The source materials of four samples:
- Sample 01: treated by NaOH of 0.10 M
- Sample 06: treated by NaOH of 0.35 M
- Sample 07: treated by NaOH of 0.40 M
- Sample 08: treated by NaOH of 0.50 M
- Sample 10: treated by NaOH of 1.00 M
Sample 01: treated by NaOH of 0.10 M
424-ZL-C22
Quantachrome Instruments
QuantachromeAutosorb Automated Gas Sorption System Report
Autosorb 1 for Windows 1.50
File name: C:\QCdata\PhysData\424-ZL-C22.raw
Sample ID: 424-ZL-C22 Description: 060906
Comments:
Operator: Sample weight: 0.196 g
Analysis gas: Nitrogen X sect. area: 16.2 Ų/molec Non-ideality: 6.58e-05
Adsbate (DRP): Nitrogen Bath Temp.: 77.40
Outgas Temp: 300.0 °C Outgas Time: 1.0 hrs Analysis Time: 261.9 min
P/Po tolerance: 3 Equil. time: 1 End of run: 09/07/2006 02:43
Station #: 1 PC sw. version: 1.50 TempComp: On
Isotherm
P/Po Volume P/Po Volume P/Po Volume
[cc/g] STP [cc/g] STP [cc/g] STP
4.7381e-02 103.0286 6.9648e-01 136.3158 6.4047e-01 154.0408
9.6571e-02 109.5643 7.5505e-01 140.4418 5.9037e-01 153.4143
1.5192e-01 113.9541 8.0458e-01 144.6862 5.4051e-01 152.7327
1.9909e-01 116.5347 8.5184e-01 149.4291 4.8793e-01 152.5184
2.5061e-01 118.7714 9.0095e-01 154.3454 4.5018e-01 129.8745
3.0208e-01 120.6832 9.5506e-01 158.3954 3.9538e-01 124.6327
3.5292e-01 122.4046 9.9541e-01 167.7781 3.4523e-01 122.3791
4.0318e-01 124.0184 9.5101e-01 160.9199 2.9359e-01 120.5709
4.5308e-01 125.6362 8.9813e-01 158.6791 2.4373e-01 118.6857
5.0267e-01 127.3255 8.4327e-01 157.2668 1.9457e-01 116.5143
5.5172e-01 129.1577 7.9185e-01 156.2245 1.4630e-01 113.8413
6.0039e-01 131.2240 7.4107e-01 155.3745 9.9643e-02 110.2036
6.4862e-01 133.5806 6.9050e-01 154.6796 5.1091e-02 104.0367
BJH DESORPTION PORE SIZE DISTRIBUTION
Diamater PoreVol Pore Surf Area Dv(d) Ds(d) Dv(log d) Ds(log d)
Å [cc/g] [m²/g] [cc/Å/g] [m²/Å/g] [cc/g] [m²/g]
14.22 1.668E-02 4.690E+01 6.175E-03 1.736E+01 2.017E-01 5.671E+02
16.73 2.447E-02 6.553E+01 3.361E-03 8.034E+00 1.293E-01 3.091E+02
19.07 2.849E-02 7.395E+01 1.701E-03 3.567E+00 7.461E-02 1.565E+02
21.49 3.059E-02 7.787E+01 8.484E-04 1.579E+00 4.194E-02 7.805E+01
24.08 3.155E-02 7.945E+01 3.562E-04 5.918E-01 1.973E-02 3.277E+01
26.94 3.194E-02 8.004E+01 1.307E-04 1.941E-01 8.098E-03 1.202E+01
30.11 3.416E-02 8.299E+01 6.729E-04 8.940E-01 4.660E-02 6.191E+01
33.82 4.676E-02 9.789E+01 3.047E-03 3.603E+00 2.370E-01 2.803E+02
37.52 1.224E-01 1.785E+02 2.315E-02 2.468E+01 1.999E+00 2.131E+03
41.81 1.225E-01 1.786E+02 2.759E-05 2.640E-02 2.652E-03 2.538E+00
47.52 1.241E-01 1.800E+02 2.648E-04 2.229E-01 2.893E-02 2.435E+01
54.42 1.255E-01 1.810E+02 1.831E-04 1.346E-01 2.291E-02 1.684E+01
63.21 1.269E-01 1.819E+02 1.398E-04 8.848E-02 2.031E-02 1.285E+01
74.96 1.284E-01 1.827E+02 1.078E-04 5.753E-02 1.856E-02 9.902E+00
91.68 1.302E-01 1.834E+02 8.951E-05 3.905E-02 1.882E-02 8.212E+00
117.81 1.323E-01 1.842E+02 6.536E-05 2.219E-02 1.762E-02 5.982E+00
168.45 1.350E-01 1.848E+02 3.981E-05 9.452E-03 1.522E-02 3.615E+00
306.05 1.391E-01 1.854E+02 1.970E-05 2.574E-03 1.334E-02 1.743E+00
2287.00 1.499E-01 1.855E+02 2.887E-06 5.049E-05 1.076E-02 1.882E-01
AREA-VOLUME-PORE SIZE SUMMARY
SURFACE AREA DATA
Multipoint BET...... 3.843E+02 m²/g
Langmuir Surface Area...... 7.353E+02 m²/g
BJH Method Cumulative Adsorption Surface Area...... 1.743E+02 m²/g
BJH Method Cumulative Desorption Surface Area...... 1.855E+02 m²/g
DH Method Cumulative Adsorption Surface Area...... 1.854E+02 m²/g
DH Method Cumulative Desorption Surface Area...... 1.932E+02 m²/g
t-Method External Surface Area...... 6.270E+01 m²/g
t-Method Micro Pore Surface Area...... 3.216E+02 m²/g
DR Method Micro Pore Area...... 6.210E+02 m²/g
PORE VOLUME DATA
Total Pore Volume for pores with Diameter
less than 4164.8 Å at P/Po = 0.99541...... 2.579E-01 cc/g
BJH Method Cumulative Adsorption Pore Volume...... 1.463E-01 cc/g
BJH Method Cumulative Desorption Pore Volume...... 1.499E-01 cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 1.463E-01 cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 1.499E-01 cc/g
DH Method Cumulative Adsorption Pore Volume...... 1.481E-01 cc/g
DH Method Cumulative Desorption Pore Volume...... 1.503E-01 cc/g
t-Method Micro Pore Volume...... 1.587E-01 cc/g
DR Method Micro Pore Volume...... 2.193E-01 cc/g
PORE SIZE DATA
Average Pore Diameter...... 2.685E+01 Å
BJH Method Adsorption Pore Diameter (Mode)...... 1.403E+01 Å
BJH Method Desorption Pore Diameter (Mode)...... 3.752E+01 Å
DH Method Adsorption Pore Diameter (Mode)...... 1.403E+01 Å
DH Method Desorption Pore Diameter (Mode)...... 3.752E+01 Å
DR Method Micro Pore Width ...... 3.419E+01 Å
Sample 06: treated by NaOH of 0.35 M
433--ZL-C27
Quantachrome Instruments
QuantachromeAutosorb Automated Gas Sorption System Report
Autosorb 1 for Windows 1.50
File name: C:\QCdata\PhysData\433-ZL-C27.raw
Sample ID: 433--ZL-C27 Description: 060914
Comments:
Operator: Sample weight: 0.165 g
Analysis gas: Nitrogen X sect. area: 16.2 Ų/molec Non-ideality: 6.58e-05
Adsbate (DRP): Nitrogen Bath Temp.: 77.40
Outgas Temp: 300.0 °C Outgas Time: 1.0 hrs Analysis Time: 443.4 min
P/Po tolerance: 3 Equil. time: 1 End of run: 09/14/2006 23:30
Station #: 1 PC sw. version: 1.50 TempComp: On
Isotherm
P/Po Volume P/Po Volume P/Po Volume
[cc/g] STP [cc/g] STP [cc/g] STP
5.2890e-02 103.7824 7.0145e-01 161.6139 6.4768e-01 207.3170
1.0354e-01 109.5697 7.4853e-01 174.1327 5.9702e-01 200.1861
1.5548e-01 113.9806 7.9765e-01 190.4557 5.4620e-01 193.3000
1.9842e-01 117.0788 8.4722e-01 214.1376 5.0266e-01 188.4170
2.4735e-01 120.3539 9.0043e-01 246.0109 4.5297e-01 138.7667
2.9734e-01 123.5600 9.4830e-01 285.3085 4.0036e-01 131.3145
3.4720e-01 126.7497 9.9432e-01 371.4570 3.4975e-01 127.1879
3.9700e-01 129.9776 9.5331e-01 318.4036 2.9746e-01 123.6697
4.4608e-01 133.3309 9.0370e-01 271.6891 2.4665e-01 120.2782
5.0355e-01 137.6436 8.4973e-01 247.4430 1.9669e-01 116.7709
5.5331e-01 141.8454 7.9688e-01 233.0436 1.4716e-01 113.0182
6.0096e-01 146.7436 7.5360e-01 224.3624 9.8448e-02 108.7188
6.4765e-01 152.6745 6.9624e-01 214.6570 4.4065e-02 102.6473
BJH DESORPTION PORE SIZE DISTRIBUTION
Diamater PoreVol Pore Surf Area Dv(d) Ds(d) Dv(log d) Ds(log d)
Å [cc/g] [m²/g] [cc/Å/g] [m²/Å/g] [cc/g] [m²/g]
13.97 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
16.72 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
19.15 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
21.62 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
24.26 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
27.19 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
30.42 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
34.11 9.014E-03 1.057E+01 2.247E-03 2.635E+00 1.763E-01 2.067E+02
38.33 1.663E-01 1.747E+02 3.555E-02 3.710E+01 3.134E+00 3.271E+03
42.82 1.763E-01 1.841E+02 2.199E-03 2.055E+00 2.167E-01 2.024E+02
48.30 1.912E-01 1.964E+02 2.331E-03 1.931E+00 2.589E-01 2.144E+02
55.51 2.063E-01 2.072E+02 1.872E-03 1.349E+00 2.388E-01 1.721E+02
64.51 2.213E-01 2.166E+02 1.513E-03 9.383E-01 2.243E-01 1.391E+02
77.71 2.408E-01 2.266E+02 1.181E-03 6.079E-01 2.105E-01 1.084E+02
95.01 2.578E-01 2.338E+02 9.415E-04 3.964E-01 2.053E-01 8.645E+01
121.84 2.860E-01 2.430E+02 7.924E-04 2.602E-01 2.207E-01 7.246E+01
176.85 3.325E-01 2.536E+02 6.246E-04 1.413E-01 2.505E-01 5.666E+01
321.34 4.175E-01 2.641E+02 3.960E-04 4.929E-02 2.818E-01 3.507E+01
1898.43 5.018E-01 2.659E+02 2.870E-05 6.048E-04 9.424E-02 1.986E+00
AREA-VOLUME-PORE SIZE SUMMARY
SURFACE AREA DATA
Multipoint BET...... 3.903E+02 m²/g
Langmuir Surface Area...... 1.470E+03 m²/g
BJH Method Cumulative Adsorption Surface Area...... 1.901E+02 m²/g
BJH Method Cumulative Desorption Surface Area...... 2.659E+02 m²/g
DH Method Cumulative Adsorption Surface Area...... 1.954E+02 m²/g
DH Method Cumulative Desorption Surface Area...... 2.726E+02 m²/g
t-Method External Surface Area...... 2.497E+02 m²/g
t-Method Micro Pore Surface Area...... 1.407E+02 m²/g
DR Method Micro Pore Area...... 8.063E+02 m²/g
PORE VOLUME DATA
Total Pore Volume for pores with Diameter
less than 3368.3 Å at P/Po = 0.99432...... 5.710E-01 cc/g
BJH Method Cumulative Adsorption Pore Volume...... 4.674E-01 cc/g
BJH Method Cumulative Desorption Pore Volume...... 5.018E-01 cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 4.674E-01 cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 5.018E-01 cc/g
DH Method Cumulative Adsorption Pore Volume...... 4.629E-01 cc/g
DH Method Cumulative Desorption Pore Volume...... 4.988E-01 cc/g
t-Method Micro Pore Volume...... 7.200E-02 cc/g
DR Method Micro Pore Volume...... 2.848E-01 cc/g
PORE SIZE DATA
Average Pore Diameter...... 5.852E+01 Å
BJH Method Adsorption Pore Diameter (Mode)...... 1.438E+01 Å
BJH Method Desorption Pore Diameter (Mode)...... 3.833E+01 Å
DH Method Adsorption Pore Diameter (Mode)...... 1.438E+01 Å
DH Method Desorption Pore Diameter (Mode)...... 3.833E+01 Å
DR Method Micro Pore Width ...... 4.881E+01 Å
Sample 07: treated by NaOH of 0.40 M
434--ZL-C28
Quantachrome Instruments
QuantachromeAutosorb Automated Gas Sorption System Report
Autosorb 1 for Windows 1.50
File name: C:\QCdata\PhysData\434-ZL-C28.raw
Sample ID: 434--ZL-C28 Description: 060915
Comments:
Operator: Sample weight: 0.17 g
Analysis gas: Nitrogen X sect. area: 16.2 Ų/molec Non-ideality: 6.58e-05
Adsbate (DRP): Nitrogen Bath Temp.: 77.40
Outgas Temp: 300.0 °C Outgas Time: 1.0 hrs Analysis Time: 569.6 min
P/Po tolerance: 3 Equil. time: 1 End of run: 09/15/2006 17:59
Station #: 1 PC sw. version: 1.50 TempComp: On
Isotherm
P/Po Volume P/Po Volume P/Po Volume
[cc/g] STP [cc/g] STP [cc/g] STP
5.1250e-02 98.1112 7.0368e-01 153.1782 6.4810e-01 197.4394
1.0405e-01 103.7129 7.4783e-01 163.0829 5.9432e-01 195.0418
1.4805e-01 107.2147 7.9927e-01 180.2512 5.4896e-01 186.8671
1.9804e-01 110.6388 8.4900e-01 205.4935 4.9797e-01 180.0776
2.4861e-01 113.8529 8.9873e-01 238.4988 4.5384e-01 131.2729
2.9887e-01 116.9518 9.4799e-01 279.1712 4.0267e-01 124.2006
3.4864e-01 120.0353 9.9406e-01 389.0994 3.4253e-01 119.4794
3.9842e-01 123.1400 9.5186e-01 318.0688 2.9579e-01 116.4500
4.4771e-01 126.3553 9.0234e-01 267.1282 2.4633e-01 113.2441
4.9650e-01 129.7812 8.4962e-01 240.2047 1.9639e-01 109.9324
5.5623e-01 134.5824 7.9817e-01 225.1306 1.4676e-01 106.5582
6.0623e-01 139.3818 7.4902e-01 214.4165 9.8085e-02 102.6935
6.5281e-01 144.9871 6.9553e-01 204.9000 4.6021e-02 97.3712
BJH DESORPTION PORE SIZE DISTRIBUTION
Diamater PoreVol Pore Surf Area Dv(d) Ds(d) Dv(log d) Ds(log d)
Å [cc/g] [m²/g] [cc/Å/g] [m²/Å/g] [cc/g] [m²/g]
14.02 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
16.71 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
19.13 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
21.61 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
24.20 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
26.91 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
30.28 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
34.23 7.932E-03 9.268E+00 2.024E-03 2.365E+00 1.594E-01 1.862E+02
38.14 1.638E-01 1.728E+02 3.993E-02 4.188E+01 3.504E+00 3.675E+03
42.75 1.789E-01 1.869E+02 2.840E-03 2.657E+00 2.792E-01 2.612E+02
48.27 1.987E-01 2.033E+02 3.457E-03 2.865E+00 3.838E-01 3.181E+02
55.36 1.994E-01 2.038E+02 8.495E-05 6.138E-02 1.081E-02 7.809E+00
64.46 2.145E-01 2.131E+02 1.548E-03 9.605E-01 2.293E-01 1.423E+02
76.84 2.333E-01 2.229E+02 1.251E-03 6.512E-01 2.206E-01 1.149E+02
94.55 2.542E-01 2.318E+02 1.029E-03 4.354E-01 2.232E-01 9.441E+01
122.11 2.834E-01 2.413E+02 8.401E-04 2.752E-01 2.346E-01 7.685E+01
175.37 3.352E-01 2.532E+02 7.213E-04 1.645E-01 2.871E-01 6.550E+01
313.74 4.280E-01 2.650E+02 4.527E-04 5.772E-02 3.150E-01 4.017E+01
1819.70 5.411E-01 2.675E+02 4.030E-05 8.858E-04 1.272E-01 2.797E+00
AREA-VOLUME-PORE SIZE SUMMARY
SURFACE AREA DATA
Multipoint BET...... 3.684E+02 m²/g
Langmuir Surface Area...... 1.452E+03 m²/g
BJH Method Cumulative Adsorption Surface Area...... 1.784E+02 m²/g
BJH Method Cumulative Desorption Surface Area...... 2.675E+02 m²/g
DH Method Cumulative Adsorption Surface Area...... 1.832E+02 m²/g
DH Method Cumulative Desorption Surface Area...... 2.736E+02 m²/g
t-Method External Surface Area...... 2.584E+02 m²/g
t-Method Micro Pore Surface Area...... 1.100E+02 m²/g
DR Method Micro Pore Area...... 7.742E+02 m²/g
PORE VOLUME DATA
Total Pore Volume for pores with Diameter
less than 3223.2 Å at P/Po = 0.99406...... 5.982E-01 cc/g
BJH Method Cumulative Adsorption Pore Volume...... 4.998E-01 cc/g
BJH Method Cumulative Desorption Pore Volume...... 5.411E-01 cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 4.998E-01 cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 5.411E-01 cc/g
DH Method Cumulative Adsorption Pore Volume...... 4.943E-01 cc/g
DH Method Cumulative Desorption Pore Volume...... 5.369E-01 cc/g
t-Method Micro Pore Volume...... 5.546E-02 cc/g
DR Method Micro Pore Volume...... 2.735E-01 cc/g
PORE SIZE DATA
Average Pore Diameter...... 6.495E+01 Å
BJH Method Adsorption Pore Diameter (Mode)...... 1.434E+01 Å
BJH Method Desorption Pore Diameter (Mode)...... 3.814E+01 Å
DH Method Adsorption Pore Diameter (Mode)...... 1.434E+01 Å
DH Method Desorption Pore Diameter (Mode)...... 3.814E+01 Å
DR Method Micro Pore Width ...... 4.967E+01 Å
Sample 08: treated by NaOH of 0.50 M
435--ZL-C29
Quantachrome Instruments
QuantachromeAutosorb Automated Gas Sorption System Report
Autosorb 1 for Windows 1.50
File name: C:\QCdata\PhysData\435-ZL-C29.raw
Sample ID: 435--ZL-C29 Description: 060915
Comments:
Operator: Sample weight: 0.158 g
Analysis gas: Nitrogen X sect. area: 16.2 Ų/molec Non-ideality: 6.58e-05
Adsbate (DRP): Nitrogen Bath Temp.: 77.40
Outgas Temp: 300.0 °C Outgas Time: 1.0 hrs Analysis Time: 387.4 min
P/Po tolerance: 3 Equil. time: 1 End of run: 09/16/2006 04:13
Station #: 1 PC sw. version: 1.50 TempComp: On
Isotherm
P/Po Volume P/Po Volume P/Po Volume
[cc/g] STP [cc/g] STP [cc/g] STP
4.9350e-02 67.4513 7.0687e-01 105.6797 6.5258e-01 163.2658
1.0683e-01 72.1684 7.5006e-01 111.0582 6.0144e-01 159.1879
1.5134e-01 74.8335 8.0114e-01 120.5804 5.4880e-01 155.4544
2.0148e-01 77.4006 8.5190e-01 137.7734 5.0272e-01 147.6348
2.5200e-01 79.7791 8.9901e-01 172.2070 4.4773e-01 92.9437
3.0234e-01 82.0259 9.4676e-01 220.0721 4.0045e-01 88.5108
3.5222e-01 84.2544 9.9479e-01 333.4772 3.4685e-01 85.0823
4.0210e-01 86.4804 9.4862e-01 270.6165 2.9411e-01 82.4456
4.5154e-01 88.7835 9.0158e-01 211.3671 2.4337e-01 79.9804
5.0074e-01 91.2418 8.4768e-01 190.7209 1.9335e-01 77.4354
5.4978e-01 93.8918 7.9505e-01 179.7342 1.4370e-01 74.6829
5.9829e-01 96.8430 7.4508e-01 172.5835 9.4536e-02 71.4772
6.5763e-01 101.1620 7.0188e-01 167.8025 5.1264e-02 67.7310
BJH DESORPTION PORE SIZE DISTRIBUTION
Diamater PoreVol Pore Surf Area Dv(d) Ds(d) Dv(log d) Ds(log d)
Å [cc/g] [m²/g] [cc/Å/g] [m²/Å/g] [cc/g] [m²/g]
14.10 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
16.54 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
18.98 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
21.45 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
24.08 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
27.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
30.34 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
33.90 2.858E-04 3.372E-01 7.988E-05 9.425E-02 6.230E-03 7.350E+00
38.12 1.745E-01 1.832E+02 3.587E-02 3.764E+01 3.144E+00 3.299E+03
42.97 1.950E-01 2.022E+02 4.230E-03 3.937E+00 4.181E-01 3.892E+02
48.76 2.016E-01 2.076E+02 9.731E-04 7.983E-01 1.091E-01 8.948E+01
56.27 2.087E-01 2.127E+02 8.618E-04 6.127E-01 1.115E-01 7.923E+01
65.63 2.167E-01 2.175E+02 7.616E-04 4.642E-01 1.148E-01 6.999E+01
76.95 2.251E-01 2.219E+02 6.945E-04 3.610E-01 1.228E-01 6.383E+01
93.11 2.381E-01 2.275E+02 6.430E-04 2.762E-01 1.373E-01 5.899E+01
120.47 2.583E-01 2.342E+02 5.849E-04 1.942E-01 1.611E-01 5.350E+01
173.72 2.968E-01 2.431E+02 5.354E-04 1.233E-01 2.111E-01 4.860E+01
300.29 4.059E-01 2.576E+02 6.020E-04 8.019E-02 4.033E-01 5.372E+01
2030.18 5.056E-01 2.596E+02 3.041E-05 5.991E-04 1.025E-01 2.020E+00
AREA-VOLUME-PORE SIZE SUMMARY
SURFACE AREA DATA
Multipoint BET...... 2.579E+02 m²/g
Langmuir Surface Area...... 1.170E+03 m²/g
BJH Method Cumulative Adsorption Surface Area...... 1.350E+02 m²/g
BJH Method Cumulative Desorption Surface Area...... 2.596E+02 m²/g
DH Method Cumulative Adsorption Surface Area...... 1.394E+02 m²/g
DH Method Cumulative Desorption Surface Area...... 2.670E+02 m²/g
t-Method External Surface Area...... 2.246E+02 m²/g
t-Method Micro Pore Surface Area...... 3.321E+01 m²/g
DR Method Micro Pore Area...... 5.791E+02 m²/g
PORE VOLUME DATA
Total Pore Volume for pores with Diameter
less than 3669.5 Å at P/Po = 0.99479...... 5.127E-01 cc/g
BJH Method Cumulative Adsorption Pore Volume...... 4.482E-01 cc/g
BJH Method Cumulative Desorption Pore Volume...... 5.056E-01 cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 4.482E-01 cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 5.056E-01 cc/g
DH Method Cumulative Adsorption Pore Volume...... 4.430E-01 cc/g
DH Method Cumulative Desorption Pore Volume...... 5.029E-01 cc/g
t-Method Micro Pore Volume...... 1.848E-02 cc/g
DR Method Micro Pore Volume...... 2.045E-01 cc/g
PORE SIZE DATA
Average Pore Diameter...... 7.953E+01 Å
BJH Method Adsorption Pore Diameter (Mode)...... 1.435E+01 Å
BJH Method Desorption Pore Diameter (Mode)...... 3.812E+01 Å
DH Method Adsorption Pore Diameter (Mode)...... 1.435E+01 Å
DH Method Desorption Pore Diameter (Mode)...... 3.812E+01 Å
DR Method Micro Pore Width ...... 5.330E+01 Å
Sample 10: treated by NaOH of 1.00 M
436--ZL-C30
Quantachrome Instruments
QuantachromeAutosorb Automated Gas Sorption System Report
Autosorb 1 for Windows 1.50
File name: C:\QCdata\PhysData\436--ZL-C30.raw
Sample ID: 436--ZL-C30 Description: 060916
Comments:
Operator: Sample weight: 0.187 g
Analysis gas: Nitrogen X sect. area: 16.2 Ų/molec Non-ideality: 6.58e-05
Adsbate (DRP): Nitrogen Bath Temp.: 77.40
Outgas Temp: 300.0 °C Outgas Time: 1.0 hrs Analysis Time: 317.6 min
P/Po tolerance: 3 Equil. time: 1 End of run: 09/16/2006 14:12
Station #: 1 PC sw. version: 1.50 TempComp: On
Isotherm
P/Po Volume P/Po Volume P/Po Volume
[cc/g] STP [cc/g] STP [cc/g] STP
5.2894e-02 18.5860 7.0475e-01 29.8429 6.4223e-01 30.7764
1.0586e-01 19.9055 7.5342e-01 31.2092 5.9149e-01 29.5513
1.5731e-01 20.8629 8.0123e-01 32.9763 5.4109e-01 28.4624
2.0787e-01 21.6648 8.4753e-01 35.4013 4.9179e-01 27.2705
2.5799e-01 22.4117 8.9684e-01 40.4090 4.4286e-01 25.4989
3.0804e-01 23.1203 9.4731e-01 57.7353 3.9095e-01 24.4426
3.5790e-01 23.8265 9.9356e-01 202.2422 3.4035e-01 23.5430
4.0772e-01 24.5290 9.5312e-01 84.9979 2.9006e-01 22.7145
4.5753e-01 25.2526 8.9460e-01 52.9534 2.3983e-01 21.9118
5.0715e-01 26.0126 8.4574e-01 39.9922 1.8976e-01 21.0952
5.5674e-01 26.8283 7.9976e-01 36.5744 1.3977e-01 20.2791
6.0621e-01 27.7127 7.4665e-01 34.0480 9.0121e-02 19.3417
6.5564e-01 28.7052 6.9394e-01 32.2160 4.2924e-02 18.2537
BJH DESORPTION PORE SIZE DISTRIBUTION
Diamater PoreVol Pore Surf Area Dv(d) Ds(d) Dv(log d) Ds(log d)
Å [cc/g] [m²/g] [cc/Å/g] [m²/Å/g] [cc/g] [m²/g]
13.71 4.484E-04 1.308E+00 1.637E-04 4.776E-01 5.152E-03 1.503E+01
16.33 1.118E-03 2.948E+00 2.685E-04 6.578E-01 1.008E-02 2.468E+01
18.80 1.620E-03 4.016E+00 2.056E-04 4.376E-01 8.887E-03 1.891E+01
21.27 2.306E-03 5.305E+00 2.725E-04 5.123E-01 1.333E-02 2.507E+01
23.88 2.978E-03 6.432E+00 2.504E-04 4.195E-01 1.375E-02 2.304E+01
26.69 3.737E-03 7.569E+00 2.584E-04 3.872E-01 1.586E-02 2.377E+01
29.80 4.689E-03 8.847E+00 2.891E-04 3.880E-01 1.982E-02 2.660E+01
33.37 6.049E-03 1.048E+01 3.533E-04 4.234E-01 2.712E-02 3.250E+01
37.41 9.947E-03 1.465E+01 9.252E-04 9.894E-01 7.961E-02 8.513E+01
42.02 1.174E-02 1.635E+01 3.570E-04 3.399E-01 3.450E-02 3.284E+01
47.63 1.294E-02 1.736E+01 1.946E-04 1.635E-01 2.131E-02 1.790E+01
54.64 1.428E-02 1.834E+01 1.713E-04 1.254E-01 2.152E-02 1.575E+01
63.75 1.586E-02 1.933E+01 1.513E-04 9.493E-02 2.216E-02 1.390E+01
76.26 1.799E-02 2.045E+01 1.458E-04 7.646E-02 2.552E-02 1.338E+01
94.56 2.123E-02 2.182E+01 1.477E-04 6.247E-02 3.201E-02 1.354E+01
120.82 2.624E-02 2.348E+01 1.638E-04 5.424E-02 4.533E-02 1.501E+01
166.23 5.067E-02 2.936E+01 4.055E-04 9.758E-02 1.535E-01 3.693E+01
311.65 1.078E-01 3.669E+01 2.478E-04 3.181E-02 1.694E-01 2.174E+01
1701.24 2.950E-01 4.110E+01 7.345E-05 1.727E-03 2.220E-01 5.220E+00
AREA-VOLUME-PORE SIZE SUMMARY
SURFACE AREA DATA
Multipoint BET...... 7.201E+01 m²/g
Langmuir Surface Area...... 2.770E+02 m²/g
BJH Method Cumulative Adsorption Surface Area...... 4.095E+01 m²/g
BJH Method Cumulative Desorption Surface Area...... 4.110E+01 m²/g
DH Method Cumulative Adsorption Surface Area...... 4.226E+01 m²/g
DH Method Cumulative Desorption Surface Area...... 4.150E+01 m²/g
t-Method External Surface Area...... 7.201E+01 m²/g
t-Method Micro Pore Surface Area...... 0.000E+00 m²/g
DR Method Micro Pore Area...... 1.483E+02 m²/g
PORE VOLUME DATA
Total Pore Volume for pores with Diameter
less than 2975.5 Å at P/Po = 0.99356...... 3.109E-01 cc/g
BJH Method Cumulative Adsorption Pore Volume...... 2.943E-01 cc/g
BJH Method Cumulative Desorption Pore Volume...... 2.950E-01 cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 2.943E-01 cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 Å Diamater...... 2.950E-01 cc/g
DH Method Cumulative Adsorption Pore Volume...... 2.892E-01 cc/g
DH Method Cumulative Desorption Pore Volume...... 2.902E-01 cc/g
t-Method Micro Pore Volume...... 0.000E+00 cc/g
DR Method Micro Pore Volume...... 5.237E-02 cc/g
PORE SIZE DATA
Average Pore Diameter...... 1.727E+02 Å
BJH Method Adsorption Pore Diameter (Mode)...... 1.444E+01 Å
BJH Method Desorption Pore Diameter (Mode)...... 3.741E+01 Å
DH Method Adsorption Pore Diameter (Mode)...... 1.444E+01 Å
DH Method Desorption Pore Diameter (Mode)...... 3.741E+01 Å
DR Method Micro Pore Width ...... 4.944E+01 Å