161095.9 / 66953.6 / 12172.5 / 80629.3 / 25581.8 / 23827.5 / 16863.3 / 6491.9 / 8384.4
17.1.1 / 140811.5 / 361142.9 / 171141.6 / 74114.3 / 12051.7 / 109894.8 / 44608 / 28879.8 / 17290.7 / 11568.8 / 11899.3
17.1.2 / 137340.9 / 344928.2 / 161339.9 / 68748.2 / 12446.8 / 100213.7 / 43247.6 / 27391.4 / 15409.3 / 10390.8 / 10956.9
17.2.1 / 112052.5 / 315281.9 / 140410.3 / 57848.9 / 10507.1 / 84935 / 34233.9 / 23115 / 12689.8 / 10081.8 / 8625.3
17.2.2 / 109529.3 / 311169.8 / 136672.2 / 56451.3 / 9732.7 / 81717.9 / 33646.3 / 21325.8 / 11749.5 / 9943.8 / 8080.1
21.1.1 / 128198.9 / 358862.1 / 155594 / 66723.4 / 11559.3 / 97733.8 / 48166.3 / 26092.6 / 13120.9 / 18017.6 / 12480.6
21.1.2 / 122252.5 / 345801.9 / 145463 / 62405.5 / 10468.8 / 91894.6 / 44604.3 / 24231.1 / 12190.8 / 15177.8 / 11509.5
21.2.1 / 109031.8 / 307883.3 / 123246.6 / 50584.8 / 8135.4 / 73117.5 / 36264.7 / 18995.7 / 10096.1 / 12837.8 / 8592.3
21.2.2 / 97314.6 / 310526.8 / 124053.7 / 50721.6 / 8383 / 73462.4 / 35325.7 / 19674 / 10012.7 / 13100.6 / 9068.6
28.1.1 / 102412.6 / 334882.8 / 136755.1 / 56914.1 / 10906.6 / 94507.5 / 41228.4 / 25857.1 / 10599.2 / 19442.8 / 9725.9
28.1.2 / 95931.8 / 319251.9 / 128464.3 / 54276.9 / 10371.6 / 88740.5 / 40417.6 / 23877.1 / 9928.8 / 17358.6 / 8676.3
28.2.1 / 94296.9 / 318127.6 / 116439 / 47145.2 / 9317.7 / 79911.7 / 35496.9 / 21446.5 / 9698.2 / 18152.5 / 9441.3
28.2.2 / 80739 / 300281.5 / 115097 / 46209.7 / 9330.2 / 78012.4 / 36773.3 / 20973.5 / 9150.3 / 17591.4 / 9674
35.1.1 / 81051.6 / 299434.2 / 135048.6 / 57156.3 / 11232.1 / 89165.7 / 39067.2 / 27199.2 / 10329.7 / 18897.8 / 9456.5
35.1.2 / 67630 / 230285.4 / 111599.4 / 46922.7 / 9085.7 / 71763.9 / 30036 / 21632.6 / 8548.7 / 15386.2 / 7832.3
35.2.1 / 77320.9 / 257067.5 / 120585.9 / 46694.8 / 7581.5 / 71449.2 / 30328.2 / 22512 / 8814 / 16989.7 / 7386.8
35.2.2 / 77307.4 / 260432.5 / 123164.5 / 49947 / 11199.8 / 76564.2 / 32216.5 / 23243.7 / 9258.9 / 17461.1 / 7621.2
42.1.1 / 62768.7 / 229136.7 / 129037.9 / 54635.6 / 10029.2 / 77161.9 / 29989.5 / 25761 / 9284.5 / 16559.9 / 7155.8
42.1.2 / 62516.8 / 221508.5 / 125087.8 / 52850.7 / 10536 / 75227.9 / 27891.5 / 24361.7 / 8002.9 / 15492.4 / 6823
42.2.1 / 66809.1 / 224738.4 / 124812 / 49868.2 / 7896.2 / 72996.1 / 27984.9 / 25471 / 8766.5 / 16120.5 / 6803.3
42.2.2 / 62504.4 / 205293.9 / 115860.8 / 44329.9 / 6979.6 / 65682.3 / 25341.1 / 22495 / 7681.3 / 14574.5 / 6182.4
M1.1 / 60604.9 / 220689.5 / 126052.8 / 53169.3 / 10174.5 / 78689.8 / 29534.5 / 26384.6 / 10492.5 / 18209.6 / 7816.4
M1.2 / 65129.6 / 246419.8 / 136927.4 / 56712.6 / 10821 / 85585 / 33604.2 / 29449.6 / 12374.4 / 20261.2 / 8663.9
M2.1 / 57759 / 176360.4 / 102689.9 / 37972.8 / 8183.1 / 60381.5 / 21230.8 / 19836.6 / 7545.5 / 15213.2 / 5119.3
M2.2 / 62201.9 / 195173.5 / 116322.1 / 42770.6 / 6878.3 / 67579.8 / 26297.7 / 23815.5 / 8859.5 / 16649.6 / 6548.1