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Safety Data Sheet according to 91/155/EEC - ISO 11014-1
Toiletcare 64
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1. Identification of the product and of the company
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Identification of the product:
Toiletcare 64
Toilet Cleaner for professional use
Company/undertaking identification:
Ecolab Ltd
David Murray John Building
Swindon
Wiltshire SN1 1NH
Telephone: 01793 511221
2. Composition/information on ingredients
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Declaration according recommendation 89/542/EEC:
Further ingredients:
Phosphoric Acid, Amine oxide, Solubilizer, Dye and Fragrance
Declaration of ingredients:
> 30 % Phosphoric Acid
Symbol: C
R-phrase: R34
EINECS: 231-633-2
1-5 % Amine oxide
Symbol: Xi
R-phrase: 22-38-41-51/53
EINECS: 263-179-6
< 1 % Amine oxide
Symbol: Xi
R-phrase: 22-38-41-50
EINECS: 287-011-6
3. Hazards identification of the product
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C Corrosive
R 34: Causes burns
R 52/53 Harmful to aquatic organisms, may cause long- term adverse
effects in the aquatic environment.
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4. First aid measures
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In case of an accident, show physician label or safety data sheet
after inhalation:
not relevant
after skin contact:
Rinse with running water, remove contaminated clothes, if
necessary, see a dermatologist.
after eye contact:
Immediately flush eyes with copious amounts of running water
(for 10 minutes), see an oculist.
after ingestion:
Rinse out mouth, drink 1-2 glasses of water, seek medical
advice.
Do not initiate vomiting; instantly call for medical help.
5. Fire-fighting measures
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Suitable extinguishing media:
Water or Foam
Extinguishing media which must not be used for safety reasons:
none known
Special exposure hazards arising from the product itself,
from combustion products or from resulting gases:
none known
Special protective equipment for firefighters:
Wear protective equipment.
(see point 8)
6. Accidental release measures
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Personal precautions:
Wear protective equipment.
(see point 8) Avoid contact with skin and eyes.
Environmental precautions:
Do not allow large amounts to be released into the sewer system.
Methods of cleaning up/of removing:
neutralise with caustic
wash away residue with plenty of water;
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Safety Data Sheet according to 91/155/EEC - ISO 11014-1
Toiletcare 64
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7. Handling and storage
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Handling:
Extract product from the supply container using only
the dispensing aids recommended by Ecolab.
Storage:
Store only in the original container.
8. Exposure controls / personal protection
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Components with specific control parameters:
Phosphoric acid: CAS No. 7664-38-2
OES: 1mg/m3 (8 hours) 2mg/m3 (15 mins.)
Personal protection:
Hand protection:
Wear Category III (EN 374) chemical protective gloves made
of butyl rubber or nitrile rubber. Please observe the glove
manufacturer's instructions on permeability and rupture times as well as the specific workplace conditions.
Eye protection: goggles which can be tightly sealed
Skin protection: suitable protective clothing
9. Physical and chemical properties
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Physical state: liquid
Colour: blue
Odour: pleasantly fresh flowery
pH:
(undiluted) (20'C) ca. 1
(at 10g/l H2O) (20'C) ca. 1,5
Flash point: not applicable
Relative density:
(20'C) ca. 1,55 g/cm3
Solubility: Soluble in water (20 'C) unlimited
10. Stability and reactivity
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Conditions to avoid:
none known
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Materials to avoid:
Do not use together with other cleaning agents. Cleanings agents
containing hypochlorites release toxic gases which may damage
the respiratory system.
Reacts with alkalis: heat generated
Hazardous decomposition products:
none known
11. Toxicological information
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Skin contact:
The product causes corrosion on skin and mucous membranes.
Eye contact:
Risk of serious damage to eyes
12. Ecological information
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Persistence and degradability:
Predominantly inorganic product. Information relating to
biodegradability relates only to the organic component(s).
This product contains surfactants which are at least 90 %
Biodegradable.
13. Disposal considerations
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Dispose of in accordance with Local Authority requirements e.g. delivery to designated station for disposal of chemical waste. Verify that procedure complies with local regulations.
14. Transport information
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Transport over land ADR/RID:
Class: 8 PG: III Classification Code C1
1st numbering of tanks panel: 80
2nd numbering of tanks panel: 1805
Designation of goods:
UN 1805 Phosphoric acid, liquid, solution
Exemption from the dangerous goods regulation of the above mentioned class due to application of the limited quantities regulation. It is valid for the following products which are transported in the complete original packaging: 4 x 1 L.
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Transport over inland waterways ADN/ADNR:
Class: 8 PG: III
Designation of goods:
UN 1805 Phosphoric acid, liquid, solution
Transport over sea IMDG:
Class: 8 UN-No.: 1805 PG: III
EmS: F-A; S-B
Proper shipping name:
Phosphoric acid, liquid, solution
Transport by air ICAO/IATA:
Class: 8 UN/ID-No.: 1805 PG: III
Pkg-Instr. (passangerair.): 819
Pkg-Instr.(cargo air. only): 821
Proper shipping name:
Phosphoric acid, liquid, solution
15. Regulatory information
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Classification and labelling according to CHIP:
Symbols of danger:
C Corrosive
Ingredients:
Phosphoric Acid
R-phrases:
R 34: Causes burns
R 52/53 Harmful to aquatic organisms, may cause long- term
adverse effects in the aquatic environment.
S-phrases:
S 26: In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice
S 36/37/39: Wear suitable protective clothing, gloves and
eye/face protection
S 45: In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible)
National prescriptions:
The Control of Substances Hazardous to Health Regulations
Health and Safety at Work Act
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16. Other information
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This information is based on our current level of knowledge and
relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety
requirements and is not intended to guarantee any particular
properties.
Full text of the R-phrases indicated by codes in this safety data
sheet. The product code/identification/designation is indicated in
Section 15.
R 22: Harmful if swallowed
R 34: Causes burns
R 38: Irritating to skin
R 41: Risk of serious damage to eyes
R 50: Very toxic to aquatic organisms.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.