How to Prepare the Abstract: the Title(14 Pt, Bold, Left Aligned)

How to Prepare the Abstract: the Title(14 Pt, Bold, Left Aligned)

How to prepare the abstract: The Title(14 pt, bold, left aligned)

(one line blank)

Presenting Author,aSecond Author,bMain Author*,a(12 pt, normal, left aligned)

aAffiliation 1, City, Country; bAffiliation 2, City, Country(12 pt, italics, left aligned)

e-mail address (12 pt, normal, left aligned)

(one line blank)

To prepare your abstract, please use thetemplate following theseguidelines:

(1) The presenting author's name should beunderlined and the main author's name should be markedwith anasterisk.

(2) Please add an e-mail address of the presenting or main author.

(3) The abstract in Englishshouldnot exceedone page of A4format (297× 210 mm) in portrait layout with all margins equal to 25 mm.

(4) The single spaced text should be typed preferably in normalTimes New Roman font being left and right justified. Please use 12 pt font size for the main body of text since the abstracts may be reducedin the printed version of Book of Abstracts.

(5) All text, equations, figures, schemes, acknowledgment and references should be integrated in the abstract. Please do not provide separate graphics files. All abstracts will be printed in black and white.

(6) The doc, docx, or pdf file formats of the abstractare acceptable.

(7) Please send your abstract file as an e-mail attachment . Hard copies will not be accepted.

1)Hutchings, L. R.; Roberts-Bleming, S. J. Macromolecules 2006, 39, 2144

2)Clarke, N.; De Luca, E.; Dodds, J. M.; Kimani, S. M.; Hutchings, L. R. European Polymer Journal2008, 44, 665

See example below

DendriMacs, HyperMacs and HyperBlocks – The Advantages of the Macromonomer Approach

Lian R. Hutchings*,a Solomon Kimania, Serena Agostinia

aDurham Centre for Soft Matter, Durham University, Durham, DH1 3LE, United Kingdom

e-mail address

The synthesis and characterisation of hierachically branched polymers continues to be an area of intense research. In recent years we have reported new strategies for the synthesis of two classes highly branched polymers, DendriMacs1 and HyperMacs2,3. These materials are essentially long chain branched analogues of classical dendrimers and hyperbranched polymers and the synthetic strategy involves two steps. The synthesis by anionic polymerization of well-defined AB2 macromonomers which can then be built up into highly branched architectures either via a one-pot polycondensation reaction to give imperfectly, long-chain (hyper)branched architectures, HyperMacs, or via a step wise convergent coupling method to yield well defined dendritically branched polymers, DendriMacs.

The macromonomer approach is not the only strategy that has been exploited to make polymers with the same or similar branched archtiectures but the use of macromonomers offers a wide range of advantages over alternative methods. We will discuss two key advantages in this paper; firstly the ability to completely characterise model branched polymers (DendriMacs) which is absolutely vital for their use in stucture-property correlation studies. Secondly we will discuss the synthesis of HyperMacs from block copolymeric macromonomers to yield HyperBlocks4 – a strategy that has recently been adopted and modified by a number of other groups5 around the world.


Figure 1. Structure and microphase separated morphologies of linear macromonomer and the branched HyperBlock created from coupling the macromonomer4

References

3)Hutchings, L. R.; Roberts-Bleming, S. J. Macromolecules 2006, 39, 2144

4)Clarke, N.; De Luca, E.; Dodds, J. M.; Kimani, S. M.; Hutchings, L. R. European Polymer Journal2008, 44, 665

5)Hutchings, L. R. Soft Matter.2008, 4, 2150

6)Hutchings, L. R.; Dodds, J. M.; Rees, D.; Kimani, S. M.; Wu, J. J.; Smith, E. Macromolecules2009, 42, 8675

7)Konkolewicz, D.; Poon, C. K.; Gray-Weale, A.; Perrier, S. Chem. Commun.2011, 47, 239