Olin Corp Pulsar Plus Dry Chlorinator Briquettes, Cpe00164 6580-00N069168
OLIN CORP -- PULSAR PLUS DRY CHLORINATOR BRIQUETTES, CPE00164 -- 6580-00N069168
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MSDS Safety Information
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FSC: 6580
MSDS Date: 04/14/1994
MSDS Num: CDMDZ
LIIN: 00N069168
Tech Review: 04/04/1997
Product ID: PULSAR PLUS DRY CHLORINATOR BRIQUETTES, CPE00164
Responsible Party
Cage: 8X135
Name: OLIN CORP
Address: 120 LONG RIDGE RD
City: STAMFORD CT 06904 US
Info Phone Number: 203-356-3449
Emergency Phone Number: 203-356-3449
Review Ind: N
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Contractor Summary
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Cage: 8X135
Name: OLIN CORP
Address: 51 CORPORATE WOODS 9393 W 110 ST
City: OVERLAND PARK KS 66210 US
Phone: 800-432-6546
Cage: 99530
Name: OLIN CORPORATION
Address: 501 MERRITT 7
Box: 4500
City: NORWALK CT 06856-4500 US
Phone: 203-750-3000/800-511-MSDS
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE) (CERCLA)
% by Wt: 65-75
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5 PPM; 1 STEL (CL)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
Ozone Depleting Chemical: N
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Cas: 7647-14-5
RTECS #: VZ4725000
Name: SODIUM CHLORIDE
% by Wt: 10-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 10137-74-3
RTECS #: FN9800000
Name: CALCIUM CHLORATE
% by Wt: 0-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 10043-52-4
RTECS #: EV9800000
Name: CALCIUM CHLORIDE
% by Wt: 0-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 1305-62-0
RTECS #: EW2800000
Name: CALCIUM HYDROXIDE
% by Wt: 0-4
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 5 MG/M3
Ozone Depleting Chemical: N
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Cas: 471-34-1
RTECS #: FF9335000
Name: CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE)
% by Wt: 0-4
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Cas: 40372-66-5
Name: 2-PHOSPHONO-1,2,4-TRICARBOXYLIC ACID, SODIUM SALT
% by Wt: 0.2-0.8
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% by Wt: 0-5.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Ozone Depleting Chemical: N
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Name: SUPDAT: EXCEPT FOR EFFECTS SECONDARY TO TISSUE DESTRUCTION.
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Name: FIRST AID PROC: FRESH AIR. SUPPORT RESPIRATION IF NEEDED. CALL MD.
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Name: SPILL PROC: FUME SUPPRESSION, DECONTAM OR FIRE SUPPRESSION MAY BE
CONTAMD & MUST BE CONTAINED BEFORE DISP. WATER(ING 12)
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Name: ING 11: RELS: THIS MATL IS HEAVIER THAN WATER. MATL IS SOLUBLE IN
WATER. MONITOR ALL EXIT WATER FOR AVAIL (ING 13)
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Name: ING 12: CHLORINE & PH. ADVISE LOC AUTHS OF ANY CONTAMD WATER RELS.
LAND SPILL: CONTAINERIZE ALL VIRGIN MATL IN (ING 14)
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Name: ING 13: CLEAN DRY CNTNR USING ONLY DEDICATED EQUIP TO CLEAN MATL UP.
CONTAINERIZE ALL CONTAMD MATL IN CLEAN DRY (ING 15)
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Name: ING 14: CNTNR & REMOVE TO WELL VENTD AREA BEING SURE TO NOT SEAL
TIGHTLY. CONTAMD SPILL MATL MAY BECOME HAZ (ING 15)
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Name: ING 15: WASTE. SPILL RESIDUES:DISPOSE OF PER GUIDELINES UNDER WASTE
DISPOSAL. MATL MAY BE NEUT FOR DISP; YOU ARE(ING 17)
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Name: ING 16:REQUESTED TO CNTCT OCEAN @ 800-OLIN-911 BEFORE BEGINNING ANY
SUCH OPERATION. FOR A SPILL OF THIS MATL NO (ING 18)
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Name: ING 17: EXTRA PROTECTION BEYOND THAT LISTED IN PERSONAL PROTECTION
SECTION IS REQUIRED.
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Name: WASTE DISP METH: MANAGED ACCORDINGLY. AS HAZ SOLID WASTE, IT MUST BE
DISPOSED OF I/A/W LOCAL, STATE & FED REGS (ING 20)
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Name: ING 19:IN PERMITTED HAZ WASTE TREATMENT, STOR & DISP FACILITY BY
TREATMENT. CARE MUST BE TAKEN TO PVNT (ING 21)
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Name: ING 20: ENVIRONMENTAL CONTAM FROM USE OF THIS MATL. USER OF MATL HAS
RESPONSIBILITY TO DISPOSE OF UNUSED MATL, (ING 22)
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Name: ING 21:RESIDUES & CNTNRS IN COMPLIANCE W/ALL RELEVANT LOCAL, STATE &
FED LAWS & REGS REGARDING TREATMENT, STOR (ING 23)
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Name: ING 22: & DISPOSAL FOR HAZARDOUS & NONHAZARDOUS WASTE.
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Name: EYE PROT: & FULL LENGTH FACESHIELD (PF N).
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL, RAT) 850 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: PROD HAS POTNTL TO BE IMMED DANGEROUS TO LIFE/HLTH.
INHAL: MATL IS IRRIT TO NOSE, MOUTH, THROAT & LUNGS, IT MAY ALSO CAUSE
BURNS TO RESP TRACT W/PRODUCTION OF LUNG EDEMA WHICH CAN RSLT IN
SHORTNESS OFBRTH, WHEEZ, CHOKING, CHEST PAIN & IMPAIRMENT OF LUNG
FUNC. INHAL OF HIGH CONCS CAN RSLT IN PERM LUNG (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:DMG. EYE:SEV IRRIT &/OR
BURNS CAN OCCUR FOLLOWING EXPOS. CNTCT MAY CAUSE IMPAIRMENT OF VISION &
CORNEAL DMG. SKIN:SEV IRRIT &/OR BURNS CHARACT BY REDNESS, SWELL & SCAB
FORM. PRLNGD SKIN EXPOS MAY CAUSE DESTRUCTION OF DERMIS W/IMPAIRMENT OF
SKIN AT SITE OF CNTCT TO REGNERATE. INGEST:IRRIT &/OR BURNS TO (SUPDAT)
Medical Cond Aggravated By Exposure: ASTHMA, RESPIRATORY AND
CARDIOVASCULAR DISEASE.
First Aid: EYES:IMMED FLUSH W/LG AMTS OF WATER FOR AT LST 15 MIN, OCCASNLY
LIFTING UPPER & LOWER LIDS. CALL MD AT ONCE. SKIN:IMMED FLUSH W/WATER
FOR AT LST 15 MIN. CALL MD. IF CLTHG COMES IN CNTCT W/PROD, REMOVE
IMMED & LAUNDER BEFORE REUSE. INGEST: IMMED DRINK LG QTYS OF WATER. DO
NOT INDUCE VOMIT. CALL MD AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF
PERSON IS UNCON OR HAVING CONVLS. INHAL:REMOVE TO (ING 10)
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Handling and Disposal
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Spill Release Procedures: HAZ CONCS IN AIR MAY BE FOUND IN LOCAL SPILL
AREA & IMMED DOWNWIND. REMOVE ALL SOURCES OF IGNIT. STOP SOURCE OF SPILL
AS SOON AS POSS & NOTIFY APPROP PERS. AIR RELS:VAPS MAY BE SUPPRESSED BY
USE OF WA TER FOG. ALL WATER UTILIZED TO ASSIST IN (ING 11)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: IF PROD BECOMES A WASTE, IT MEETS CRITERIA OF HAZ
WASTE AS DEFINED UNDER 40 CFR 261 & WOULD HAVE EPA HAZ WASTE
NUMBER:D001. IF PROD BECOMES HAZ WASTE, IT WILL BE HAZ WASTE WHICH IS
SUBJECT TO LAND DIS P RESTRICTIONS UNDER 40 CFR 268 & MUST BE (ING 19)
Handling And Storage Precautions: KEEP TIGHTLY SEALED. STORE IN A CLEAN,
DRY WELL-VENTD AREA. DO NOT STORE ABOVE 52C(125F). SHELF LIFE: APPROX 2
YRS AT TEMPS >52C(125F) & LOW HUMIDITY.
Other Precautions: CNTNRS MUST BE CLEAN & FREE OF ORG RESIDUES. INCOMPAT
MATLS FOR STOR/TRNASPORT: ACIDS, OTHER OXIDIZERS, ORG MATLS, ALL CORR
LIQ. DO NOT TAKE INTERNALLY. AVOID CONTACT W/EYES, SKIN OR CLTHG. UPON
CONTA CT W/SKIN OR EYES, WASH OFF W/WATER.
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Fire and Explosion Hazard Information
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Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIPMENT (FP
N). USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. DO NOT USE DRY
EXTINGUISHERS CONTAINING AMMONIUM COMPOUNDS.
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
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Control Measures
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Respiratory Protection: WEAR A NIOSH APPROVED CHLORINE CARTRIDGE WITH
DUST/MIST PREFILTER.
Ventilation: USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST LEVELS AND
CHLORINE GAS.
Protective Gloves: NEOPRENE OR PVC GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (ING 24)
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
WEAR NEOPRENE/PVC BOOTS, NEOPRENE APRON OR SUIT TO AVOID SKIN & EYE
CNTCT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PH: 10.5-11.5 @ 25C (1% SOLN). MATL TO
AVOID: FLAM OR COMBUST MATLS. EFTS OF OVEREXP: ENTIRE GI TRACT, INCL
STOM & INTSTINES, CHARACT BY NAUS, VOMIT, DIARR, ABDOM PAIN, BLEEDING
&/OR TISS ULCERATION. CHRONIC: INHAL:MAY CAUSE IMPAIRMENT OF LUNG FUNC
& PERM LUNG DMG. EYES:EFTS SIMILAR TO THOSE FROM SINGLE EXPOS (ING 9)
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Physical/Chemical Properties
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Decomp Text: 351F,177C
PH: SUPDAT
Solubility in Water: 18% @ 25C
Appearance and Odor: WHITE, FREE FLOWING GRANULES OR TABLET-FORM PRODUCT;
CHLORINE-LIKE ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES >125F, HIGH HUMIDITY.
Materials To Avoid: ACIDS, ORGANICS, NITROGEN CONTAINING CMPDS, DRY PWDR
FIRE EXTINGS (CONTAINING MONO-AMMOUNIUM PHOSPHATES), CORR, (SUPDAT)
Hazardous Decomposition Products: CHLORINE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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Product ID: PULSAR PLUS DRY CHLORINATOR BRIQUETTES, CPE00164
Cage: 8X135
Company Name: OLIN CORP
Street: 51 CORPORATE WOODS 9393 W 110 ST
City: OVERLAND PARK KS
Zipcode: 66210 US
Health Emergency Phone: 203-356-3449
Date Of Label Review: 02/18/1997
Label Date: 02/18/1997
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: IRRITANT. OXIDIZER. ACUTE:INHALATION: IRRITATION
TO NOSE, MOUTH, THROAT AND LUNGS. BURNS TO RESPIRATORY TRACT CAUSING
EDEMA W/SHORTNESS OF BREATH, WHEEZING, CHOKING, CHEST PAIN AND LUNG
FUNCTION IMPAI RMENT. PERMANENT LUNG DAMAGE. EYES: SEVERE IRRITATION
AND/OR BURNS; IMPAIRMENT OF VISION AND CORNEAL DAMAGE. SKIN: SEVERE
IRRITATION AND/OR BURNS W/REDNESS, SWELLING AND SCAB FORMATION. MAY
CAUSE DEST RUCTION OF DERMIS WITH IMPAIRMENT OF SKIN TO REGENERATE.
INGESTION: IRRITATION AND/OR BURNS TO GI TRACT WITH NAUSEA, VOMITING,
DIARRHEA, ABDOMINAL PAIN, BLEEDING AND/OR TISSUE ULCERATION. CHRONIC:
IMP AIRMENT OF LUNG FUNCTION & PERMANENT LUNG DAMAGE.
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